Nucleophiles

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Name	Solvent	Reactivity Parameters	Reference (title or year)
7-F-BTM (in CH2Cl2)	dichloromethane	N Param.: 13.46 s_N Param.: 0.66	Angew. Chem. Int. Ed. 2025, EarlyView, e202514865 10.1002/anie.202514865
7-azaindole	MeCN	N Param.: 3.87 s_N Param.: 1.10	J. Org. Chem. 2006, 71, 9088-9095 10.1021/jo0614339
7% water/93% HFIP (w/w)	water-HFIP mix	N Param.: 0.34 s_N Param.: 0.96	J. Phys. Org. Chem. 2013, 26, 59-63 10.1002/poc.3064
67% water/33% MeCN (v/v)	water-MeCN mix	N Param.: 5.05 s_N Param.: 0.90	J. Am. Chem. Soc. 2004, 126, 5174-5181 10.1021/ja031828z
67% methanol/33% MeCN (v/v)	MeOH-MeCN mix	N Param.: 7.01 s_N Param.: 0.91	J. Am. Chem. Soc. 2004, 126, 5174-5181 10.1021/ja031828z
67% ethanol/33% MeCN (v/v)	EtOH-MeCN mix	N Param.: 6.74 s_N Param.: 0.89	J. Am. Chem. Soc. 2004, 126, 5174-5181 10.1021/ja031828z
60% water/40%TFE (v/v)	water-TFE mix	N Param.: 3.77 s_N Param.: 0.88	J. Am. Chem. Soc. 2004, 126, 5174-5181 10.1021/ja031828z
60% water/40%EtOH (v/v)	water-EtOH mix	N Param.: 5.81 s_N Param.: 0.90	J. Am. Chem. Soc. 2004, 126, 5174-5181 10.1021/ja031828z
6-methyl-3-(phenyl-l3-iodanylidene)dihydro-2H-pyran-2,4(3H)-dione (in CH2Cl2)	dichloromethane	N Param.: 4.67 s_N Param.: 0.92	J. Am. Chem. Soc. 2016, 138, 10304-10313 10.1021/jacs.6b05768
6-methoxy-quinoline (in MeCN)	MeCN	N Param.: 10.86 s_N Param.: 0.66	J. Org. Chem. 2009, 74, 7157-7164 10.1021/jo901670w