| MacMillan-iminium ion (1st generation) |
MeCN | E Param.: -7.37 |  | Angew. Chem. Int. Ed. 2011, 50, 9953-9956
10.1002/anie.201103683 |
| mor iminium |
| E Param.: -8.60 | | Angew. Chem. Int. Ed. 2008, 47, 8723-8726
10.1002/anie.200802889 |
| MacMillan-iminium ion (2nd generation) |
MeCN | E Param.: -5.52 | | Angew. Chem. Int. Ed. 2011, 50, 9953-9956
10.1002/anie.201103683 |
| MacMillan-iminium ion (spiro) |
MeCN | E Param.: -7.67 | | Angew. Chem. Int. Ed. 2011, 50, 9953-9956
10.1002/anie.201103683 |
| indolecarboxylate derived iminium ion |
dichloromethane | E Param.: -9.50 | | Angew. Chem. Int. Ed. 2009, 48, 5034-5037
10.1002/anie.200900933 |
| 2-cinnamoyl-1,3-dimethyl-1H-imidazol-3-ium |
DMSO | E Param.: -11.52 | | Angew. Chem. Int. Ed. 2012, 51, 5234-5238
10.1002/anie.201109042 |
| (S,E)-2,2,3-trimethyl-4-oxo-5-((perfluorophenyl)methyl)-1-((E)-3-phenylallylidene)imidazolidin-1-ium |
dichloromethane | E Param.: -6.00 | | Angew. Chem. Int. Ed. 2013, 52, 7967-7971
10.1002/anie.201301864 |
| (S,E)-2,2,3-trimethyl-4-oxo-1-((E)-3-phenylallylidene)-5-(3,4,5-trimethoxybenzyl)imidazolidin-1-ium |
dichloromethane | E Param.: -7.00 | | Angew. Chem. Int. Ed. 2013, 52, 7967-7971
10.1002/anie.201301864 |
| ethenesulfonyl fluoride (ESF) |
DMSO | E Param.: -12.09 | | Angew. Chem. Int. Ed. 2016, 55, 12664-12667
10.1002/anie.201601875 |
| 2-phenylethene-1-sulfonyl fluoride |
DMSO | E Param.: -16.63 | | Angew. Chem. Int. Ed. 2016, 55, 12664-12667
10.1002/anie.201601875 |
| N-(phenylsulfonyl)-N-((trifluoromethyl)thio)benzenesulfonamide |
| E Param.: -6.06 | | Angew. Chem. Int. Ed. 2018, 57, 12690-12695
10.1002/anie.201805859 |
| N-(trifluoromethyl)thio)phthalimide |
| E Param.: -11.92 | | Angew. Chem. Int. Ed. 2018, 57, 12690-12695
10.1002/anie.201805859 |
| N-(trifluoromethyl)thio)saccharin |
| E Param.: -6.48 | | Angew. Chem. Int. Ed. 2018, 57, 12690-12695
10.1002/anie.201805859 |
| N-(trifluoromethyl)thio)succinimide |
| E Param.: -12.56 | | Angew. Chem. Int. Ed. 2018, 57, 12690-12695
10.1002/anie.201805859 |
| N-(difluoromethyl)thio)phthalimide |
| E Param.: -11.86 | | Angew. Chem. Int. Ed. 2018, 57, 12690-12695
10.1002/anie.201805859 |
| N-methyl-N-((trifluoromethyl)thio)-p-toluenesulfonamide |
| E Param.: -13.44 | | Angew. Chem. Int. Ed. 2018, 57, 12690-12695
10.1002/anie.201805859 |
| N-methyl-N-((trifluoromethyl)thio)-aniline |
| E Param.: -23.32 | | Angew. Chem. Int. Ed. 2018, 57, 12690-12695
10.1002/anie.201805859 |
| ((2-phenylpropan-2-yl)oxy)(trifluoromethyl)sulfane |
| E Param.: -13.77 | | Angew. Chem. Int. Ed. 2018, 57, 12690-12695
10.1002/anie.201805859 |
| ((2-(2-iodophenyl)propan-2-yl)oxy)(trifluoromethyl)sulfane |
| E Param.: -14.52 | | Angew. Chem. Int. Ed. 2018, 57, 12690-12695
10.1002/anie.201805859 |
| 4-phenylbut-3-yn-2-one |
| E Param.: -16.90 |  | Angew. Chem. Int. Ed. 2019, 58, 17704-17708
10.1002/anie.201909803 |
| hex-3-yn-2-one |
| E Param.: -17.90 | | Angew. Chem. Int. Ed. 2019, 58, 17704-17708
10.1002/anie.201909803 |
| butynone |
| E Param.: -16.60 | | Angew. Chem. Int. Ed. 2019, 58, 17704-17708
10.1002/anie.201909803 |
| (S,E)-5-benzyl-2,2,3-trimethyl-1-((E)-3-(4-nitrophenyl)allylidene)-4-oxoimidazolidin-1-ium |
dichloromethane | E Param.: -5.90 | | Asian J. Org. Chem. 2014, 3, 550-555
10.1002/ajoc.201402009 |
| (S,E)-5-benzyl-1-((E)-3-(4-cyanophenyl)allylidene)-2,2,3-trimethyl-4-oxoimidazolidin-1-ium |
dichloromethane | E Param.: -6.00 | | Asian J. Org. Chem. 2014, 3, 550-555
10.1002/ajoc.201402009 |
| (S,E)-5-benzyl-1-((E)-3-(4-(dimethylamino)phenyl)allylidene)-2,2,3-trimethyl-4-oxoimidazolidin-1-ium |
dichloromethane | E Param.: -10.60 | | Asian J. Org. Chem. 2014, 3, 550-555
10.1002/ajoc.201402009 |
| (S,E)-5-benzyl-2,2,3-trimethyl-4-oxo-1-((E)-3-(p-tolyl)allylidene)imidazolidin-1-ium |
dichloromethane | E Param.: -7.20 | | Asian J. Org. Chem. 2014, 3, 550-555
10.1002/ajoc.201402009 |
| (S,E)-5-benzyl-1-((E)-3-(4-methoxyphenyl)allylidene)-2,2,3-trimethyl-4-oxoimidazolidin-1-ium |
dichloromethane | E Param.: -8.00 | | Asian J. Org. Chem. 2014, 3, 550-555
10.1002/ajoc.201402009 |
| (S,E)-5-benzyl-2,2,3-trimethyl-1-((E)-3-(3-nitrophenyl)allylidene)-4-oxoimidazolidin-1-ium |
dichloromethane | E Param.: -6.10 | | Asian J. Org. Chem. 2014, 3, 550-555
10.1002/ajoc.201402009 |
| (S,E)-5-((1H-indol-3-yl)methyl)-2,2,3-trimethyl-4-oxo-1-((E)-3-phenylallylidene)imidazolidin-1-ium |
dichloromethane | E Param.: -7.30 | | Asian J. Org. Chem. 2014, 3, 550-555
10.1002/ajoc.201402009 |
| (2S,5S)-5-benzyl-3-methyl-4-oxo-1-(3-phenylallylidene)-2-((E)-styryl)imidazolidin-1-ium |
dichloromethane | E Param.: -5.90 | | Asian J. Org. Chem. 2014, 3, 550-555
10.1002/ajoc.201402009 |
| (ethene-1,1-diyldisulfonyl)dibenzene |
DMSO | E Param.: -7.50 | | Chem. Asian J. 2012, 7, 1401-1407
10.1002/asia.201101046 |
| (2-phenylethene-1,1-diyldisulfonyl)dibenzene |
DMSO | E Param.: -12.93 | | Chem. Asian J. 2012, 7, 1401-1407
10.1002/asia.201101046 |
| (2-(4-methoxyphenyl)ethene-1,1-diyldisulfonyl)dibenzene |
DMSO | E Param.: -13.88 | | Chem. Asian J. 2012, 7, 1401-1407
10.1002/asia.201101046 |
| 4-(2,2-bis(phenylsulfonyl)vinyl)-N,N-dimethylaniline |
DMSO | E Param.: -16.53 | | Chem. Asian J. 2012, 7, 1401-1407
10.1002/asia.201101046 |
| 2-benzylidenebenzo[d][1,3]dithiole 1,1,3,3-tetraoxide |
DMSO | E Param.: -11.78 | | Chem. Asian J. 2012, 7, 1401-1407
10.1002/asia.201101046 |
| 2-(4-methoxybenzylidene)benzo[d][1,3]dithiole 1,1,3,3-tetraoxide |
DMSO | E Param.: -13.02 | | Chem. Asian J. 2012, 7, 1401-1407
10.1002/asia.201101046 |
| 2-(4-methoxybenzylidene)-1,3-dithiane 1,1,3,3-tetraoxide |
DMSO | E Param.: -14.55 | | Chem. Asian J. 2012, 7, 1401-1407
10.1002/asia.201101046 |
| ethyl 3-nitro-1H-indole-1-carboxylate |
| E Param.: -14.10 | | Chem. Commun. 2021, 57, 10071-10074
10.1039/d1cc04074j |
| 3-nitro-1-tosyl-1H-indole |
| E Param.: -14.87 | | Chem. Commun. 2021, 57, 10071-10074
10.1039/d1cc04074j |
| 4-bromo-3-nitro-1-tosyl-1H-indole |
| E Param.: -14.60 | | Chem. Commun. 2021, 57, 10071-10074
10.1039/d1cc04074j |
| 3,6-dinitro-1-tosyl-1H-indole |
| E Param.: -12.90 | | Chem. Commun. 2021, 57, 10071-10074
10.1039/d1cc04074j |
| 4-nitrobenzodifuroxan (NBDF) |
| E Param.: -6.15 | | Chem. Eur. J. 2007, 13, 8317-8324
10.1002/chem.200700676 |
| diethyl benzylidene malonate |
| E Param.: -20.55 | | Chem. Eur. J. 2008, 14, 9675-9682
10.1002/chem.200801277 |
| diethyl 4-nitrobenzylidene malonate |
| E Param.: -17.67 | | Chem. Eur. J. 2008, 14, 9675-9682
10.1002/chem.200801277 |
| diethyl 4-cyano-benzylidene malonate |
| E Param.: -18.06 | | Chem. Eur. J. 2008, 14, 9675-9682
10.1002/chem.200801277 |
| diethyl 3-chloro-benzylidene malonate |
| E Param.: -18.98 | | Chem. Eur. J. 2008, 14, 9675-9682
10.1002/chem.200801277 |
| diethyl 4-methyl-benzylidene malonate |
| E Param.: -21.11 | | Chem. Eur. J. 2008, 14, 9675-9682
10.1002/chem.200801277 |
| diethyl 4-methoxy-benzylidene malonate |
| E Param.: -21.47 | | Chem. Eur. J. 2008, 14, 9675-9682
10.1002/chem.200801277 |
| diethyl 4-(dimethylamino)benzylidene malonate |
| E Param.: -23.10 | | Chem. Eur. J. 2008, 14, 9675-9682
10.1002/chem.200801277 |
| diethyl 2-((1-methyl-1,2,3,4-tetrahydroquinolin-6-yl)methylene)malonate |
| E Param.: -23.40 | | Chem. Eur. J. 2008, 14, 9675-9682
10.1002/chem.200801277 |
C-Nucleophiles (572)
