Electrophiles

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Name	Solvent	Reactivity Parameters	Reference (title or year)
2-cinnamoyl-3-methyl-1-(perfluorophenyl)-1H-imidazol-3-ium	DMSO	E Param.: -10.09	Top. Catal. 2018, 61, 585-590 10.1007/s11244-018-0[...]
2-methylcyclohexenone	DMSO	E Param.: -27.50	Chem. Sci. 2021, 12, 4850-4865 10.1039/D0SC06628A
2-methylcyclopentenone	DMSO	E Param.: -22.10	Chem. Sci. 2021, 12, 4850-4865 10.1039/D0SC06628A
2-phenyl-1,3-dithianylium ion		E Param.: -6.43	Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c
2-phenyl-1,3-dithiolan-2-ylium ion		E Param.: -5.91	Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c
2-phenylethene-1-sulfonyl fluoride	DMSO	E Param.: -16.63	Angew. Chem. Int. Ed. 2016, 55, 12664-12667 10.1002/anie.201601875
3,6-dinitro-1-tosyl-1H-indole		E Param.: -12.90	Chem. Commun. 2021, 57, 10071-10074 10.1039/d1cc04074j
3-(4-(dimethylamino)benzylidene)-1-methyl-3H-indol-1-ium ion		E Param.: -6.26	J. Org. Chem. 2015, 80, 8643-8656 10.1021/acs.joc.5b01298
3-(4-methoxybenzylidene)-1-methyl-3H-indol-1-ium iom		E Param.: -3.02	J. Org. Chem. 2015, 80, 8643-8656 10.1021/acs.joc.5b01298
3-(trimethylsilyl)propyn-1-ylium-Co2(CO)6		E Param.: -1.60	Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c
3-benzylidene-1-methyl-3H-indol-1-ium ion		E Param.: -1.80	J. Org. Chem. 2015, 80, 8643-8656 10.1021/acs.joc.5b01298
3-chloro-benzaldehyde (in DMSO)	DMSO		J. Am. Chem. Soc. 2011, 133, 8240-8251 10.1021/ja200820m
3-fluoro-benzaldehyde (in DMSO)	DMSO		J. Am. Chem. Soc. 2011, 133, 8240-8251 10.1021/ja200820m
3-methoxy-benzaldehyde (in DMSO)	DMSO		J. Am. Chem. Soc. 2011, 133, 8240-8251 10.1021/ja200820m
3-methylcyclohexenone	DMSO	E Param.: -29.60	Chem. Sci. 2021, 12, 4850-4865 10.1039/D0SC06628A
3-methylcyclopentenone	DMSO	E Param.: -28.90	Chem. Sci. 2021, 12, 4850-4865 10.1039/D0SC06628A
3-methylenedihydrofuranone	DMSO	E Param.: -19.40	Chem. Sci. 2021, 12, 4850-4865 10.1039/D0SC06628A
3-methylenetetrahydropyran-2-one	DMSO	E Param.: -19.50	Chem. Sci. 2021, 12, 4850-4865 10.1039/D0SC06628A
3-nitro-1-tosyl-1H-indole		E Param.: -14.87	Chem. Commun. 2021, 57, 10071-10074 10.1039/d1cc04074j
3-phenylpropyn-1-ylium-Co2(CO)6		E Param.: -1.58	Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c
4,6-dinitrobenzofurazan		E Param.: -5.46	J. Org. Chem. 2005, 70, 6242-6253 10.1021/jo0505526
4,6-dinitrobenzofuroxan		E Param.: -5.06	J. Org. Chem. 2006, 71, 9088-9095 10.1021/jo0614339
4,6-dinitrotetrazolopyridine		E Param.: -4.67	J. Org. Chem. 2005, 70, 6242-6253 10.1021/jo0505526
4-(2,2-bis(phenylsulfonyl)vinyl)-N,N-dimethylaniline	DMSO	E Param.: -16.53	Chem. Asian J. 2012, 7, 1401-1407 10.1002/asia.201101046
4-aza-6-nitrobenzofuroxan		E Param.: -5.86	J. Org. Chem. 2005, 70, 6242-6253 10.1021/jo0505526
4-bromo-3-nitro-1-tosyl-1H-indole		E Param.: -14.60	Chem. Commun. 2021, 57, 10071-10074 10.1039/d1cc04074j
4-bromo-<i>trans-beta</i>-nitrostyrene		E Param.: -13.37	J. Org. Chem. 2011, 76, 9370-9378 10.1021/jo201678u
4-chlorobenzaldehyde-boron trichloride complex		E Param.: 1.44	Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c
4-cyano-6-nitro-benzofuroxane		E Param.: -6.41	J. Org. Chem. 2005, 70, 6242-6253 10.1021/jo0505526
4-cyano-<i>trans-beta</i>-nitrostyrene		E Param.: -12.61	J. Org. Chem. 2011, 76, 9370-9378 10.1021/jo201678u
4-fluoro-benzaldehyde (in DMSO)	DMSO		J. Am. Chem. Soc. 2011, 133, 8240-8251 10.1021/ja200820m
4-methoxy-<i>trans-beta</i>-nitrostyrene		E Param.: -14.70	J. Org. Chem. 2011, 76, 9370-9378 10.1021/jo201678u
4-methyl-<i>trans-beta</i>-nitrostyrene		E Param.: -14.23	J. Org. Chem. 2011, 76, 9370-9378 10.1021/jo201678u
4-nitro-6-(trifluoromethylsulfonyl)benzofuroxan		E Param.: -4.91	J. Org. Chem. 2005, 70, 6242-6253 10.1021/jo0505526
4-nitro-<i>trans-beta</i>-nitrostyrene		E Param.: -12.37	J. Org. Chem. 2011, 76, 9370-9378 10.1021/jo201678u
4-nitrobenzodifuroxan (NBDF)		E Param.: -6.15	Chem. Eur. J. 2007, 13, 8317-8324 10.1002/chem.200700676
4-phenylbut-3-yn-2-one		E Param.: -16.90	Angew. Chem. Int. Ed. 2019, 58, 17704-17708 10.1002/anie.201909803
5,7,7-trichloro-8(7H)-quinolinone	MeCN	E Param.: -10.48	Org. Lett. 2010, 12, 2238-2241 10.1021/ol100592j
5-methoxyfuroxano[3,4-d]pyrimidine		E Param.: -8.37	J. Phys. Org. Chem. 2003, 16, 431-437 10.1002/poc.606
6-cyano-4-nitrobenzofuroxan		E Param.: -7.01	J. Org. Chem. 2005, 70, 6242-6253 10.1021/jo0505526
6-nitro-tetrazolo[1,5a]pyridine		E Param.: -9.05	J. Org. Chem. 2005, 70, 6242-6253 10.1021/jo0505526
9-(4-(dimethylamino)phenyl)-9H-fluoren-9-ylium	dichloromethane	E Param.: -4.51	Chem. Eur. J. 2017, 23, 623-630 10.1002/chem.201603963
9-(4-methoxyphenyl)-9H-fluoren-9-ylium	dichloromethane	E Param.: 0.85	Chem. Eur. J. 2017, 23, 623-630 10.1002/chem.201603963
9-phenyl-9H-fluoren-9-ylium	dichloromethane	E Param.: 2.41	Chem. Eur. J. 2017, 23, 623-630 10.1002/chem.201603963
<i>trans-beta</i>-nitrostyrene		E Param.: -13.85	J. Org. Chem. 2011, 76, 9370-9378 10.1021/jo201678u
acrylonitrile (in DMSO)	DMSO	E Param.: -19.05	J. Am. Chem. Soc. 2017, 139, 13318-13329 10.1021/jacs.7b05106
ani(Br)2QM		E Param.: -8.63	Angew. Chem. Int. Ed. 2002, 41, 91-95 10.1002/1521-3773(20[...]
ani(Ph)2QM		E Param.: -12.18	Angew. Chem. Int. Ed. 2002, 41, 91-95 10.1002/1521-3773(20[...]
ani(Ph)CH+		E Param.: 2.11	J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y
ani(pop)CH+		E Param.: 0.61	J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y