| 2,6-di-tert.butyl-4-(3,5-difluorobenzylidene)cyclohexa-2,5-dienone |
| E Param.: -14.50 |  | Eur. J. Org. Chem. 2009, , 3203-3211
10.1002/ejoc.200900299 |
| ((2-(2-iodophenyl)propan-2-yl)oxy)(trifluoromethyl)sulfane |
| E Param.: -14.52 | | Angew. Chem. Int. Ed. 2018, 57, 12690-12695
10.1002/anie.201805859 |
| 2-(4-methoxybenzylidene)-1,3-dithiane 1,1,3,3-tetraoxide |
DMSO | E Param.: -14.55 | | Chem. Asian J. 2012, 7, 1401-1407
10.1002/asia.201101046 |
| 4-bromo-3-nitro-1-tosyl-1H-indole |
| E Param.: -14.60 | | Chem. Commun. 2021, 57, 10071-10074
10.1039/d1cc04074j |
| jul-indan-1,3-dione |
| E Param.: -14.68 | | Org. Biomol. Chem. 2007, 5, 3020-3026
10.1039/b708025e |
| 4-methoxy-<i>trans-beta</i>-nitrostyrene |
| E Param.: -14.70 | | J. Org. Chem. 2011, 76, 9370-9378
10.1021/jo201678u |
| (E)-6-(4-methylbenzylidene)benzo[d][1,3]dioxol-5(6H)-one |
| E Param.: -14.85 | | Chem. Eur. J. 2024, , e202403785
10.1002/chem.202403785 |
| 3-nitro-1-tosyl-1H-indole |
| E Param.: -14.87 | | Chem. Commun. 2021, 57, 10071-10074
10.1039/d1cc04074j |
| 1,2-diaza-1,3-diene 1e |
MeOH | E Param.: -14.90 | | Chem. Eur. J. 2010, 16, 12008-12016
10.1002/chem.201000828 |
| 1,2-diaza-1,3-diene 1c |
DMSO | E Param.: -14.91 | | Chem. Eur. J. 2010, 16, 12008-12016
10.1002/chem.201000828 |
| 2,6-di-tert.butyl-4-(3-fluorobenzylidene)cyclohexa-2,5-dienone |
| E Param.: -15.03 | | Eur. J. Org. Chem. 2009, , 3203-3211
10.1002/ejoc.200900299 |
| (E)-N-(4-(dimethylamino)benzylidene)-4-methylbenzenesulfonamide (in DMSO) |
DMSO | E Param.: -15.09 | | J. Am. Chem. Soc. 2011, 133, 8240-8251
10.1021/ja200820m |
| (E)-6-(4-methoxybenzylidene)benzo[d][1,3]dioxol-5(6H)-one |
| E Param.: -15.20 | | Chem. Eur. J. 2024, , e202403785
10.1002/chem.202403785 |
| 1-phenylprop-2-en-1-one (in DMSO) |
DMSO | E Param.: -15.25 | | J. Am. Chem. Soc. 2017, 139, 13318-13329
10.1021/jacs.7b05106 |
| 1,2-diaza-1,3-diene 1f |
MeOH | E Param.: -15.30 | | Chem. Eur. J. 2010, 16, 12008-12016
10.1002/chem.201000828 |
| 1,2-diaza-1,3-diene 1d |
DMSO | E Param.: -15.38 | | Chem. Eur. J. 2010, 16, 12008-12016
10.1002/chem.201000828 |
| phenyl isocyanate |
MeCN | E Param.: -15.38 | | J. Am. Chem. Soc. 2020, 142, 8383-8402
10.1021/jacs.0c01960 |
| (E)-6-((1-methyl-1H-indol-2-yl)methylene)benzo[d][1,3]dioxol-5(6H)-one |
| E Param.: -15.55 | | Org. Biomol. Chem. 2024, , accepted
10.1039/D4OB01855A |
| 1-methylsulfanylpropan-2-one (in DMSO) |
DMSO | E Param.: -15.60 | | J. Am. Chem. Soc. 2018, 140, 5500-5515
10.1021/jacs.8b01657 |
| fumaronitrile |
DMSO | E Param.: -15.71 | | Eur. J. Org. Chem. 2014, , 2956-2963
10.1002/ejoc.201301779 |
| (E)-6-(furan-2-ylmethylene)benzo[d][1,3]dioxol-5(6H)-one |
| E Param.: -15.73 | | Org. Biomol. Chem. 2024, , accepted
10.1039/D4OB01855A |
| tol(t-Bu)2QM |
| E Param.: -15.83 | | Angew. Chem. Int. Ed. 2002, 41, 91-95
10.1002/1521-3773(20[...] |
| (E)-N-benzylidene-P,P-diphenylphosphinic amide |
DMSO | E Param.: -15.89 | | J. Am. Chem. Soc. 2011, 133, 8240-8251
10.1021/ja200820m |
| p-nitrophenyl isothiocyanate |
DMSO | E Param.: -15.89 | | J. Am. Chem. Soc. 2020, 142, 8383-8402
10.1021/jacs.0c01960 |
| (E)-6-((E)-3-phenylallylidene)benzo[d][1,3]dioxol-5(6H)-one |
| E Param.: -16.00 | | Org. Biomol. Chem. 2024, , accepted
10.1039/D4OB01855A |
| (E)-6-(4-(dimethylamino)benzylidene)benzo[d][1,3]dioxol-5(6H)-one |
| E Param.: -16.07 | | Chem. Eur. J. 2024, , e202403785
10.1002/chem.202403785 |
| ani(t-Bu)2QM |
| E Param.: -16.11 | | Angew. Chem. Int. Ed. 2002, 41, 91-95
10.1002/1521-3773(20[...] |
| 2,5-dichloroquinone (C-Cl) |
| E Param.: -16.11 | | J. Am. Chem. Soc. 2014, 136, 11499-11512
10.1021/ja505613b |
| p-quinone (C-H) |
| E Param.: -16.19 | | J. Am. Chem. Soc. 2014, 136, 11499-11512
10.1021/ja505613b |
| (E)-2,6-di-tert-butyl-4-(3-(4-nitrophenyl)allylidene)cyclohexa-2,5-dien-1-one |
DMSO | E Param.: -16.25 | | Org. Lett. 2020, 22, 2182-2186
10.1021/acs.orglett.[...] |
| 2,6-dimethyl-4-(4-(dimethylamino)benzylidene)cyclohexa-2,5-dienone |
| E Param.: -16.36 | | Eur. J. Org. Chem. 2009, , 3203-3211
10.1002/ejoc.200900299 |
| 2,6-dimethoxy-4-(4-methoxybenzylidene)cyclohexa-2,5-dienone |
| E Param.: -16.38 | | Eur. J. Org. Chem. 2009, , 3203-3211
10.1002/ejoc.200900299 |
| 4-(2,2-bis(phenylsulfonyl)vinyl)-N,N-dimethylaniline |
DMSO | E Param.: -16.53 | | Chem. Asian J. 2012, 7, 1401-1407
10.1002/asia.201101046 |
| butynone |
| E Param.: -16.60 |  | Angew. Chem. Int. Ed. 2019, 58, 17704-17708
10.1002/anie.201909803 |
| 2-phenylethene-1-sulfonyl fluoride |
DMSO | E Param.: -16.63 | | Angew. Chem. Int. Ed. 2016, 55, 12664-12667
10.1002/anie.201601875 |
| but-3-en-2-one (in DMSO) |
DMSO | E Param.: -16.76 | | J. Am. Chem. Soc. 2017, 139, 13318-13329
10.1021/jacs.7b05106 |
| E)-2,6-di-tert-butyl-4-(3-(4-chlorophenyl)allylidene)cyclohexa-2,5-dien-1-one |
DMSO | E Param.: -16.84 | | Org. Lett. 2020, 22, 2182-2186
10.1021/acs.orglett.[...] |
| thian-4-one (in DMSO) |
DMSO | E Param.: -16.90 | | J. Am. Chem. Soc. 2018, 140, 5500-5515
10.1021/jacs.8b01657 |
| 4-phenylbut-3-yn-2-one |
| E Param.: -16.90 | | Angew. Chem. Int. Ed. 2019, 58, 17704-17708
10.1002/anie.201909803 |
| (E)-2,6-di-tert-butyl-4-(3-phenylallylidene)cyclohexa-2,5-dien-1-one |
DMSO | E Param.: -17.00 | | Org. Lett. 2020, 22, 2182-2186
10.1021/acs.orglett.[...] |
| (E)-6-((1-methyl-1H-pyrrol-2-yl)methylene)benzo[d][1,3]dioxol-5(6H)-one |
| E Param.: -17.03 | | Org. Biomol. Chem. 2024, , accepted
10.1039/D4OB01855A |
| 2,6-dimethoxy-4-(4-(dimethylamino)benzylidene)cyclohexa-2,5-dienone |
| E Param.: -17.18 | | Eur. J. Org. Chem. 2009, , 3203-3211
10.1002/ejoc.200900299 |
| dma(t-Bu)2QM |
| E Param.: -17.29 | | Angew. Chem. Int. Ed. 2002, 41, 91-95
10.1002/1521-3773(20[...] |
| bh 6m |
| E Param.: -17.30 | | Chem. Eur. J. 2010, 16, 1365-1371
10.1002/chem.200902487 |
| (E)-3-(4-nitro-phenyl)-1-phenyl-prop-2-en-1-one (in DMSO) |
DMSO | E Param.: -17.33 | | J. Am. Chem. Soc. 2011, 133, 8240-8251
10.1021/ja200820m |
| (E)-2,6-di-tert-butyl-4-(3-(4-methoxyphenyl)allylidene)cyclohexa-2,5-dien-1-one |
DMSO | E Param.: -17.42 | | Org. Lett. 2020, 22, 2182-2186
10.1021/acs.orglett.[...] |
| cyclobutanone (in DMSO) |
DMSO | E Param.: -17.50 | | J. Am. Chem. Soc. 2018, 140, 5500-5515
10.1021/jacs.8b01657 |
| (E)-3-(4-cyano-phenyl)-1-phenyl-prop-2-en-1-one (in DMSO) |
DMSO | E Param.: -17.64 | | J. Am. Chem. Soc. 2011, 133, 8240-8251
10.1021/ja200820m |
| diethyl 4-nitrobenzylidene malonate |
| E Param.: -17.67 | | Chem. Eur. J. 2008, 14, 9675-9682
10.1002/chem.200801277 |
| carbon disulfide |
DMSO | E Param.: -17.70 | | J. Am. Chem. Soc. 2020, 142, 8383-8402
10.1021/jacs.0c01960 |
C-Nucleophiles (572)
