Electrophiles

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Name	Solvent	Reactivity Parameters	Reference (title or year)
o-chloranil (C-Cl)		E Param.: -12.02	J. Am. Chem. Soc. 2014, 136, 11499-11512 10.1021/ja505613b
3-benzylidene-1-methyl-3H-indol-1-ium ion		E Param.: -1.80	J. Org. Chem. 2015, 80, 8643-8656 10.1021/acs.joc.5b01298
1-methyl-3-(4-methylbenzylidene)-3H-indol-1-ium ion		E Param.: -2.19	J. Org. Chem. 2015, 80, 8643-8656 10.1021/acs.joc.5b01298
3-(4-methoxybenzylidene)-1-methyl-3H-indol-1-ium iom		E Param.: -3.02	J. Org. Chem. 2015, 80, 8643-8656 10.1021/acs.joc.5b01298
3-(4-(dimethylamino)benzylidene)-1-methyl-3H-indol-1-ium ion		E Param.: -6.26	J. Org. Chem. 2015, 80, 8643-8656 10.1021/acs.joc.5b01298
1-methyl-3-((julolidin-9-yl)methylene)-3H-indol-1-ium ion		E Param.: -7.79	J. Org. Chem. 2015, 80, 8643-8656 10.1021/acs.joc.5b01298
(E)-2-methyl-3-(4-methylbenzylidene)-3H-indol-1-ium ion		E Param.: -5.15	J. Org. Chem. 2015, 80, 8643-8656 10.1021/acs.joc.5b01298
(E)-1,2-dimethyl-3-(4-methylbenzylidene)-3H-indol-1-ium ion		E Param.: -5.05	J. Org. Chem. 2015, 80, 8643-8656 10.1021/acs.joc.5b01298
bis(1-methylindol-3-yl)methylium ion		E Param.: -5.99	J. Org. Chem. 2015, 80, 8643-8656 10.1021/acs.joc.5b01298
bis(5-methoxy-1-methylindol-3-yl)methylium ion		E Param.: -6.90	J. Org. Chem. 2015, 80, 8643-8656 10.1021/acs.joc.5b01298
bis(1,2-dimethylindol-3-yl)methylium ion		E Param.: -10.23	J. Org. Chem. 2015, 80, 8643-8656 10.1021/acs.joc.5b01298
ethenesulfonyl fluoride (ESF)	DMSO	E Param.: -12.09	Angew. Chem. Int. Ed. 2016, 55, 12664-12667 10.1002/anie.201601875
2-phenylethene-1-sulfonyl fluoride	DMSO	E Param.: -16.63	Angew. Chem. Int. Ed. 2016, 55, 12664-12667 10.1002/anie.201601875
9-phenyl-9H-fluoren-9-ylium	dichloromethane	E Param.: 2.41	Chem. Eur. J. 2017, 23, 623-630 10.1002/chem.201603963
9-(4-methoxyphenyl)-9H-fluoren-9-ylium	dichloromethane	E Param.: 0.85	Chem. Eur. J. 2017, 23, 623-630 10.1002/chem.201603963
9-(4-(dimethylamino)phenyl)-9H-fluoren-9-ylium	dichloromethane	E Param.: -4.51	Chem. Eur. J. 2017, 23, 623-630 10.1002/chem.201603963
(E)-4-phenylbut-3-en-2-one (in DMSO)	DMSO	E Param.: -23.01	J. Am. Chem. Soc. 2017, 139, 13318-13329 10.1021/jacs.7b05106
methyl prop-2-enoate (in DMSO)	DMSO	E Param.: -18.84	J. Am. Chem. Soc. 2017, 139, 13318-13329 10.1021/jacs.7b05106
ethyl prop-2-enoate (in DMSO)	DMSO	E Param.: -19.07	J. Am. Chem. Soc. 2017, 139, 13318-13329 10.1021/jacs.7b05106
tert-butyl prop-2-enoate (in DMSO)	DMSO	E Param.: -20.22	J. Am. Chem. Soc. 2017, 139, 13318-13329 10.1021/jacs.7b05106
N,N-dimethylprop-2-enamide (in DMSO)	DMSO	E Param.: -23.54	J. Am. Chem. Soc. 2017, 139, 13318-13329 10.1021/jacs.7b05106
ethenylsulfonylbenzene (in DMSO)	DMSO	E Param.: -18.36	J. Am. Chem. Soc. 2017, 139, 13318-13329 10.1021/jacs.7b05106
acrylonitrile (in DMSO)	DMSO	E Param.: -19.05	J. Am. Chem. Soc. 2017, 139, 13318-13329 10.1021/jacs.7b05106
but-3-en-2-one (in DMSO)	DMSO	E Param.: -16.76	J. Am. Chem. Soc. 2017, 139, 13318-13329 10.1021/jacs.7b05106
1-phenylprop-2-en-1-one (in DMSO)	DMSO	E Param.: -15.25	J. Am. Chem. Soc. 2017, 139, 13318-13329 10.1021/jacs.7b05106
2-cinnamoyl-3-methyl-1-(perfluorophenyl)-1H-imidazol-3-ium	DMSO	E Param.: -10.09	Top. Catal. 2018, 61, 585-590 10.1007/s11244-018-0[...]
1-(tert-butyl)-2-cinnamoyl-3-methyl-1H-imidazol-3-ium	DMSO	E Param.: -11.80	Top. Catal. 2018, 61, 585-590 10.1007/s11244-018-0[...]
2-cinnamoyl-1-mesityl-3-methyl-1H-imidazol-3-ium	DMSO	E Param.: -11.48	Top. Catal. 2018, 61, 585-590 10.1007/s11244-018-0[...]
2-cinnamoyl-1-(4-methoxyphenyl)-3-methyl-1H-imidazol-3-ium	DMSO	E Param.: -11.79	Top. Catal. 2018, 61, 585-590 10.1007/s11244-018-0[...]
2-cinnamoyl-1-(2,6-dimethoxyphenyl)-3-methyl-1H-imidazol-3-ium	DMSO	E Param.: -12.02	Top. Catal. 2018, 61, 585-590 10.1007/s11244-018-0[...]
N-(phenylsulfonyl)-N-((trifluoromethyl)thio)benzenesulfonamide		E Param.: -6.06	Angew. Chem. Int. Ed. 2018, 57, 12690-12695 10.1002/anie.201805859
N-fluoro-2,4,6-trimethylpyridinium tetrafluoroborate		E Param.: -10.46	J. Am. Chem. Soc. 2018, 140, 11474-11486 10.1021/jacs.8b07147
N-fluoro-2,6-dichloropyridinium tetrafluoroborate		E Param.: -5.29	J. Am. Chem. Soc. 2018, 140, 11474-11486 10.1021/jacs.8b07147
Selectfluor		E Param.: -5.20	J. Am. Chem. Soc. 2018, 140, 11474-11486 10.1021/jacs.8b07147
NFSI	MeCN	E Param.: -8.44	J. Am. Chem. Soc. 2018, 140, 11474-11486 10.1021/jacs.8b07147
N-fluoropyridinium tetrafluoroborate		E Param.: -9.89	J. Am. Chem. Soc. 2018, 140, 11474-11486 10.1021/jacs.8b07147
N-(trifluoromethyl)thio)phthalimide		E Param.: -11.92	Angew. Chem. Int. Ed. 2018, 57, 12690-12695 10.1002/anie.201805859
N-(trifluoromethyl)thio)saccharin		E Param.: -6.48	Angew. Chem. Int. Ed. 2018, 57, 12690-12695 10.1002/anie.201805859
N-(trifluoromethyl)thio)succinimide		E Param.: -12.56	Angew. Chem. Int. Ed. 2018, 57, 12690-12695 10.1002/anie.201805859
N-(difluoromethyl)thio)phthalimide		E Param.: -11.86	Angew. Chem. Int. Ed. 2018, 57, 12690-12695 10.1002/anie.201805859
N-methyl-N-((trifluoromethyl)thio)-p-toluenesulfonamide		E Param.: -13.44	Angew. Chem. Int. Ed. 2018, 57, 12690-12695 10.1002/anie.201805859
((2-phenylpropan-2-yl)oxy)(trifluoromethyl)sulfane		E Param.: -13.77	Angew. Chem. Int. Ed. 2018, 57, 12690-12695 10.1002/anie.201805859
((2-(2-iodophenyl)propan-2-yl)oxy)(trifluoromethyl)sulfane		E Param.: -14.52	Angew. Chem. Int. Ed. 2018, 57, 12690-12695 10.1002/anie.201805859
2-methylcyclopentenone	DMSO	E Param.: -22.10	Chem. Sci. 2021, 12, 4850-4865 10.1039/D0SC06628A
cyclopentenone	DMSO	E Param.: -20.60	Chem. Sci. 2021, 12, 4850-4865 10.1039/D0SC06628A
furan-2(5H)-one	DMSO	E Param.: -20.70	Chem. Sci. 2021, 12, 4850-4865 10.1039/D0SC06628A
cyclohexenone	DMSO	E Param.: -22.10	Chem. Sci. 2021, 12, 4850-4865 10.1039/D0SC06628A
3-methylenetetrahydropyran-2-one	DMSO	E Param.: -19.50	Chem. Sci. 2021, 12, 4850-4865 10.1039/D0SC06628A
3-methylenedihydrofuranone	DMSO	E Param.: -19.40	Chem. Sci. 2021, 12, 4850-4865 10.1039/D0SC06628A
(E)-2,6-di-tert-butyl-4-(3-phenylallylidene)cyclohexa-2,5-dien-1-one	DMSO	E Param.: -17.00	Org. Lett. 2020, 22, 2182-2186 10.1021/acs.orglett.[...]