Carbanions
| Name | Solvent |
Reactivity Parameters |
Classification |
Reference (title or year) |
|---|---|---|---|---|
anion of Meldrums acid (in DMSO)   |
DMSO | N Param.: 13.91 sN Param.: 0.86 |
 |
Angew. Chem. Int. Ed. 2002, 41, 91-95 10.1002/1521-3773(20[...] |
anion of dimedone (in DMSO)  |
DMSO | N Param.: 16.27 sN Param.: 0.77 |
|
Angew. Chem. Int. Ed. 2002, 41, 91-95 10.1002/1521-3773(20[...] |
anion of acetylacetone (in DMSO)  |
DMSO | N Param.: 17.64 sN Param.: 0.73 |
|
Angew. Chem. Int. Ed. 2002, 41, 91-95 10.1002/1521-3773(20[...] |
anion of ethyl acetylacetate (in DMSO)  |
DMSO | N Param.: 18.82 sN Param.: 0.69 |
|
Angew. Chem. Int. Ed. 2002, 41, 91-95 10.1002/1521-3773(20[...] |
anion of malononitrile (in DMSO)  |
DMSO | N Param.: 19.36 sN Param.: 0.67 |
|
Angew. Chem. Int. Ed. 2002, 41, 91-95 10.1002/1521-3773(20[...] |
anion of ethyl cyanoacetate (in DMSO)  |
DMSO | N Param.: 19.62 sN Param.: 0.67 |
|
Angew. Chem. Int. Ed. 2002, 41, 91-95 10.1002/1521-3773(20[...] |
anion of diethyl malonate (in DMSO)  |
DMSO | N Param.: 20.22 sN Param.: 0.65 |
|
Angew. Chem. Int. Ed. 2002, 41, 91-95 10.1002/1521-3773(20[...] |
anion of nitroethane (in DMSO)  |
DMSO | N Param.: 21.54 sN Param.: 0.62 |
|
J. Org. Chem. 2003, 68, 6880-6886 10.1021/jo0344182 |
anion of Meldrum's acid (in water)  |
water | N Param.: 12.06 sN Param.: 0.66 |
|
J. Am. Chem. Soc. 2003, 125, 12980-12986 10.1021/ja036838e |
anion of dimedone (in water)  |
water | N Param.: 11.77 sN Param.: 0.63 |
|
J. Am. Chem. Soc. 2003, 125, 12980-12986 10.1021/ja036838e |
anion of acetylacetone (in water)  |
water | N Param.: 13.73 sN Param.: 0.64 |
|
J. Am. Chem. Soc. 2003, 125, 12980-12986 10.1021/ja036838e |
anion of ethyl acetylacetate (in water)  |
water | N Param.: 15.99 sN Param.: 0.62 |
|
J. Am. Chem. Soc. 2003, 125, 12980-12986 10.1021/ja036838e |
anion of malononitrile (in water)  |
water | N Param.: 19.50 sN Param.: 0.55 |
|
J. Am. Chem. Soc. 2003, 125, 12980-12986 10.1021/ja036838e |
anion of ethyl cyanoacetate (in water)  |
water | N Param.: 15.57 sN Param.: 0.58 |
|
J. Am. Chem. Soc. 2003, 125, 12980-12986 10.1021/ja036838e |
anion of diethyl malonate (in water)  |
water | N Param.: 16.15 sN Param.: 0.66 |
|
J. Am. Chem. Soc. 2003, 125, 12980-12986 10.1021/ja036838e |
anion of diethyl methylmalonate (in DMSO)  |
DMSO | N Param.: 21.13 sN Param.: 0.68 |
|
J. Am. Chem. Soc. 2003, 125, 12980-12986 10.1021/ja036838e |
anion of diethyl methylmalonate (in water)  |
water | N Param.: 17.68 sN Param.: 0.50 |
|
J. Am. Chem. Soc. 2003, 125, 12980-12986 10.1021/ja036838e |
anion of 3-methyl acetylacetone (in DMSO)  |
DMSO | N Param.: 18.38 sN Param.: 0.72 |
|
J. Am. Chem. Soc. 2003, 125, 12980-12986 10.1021/ja036838e |
anion of 3-methyl acetylacetone (in water)  |
water | N Param.: 14.33 sN Param.: 0.69 |
|
J. Am. Chem. Soc. 2003, 125, 12980-12986 10.1021/ja036838e |
anion of nitroethane (in water)  |
water | N Param.: 11.25 sN Param.: 0.52 |
|
J. Org. Chem. 2004, 69, 7565-7576 10.1021/jo048773j |
anion of nitromethane (in water)  |
water | N Param.: 12.06 sN Param.: 0.53 |
|
J. Org. Chem. 2004, 69, 7565-7576 10.1021/jo048773j |
anion of nitromethane (in DMSO)  |
DMSO | N Param.: 20.71 sN Param.: 0.60 |
|
J. Org. Chem. 2004, 69, 7565-7576 10.1021/jo048773j |
anion of 2-nitropropane (in DMSO)  |
DMSO | N Param.: 20.61 sN Param.: 0.69 |
|
J. Org. Chem. 2004, 69, 7565-7576 10.1021/jo048773j |
anion of 2-nitropropane (in water)  |
water | N Param.: 10.69 sN Param.: 0.56 |
|
J. Org. Chem. 2004, 69, 7565-7576 10.1021/jo048773j |
anion of phenylnitromethane (in H2O)  |
water | N Param.: 12.05 sN Param.: 0.53 |
|
J. Org. Chem. 2004, 69, 7565-7576 10.1021/jo048773j |
anion of phenylnitromethane (in DMSO)  |
DMSO | N Param.: 18.29 sN Param.: 0.71 |
|
J. Org. Chem. 2004, 69, 7565-7576 10.1021/jo048773j |
anion of p-tolylnitromethane (in water)  |
water | N Param.: 13.09 sN Param.: 0.50 |
|
J. Org. Chem. 2004, 69, 7565-7576 10.1021/jo048773j |
anion of p-tolylnitromethane (in DMSO)  |
DMSO | N Param.: 18.31 sN Param.: 0.76 |
|
J. Org. Chem. 2004, 69, 7565-7576 10.1021/jo048773j |
anion of (4-nitrophenyl)nitromethane (in water)  |
water | N Param.: 13.58 sN Param.: 0.52 |
|
J. Org. Chem. 2004, 69, 7565-7576 10.1021/jo048773j |
anion of (4-nitrophenyl)nitromethane (in DMSO)  |
DMSO | N Param.: 16.29 sN Param.: 0.75 |
|
J. Org. Chem. 2004, 69, 7565-7576 10.1021/jo048773j |
anion of (3-nitrophenyl)nitromethane (in water)  |
water | N Param.: 14.25 sN Param.: 0.46 |
|
J. Org. Chem. 2004, 69, 7565-7576 10.1021/jo048773j |
anion of (3-nitrophenyl)nitromethane (in DMSO)  |
DMSO | N Param.: 18.06 sN Param.: 0.71 |
|
J. Org. Chem. 2004, 69, 7565-7576 10.1021/jo048773j |
anion of (4-cyanophenyl)nitromethane (in water)  |
water | N Param.: 13.23 sN Param.: 0.52 |
|
J. Org. Chem. 2004, 69, 7565-7576 10.1021/jo048773j |
anion of (4-cyanophenyl)nitromethane (in DMSO)  |
DMSO | N Param.: 16.96 sN Param.: 0.73 |
|
J. Org. Chem. 2004, 69, 7565-7576 10.1021/jo048773j |
cyanide (in MeCN)  |
MeCN | N Param.: 16.27 sN Param.: 0.70 |
|
Angew. Chem. Int. Ed. 2005, 44, 142-145 10.1002/anie.200461640 |
anion of nitromethane (in 91M9AN)  |
MeOH-MeCN mix | N Param.: 14.02 sN Param.: 0.61 |
|
Eur. J. Org. Chem. 2006, , 2530-2537 10.1002/ejoc.200500769 |
anion of nitroethane (in 91M9AN)  |
MeOH-MeCN mix | N Param.: 13.41 sN Param.: 0.67 |
|
Eur. J. Org. Chem. 2006, , 2530-2537 10.1002/ejoc.200500769 |
anion of 2-nitropropane (in 91M9AN)  |
MeOH-MeCN mix | N Param.: 12.20 sN Param.: 0.71 |
|
Eur. J. Org. Chem. 2006, , 2530-2537 10.1002/ejoc.200500769 |
anion of phenylnitromethane (in 91M9AN)  |
MeOH-MeCN mix | N Param.: 12.51 sN Param.: 0.67 |
|
Eur. J. Org. Chem. 2006, , 2530-2537 10.1002/ejoc.200500769 |
anion of p-tolylnitromethane (in 91M9AN)  |
MeOH-MeCN mix | N Param.: 13.58 sN Param.: 0.64 |
|
Eur. J. Org. Chem. 2006, , 2530-2537 10.1002/ejoc.200500769 |
anion of (4-nitrophenyl)nitromethane (in 91M9AN)  |
MeOH-MeCN mix | N Param.: 14.05 sN Param.: 0.72 |
|
Eur. J. Org. Chem. 2006, , 2530-2537 10.1002/ejoc.200500769 |
anion of (3-nitrophenyl)nitromethane (in 91M9AN)  |
MeOH-MeCN mix | N Param.: 14.75 sN Param.: 0.71 |
|
Eur. J. Org. Chem. 2006, , 2530-2537 10.1002/ejoc.200500769 |
anion of (4-cyanophenyl)nitromethane (in 91M9AN)  |
MeOH-MeCN mix | N Param.: 13.92 sN Param.: 0.74 |
|
Eur. J. Org. Chem. 2006, , 2530-2537 10.1002/ejoc.200500769 |
anion of ethyl cyanoacetate (in 91M9AN)  |
MeOH-MeCN mix | N Param.: 18.59 sN Param.: 0.65 |
|
Eur. J. Org. Chem. 2006, , 2530-2537 10.1002/ejoc.200500769 |
anion of malononitrile (in 91M9AN)  |
MeOH-MeCN mix | N Param.: 18.21 sN Param.: 0.69 |
|
Eur. J. Org. Chem. 2006, , 2530-2537 10.1002/ejoc.200500769 |
anion of dimethyl malonate (in 91M9AN)  |
MeOH-MeCN mix | N Param.: 18.24 sN Param.: 0.64 |
|
Eur. J. Org. Chem. 2006, , 2530-2537 10.1002/ejoc.200500769 |
anion of 4-nitrobenzyl trifluoromethyl sulfone (in DMSO)  |
DMSO | N Param.: 14.49 sN Param.: 0.86 |
|
J. Am. Chem. Soc. 2007, 129, 9753-9761 10.1021/ja072135b |
anion of 4-cyanobenzyl trifluoromethyl sulfone (in DMSO)  |
DMSO | N Param.: 16.28 sN Param.: 0.75 |
|
J. Am. Chem. Soc. 2007, 129, 9753-9761 10.1021/ja072135b |
anion of 4-(trifluoromethyl)benzyl trifluoromethyl sulfone (in DMSO)  |
DMSO | N Param.: 17.33 sN Param.: 0.74 |
|
J. Am. Chem. Soc. 2007, 129, 9753-9761 10.1021/ja072135b |
anion of benzyl trifluoromethyl sulfone (in DMSO)  |
DMSO | N Param.: 18.67 sN Param.: 0.68 |
|
J. Am. Chem. Soc. 2007, 129, 9753-9761 10.1021/ja072135b |