Mayr's Database of Reactivity Parameters

H-B hydride donors

1 | 2 | 3 Found 23 molecules, displaying page 2 of 3 Results per page 10|50|100|all
Name Solvent Reactivity
Parameters
Classification Reference
(title or year)
borane-2,6-lutidine-complex
*
dichloromethane

N  Param.: 10.33

sN Param.: 0.75
*Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
borane-4-tBu-pyridine-complex
*
dichloromethane

N  Param.: 10.46

sN Param.: 0.75
*Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
borane-4-methoxypyridine-complex
*
dichloromethane

N  Param.: 11.01

sN Param.: 0.75
*Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
NaBH3(CN) (in DMSO)
CH3BN-*
DMSO

N  Param.: 11.52

sN Param.: 0.67
***Angew. Chem. Int. Ed. 2009, 48, 1958-1961
10.1002/anie.200804263
Me2 Imd boronate
*
dichloromethane

N  Param.: 11.88

sN Param.: 0.71
***Org. Lett. 2012, 14, 82-85
10.1021/ol202836p
tetrahydroborate ion (in water)
*
water

N  Param.: 12.10

sN Param.: 0.79
-Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
borane-DMAP-complex
*
dichloromethane

N  Param.: 12.44

sN Param.: 0.76
***Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
[H-B(2,6-F2C6H3)3]- [NEt4]+
*
MeCN

N  Param.: 13.97

sN Param.: 0.66
***Angew. Chem. Int. Ed. 2015, 54, 14508-14512
10.1002/anie.201507298
[H-B(2,4,6-F3C6H2)3]- [NEt4]+
*
MeCN

N  Param.: 14.13

sN Param.: 0.61
***Angew. Chem. Int. Ed. 2015, 54, 14508-14512
10.1002/anie.201507298
NaB(OAc)3H (in DMSO)
C6H10BO6-*
DMSO

N  Param.: 14.45

sN Param.: 0.76
***Angew. Chem. Int. Ed. 2009, 48, 1958-1961
10.1002/anie.200804263