O-Nucleophiles
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| Name | Solvent |
Reactivity Parameters |
Classification |
Reference (title or year) |
|---|---|---|---|---|
peroxybenzoate (in H2O)  |
water | N Param.: 18.57 sN Param.: 0.43 |  | Angew. Chem. Int. Ed. 2017, 56, 13279-13282 10.1002/anie.201707086 |
hypochlorite (in water) |
water | N Param.: 14.50 sN Param.: 0.58 | | Org. Lett. 2018, 20, 2816-2820 10.1021/acs.orglett.[...] |
hypobromite (in water) |
water | N Param.: 16.69 sN Param.: 0.46 | | Org. Lett. 2018, 20, 2816-2820 10.1021/acs.orglett.[...] |
bromite (in water) |
water | N Param.: 12.75 sN Param.: 0.59 | | Org. Lett. 2018, 20, 2816-2820 10.1021/acs.orglett.[...] |
peroxomonosulfate (in water) |
water | N Param.: 14.41 sN Param.: 0.60 | | Org. Lett. 2018, 20, 2816-2820 10.1021/acs.orglett.[...] |
beta-piperidinium-peroxypropionate |
water | N Param.: 13.94 sN Param.: 0.62 | | Eur. J. Org. Chem. 2018, , 6010-6017 10.1002/ejoc.201801158 |
peroxy-beta-alanate |
water | N Param.: 14.07 sN Param.: 0.56 | | Eur. J. Org. Chem. 2018, , 6010-6017 10.1002/ejoc.201801158 |
peroxy-GABA |
water | N Param.: 14.33 sN Param.: 0.57 | | Eur. J. Org. Chem. 2018, , 6010-6017 10.1002/ejoc.201801158 |
p-nitrophenolate (in DMSO) |
DMSO | N Param.: 14.32 sN Param.: 0.77 | | J. Org. Chem. 2019, 84, 8837-8858 10.1021/acs.joc.9b01485 |
p-nitrophenolate (in MeCN) |
MeCN | N Param.: 15.14 sN Param.: 0.82 | | J. Org. Chem. 2019, 84, 8837-8858 10.1021/acs.joc.9b01485 |
p-nitrophenolate (in DMF) |
DMF | N Param.: 15.05 sN Param.: 0.80 | | J. Org. Chem. 2019, 84, 8837-8858 10.1021/acs.joc.9b01485 |
o-nitrophenolate (in DMSO) |
DMSO | N Param.: 15.48 sN Param.: 0.71 | | J. Org. Chem. 2019, 84, 8837-8858 10.1021/acs.joc.9b01485 |
o-nitrophenolate (in MeCN) |
MeCN | N Param.: 15.83 sN Param.: 0.80 | | J. Org. Chem. 2019, 84, 8837-8858 10.1021/acs.joc.9b01485 |
o-nitrophenolate (in DMF) |
DMF | N Param.: 16.65 sN Param.: 0.70 | | J. Org. Chem. 2019, 84, 8837-8858 10.1021/acs.joc.9b01485 |
m-nitrophenolate (in DMSO) |
DMSO | N Param.: 21.29 sN Param.: 0.54 | | J. Org. Chem. 2019, 84, 8837-8858 10.1021/acs.joc.9b01485 |
m-nitrophenolate (in MeCN) |
MeCN | N Param.: 25.51 sN Param.: 0.43 | | J. Org. Chem. 2019, 84, 8837-8858 10.1021/acs.joc.9b01485 |
m-nitrophenolate (in DMF) |
DMF | N Param.: 22.41 sN Param.: 0.54 | | J. Org. Chem. 2019, 84, 8837-8858 10.1021/acs.joc.9b01485 |
p-cyanophenolate (in DMSO) |
DMSO | N Param.: 18.78 sN Param.: 0.57 | | J. Org. Chem. 2019, 84, 8837-8858 10.1021/acs.joc.9b01485 |
p-cyanophenolate (in DMF) |
DMF | N Param.: 17.85 sN Param.: 0.71 | | J. Org. Chem. 2019, 84, 8837-8858 10.1021/acs.joc.9b01485 |
o-(trifluoromethyl)phenolate (in DMSO) |
DMSO | N Param.: 18.47 sN Param.: 0.61 | | J. Org. Chem. 2019, 84, 8837-8858 10.1021/acs.joc.9b01485 |