Carbocations

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Name	Solvent	Reactivity Parameters	Reference (title or year)
PhCH=N+Me2 (in MeCN)	MeCN	E Param.: -9.27	J. Am. Chem. Soc. 2013, 135, 6579-6587 10.1021/ja401106x
pTolCH=N+CH2 (in MeCN)	MeCN	E Param.: -9.64	J. Am. Chem. Soc. 2013, 135, 6579-6587 10.1021/ja401106x
p-AniCH=N+Me2 (in MeCN)	MeCN	E Param.: -10.69	J. Am. Chem. Soc. 2013, 135, 6579-6587 10.1021/ja401106x
PhCH=N+(CH2)4 (in MeCN)	MeCN	E Param.: -9.35	J. Am. Chem. Soc. 2013, 135, 6579-6587 10.1021/ja401106x
PhCH=N+(CH2)5 (in MeCN)	MeCN	E Param.: -9.60	J. Am. Chem. Soc. 2013, 135, 6579-6587 10.1021/ja401106x
p-CF3-C6H4-CH=N+Me2 (in MeCN)	MeCN	E Param.: -8.34	J. Am. Chem. Soc. 2013, 135, 6579-6587 10.1021/ja401106x
(S,E)-2,2,3-trimethyl-4-oxo-5-((perfluorophenyl)methyl)-1-((E)-3-phenylallylidene)imidazolidin-1-ium	dichloromethane	E Param.: -6.00	Angew. Chem. Int. Ed. 2013, 52, 7967-7971 10.1002/anie.201301864
(S,E)-2,2,3-trimethyl-4-oxo-1-((E)-3-phenylallylidene)-5-(3,4,5-trimethoxybenzyl)imidazolidin-1-ium	dichloromethane	E Param.: -7.00	Angew. Chem. Int. Ed. 2013, 52, 7967-7971 10.1002/anie.201301864
(S,E)-5-benzyl-2,2,3-trimethyl-1-((E)-3-(4-nitrophenyl)allylidene)-4-oxoimidazolidin-1-ium	dichloromethane	E Param.: -5.90	Asian J. Org. Chem. 2014, 3, 550-555 10.1002/ajoc.201402009
(S,E)-5-benzyl-1-((E)-3-(4-cyanophenyl)allylidene)-2,2,3-trimethyl-4-oxoimidazolidin-1-ium	dichloromethane	E Param.: -6.00	Asian J. Org. Chem. 2014, 3, 550-555 10.1002/ajoc.201402009
(S,E)-5-benzyl-1-((E)-3-(4-(dimethylamino)phenyl)allylidene)-2,2,3-trimethyl-4-oxoimidazolidin-1-ium	dichloromethane	E Param.: -10.60	Asian J. Org. Chem. 2014, 3, 550-555 10.1002/ajoc.201402009
(S,E)-5-benzyl-2,2,3-trimethyl-4-oxo-1-((E)-3-(p-tolyl)allylidene)imidazolidin-1-ium	dichloromethane	E Param.: -7.20	Asian J. Org. Chem. 2014, 3, 550-555 10.1002/ajoc.201402009
(S,E)-5-benzyl-1-((E)-3-(4-methoxyphenyl)allylidene)-2,2,3-trimethyl-4-oxoimidazolidin-1-ium	dichloromethane	E Param.: -8.00	Asian J. Org. Chem. 2014, 3, 550-555 10.1002/ajoc.201402009
(S,E)-5-benzyl-2,2,3-trimethyl-1-((E)-3-(3-nitrophenyl)allylidene)-4-oxoimidazolidin-1-ium	dichloromethane	E Param.: -6.10	Asian J. Org. Chem. 2014, 3, 550-555 10.1002/ajoc.201402009
(S,E)-5-((1H-indol-3-yl)methyl)-2,2,3-trimethyl-4-oxo-1-((E)-3-phenylallylidene)imidazolidin-1-ium	dichloromethane	E Param.: -7.30	Asian J. Org. Chem. 2014, 3, 550-555 10.1002/ajoc.201402009
(2S,5S)-5-benzyl-3-methyl-4-oxo-1-(3-phenylallylidene)-2-((E)-styryl)imidazolidin-1-ium	dichloromethane	E Param.: -5.90	Asian J. Org. Chem. 2014, 3, 550-555 10.1002/ajoc.201402009
3-benzylidene-1-methyl-3H-indol-1-ium ion		E Param.: -1.80	J. Org. Chem. 2015, 80, 8643-8656 10.1021/acs.joc.5b01298
1-methyl-3-(4-methylbenzylidene)-3H-indol-1-ium ion		E Param.: -2.19	J. Org. Chem. 2015, 80, 8643-8656 10.1021/acs.joc.5b01298
3-(4-methoxybenzylidene)-1-methyl-3H-indol-1-ium iom		E Param.: -3.02	J. Org. Chem. 2015, 80, 8643-8656 10.1021/acs.joc.5b01298
3-(4-(dimethylamino)benzylidene)-1-methyl-3H-indol-1-ium ion		E Param.: -6.26	J. Org. Chem. 2015, 80, 8643-8656 10.1021/acs.joc.5b01298
1-methyl-3-((julolidin-9-yl)methylene)-3H-indol-1-ium ion		E Param.: -7.79	J. Org. Chem. 2015, 80, 8643-8656 10.1021/acs.joc.5b01298
(E)-2-methyl-3-(4-methylbenzylidene)-3H-indol-1-ium ion		E Param.: -5.15	J. Org. Chem. 2015, 80, 8643-8656 10.1021/acs.joc.5b01298
(E)-1,2-dimethyl-3-(4-methylbenzylidene)-3H-indol-1-ium ion		E Param.: -5.05	J. Org. Chem. 2015, 80, 8643-8656 10.1021/acs.joc.5b01298
(E)-3-benzylidene-1,2-dimethyl-3H-indol-1-ium ion		E Param.: -4.96	J. Org. Chem. 2015, 80, 8643-8656 10.1021/acs.joc.5b01298
bis(1-methylindol-3-yl)methylium ion		E Param.: -5.99	J. Org. Chem. 2015, 80, 8643-8656 10.1021/acs.joc.5b01298
bis(5-methoxy-1-methylindol-3-yl)methylium ion		E Param.: -6.90	J. Org. Chem. 2015, 80, 8643-8656 10.1021/acs.joc.5b01298
bis(1,2-dimethylindol-3-yl)methylium ion		E Param.: -10.23	J. Org. Chem. 2015, 80, 8643-8656 10.1021/acs.joc.5b01298
dibenzo[a,d]tropylium ion	dichloromethane	E Param.: -0.63	Liebigs Ann. 1995, , 2005-2009 10.1002/jlac.1995199[...]
(E)-2-(tert-butyl)-3-(4-methylbenzylidene)-3H-indol-1-ium	dichloromethane	E Param.: -5.06	Eur. J. Org. Chem. 2016, , 4050-4058 10.1002/ejoc.201600572
9-phenyl-9H-fluoren-9-ylium	dichloromethane	E Param.: 2.41	Chem. Eur. J. 2017, 23, 623-630 10.1002/chem.201603963
9-(4-methoxyphenyl)-9H-fluoren-9-ylium	dichloromethane	E Param.: 0.85	Chem. Eur. J. 2017, 23, 623-630 10.1002/chem.201603963
9-(4-(dimethylamino)phenyl)-9H-fluoren-9-ylium	dichloromethane	E Param.: -4.51	Chem. Eur. J. 2017, 23, 623-630 10.1002/chem.201603963
Me2C=C=N(+)Me2		E Param.: -2.80	Synthesis 2025, 57, 3251-3262 10.1055/a-2649-1999
Ph2C=C=N(+)Me2		E Param.: -1.90	Synthesis 2025, 57, 3251-3262 10.1055/a-2649-1999