Mayr's Database of Reactivity Parameters

Aldehydes

For reactivities of structurally related compounds go to: Electrophiles » C-Electrophiles » Aldehydes

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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
benzaldehyde-boron trichloride complex
*

E Param.: 1.12, Deviation: ±0.24

 *** Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
4-chlorobenzaldehyde-boron trichloride complex
*

E Param.: 1.44, Deviation: ±0.20

 *** Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
3-chloro-benzaldehyde (in DMSO)
C7H5ClO *
 DMSO - J. Am. Chem. Soc. 2011, 133, 8240-8251
10.1021/ja200820m
3-fluoro-benzaldehyde (in DMSO)
C7H5FO *
 DMSO - J. Am. Chem. Soc. 2011, 133, 8240-8251
10.1021/ja200820m
3-methoxy-benzaldehyde (in DMSO)
C8H8O2 *
 DMSO - J. Am. Chem. Soc. 2011, 133, 8240-8251
10.1021/ja200820m
4-fluoro-benzaldehyde (in DMSO)
C7H5FO *
 DMSO - J. Am. Chem. Soc. 2011, 133, 8240-8251
10.1021/ja200820m
benzaldehyde (in DMSO)
C7H6O *
 DMSO

E Param.: -12.90

 * J. Am. Chem. Soc. 2018, 140, 5500-5515
10.1021/jacs.8b01657
hexanal (in DMSO)
C6H12O *
 DMSO - J. Am. Chem. Soc. 2011, 133, 8240-8251
10.1021/ja200820m
butanal (in DMSO)
C4H8O *
 DMSO - J. Am. Chem. Soc. 2011, 133, 8240-8251
10.1021/ja200820m
cinnamaldehyde (in DMSO)
C9H8O *
 DMSO - J. Am. Chem. Soc. 2011, 133, 8240-8251
10.1021/ja200820m
p-nitro-cinnamaldehyde (in DMSO)
C9H7NO3 *
 DMSO - J. Am. Chem. Soc. 2011, 133, 8240-8251
10.1021/ja200820m