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Mayr's Database Of Reactivity Parameters: Searches
Mayr's Database of Reactivity Parameters

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77 | 78 | 79 | 80 | 81 | 82 | 83 | 84 | 85Found 1683 molecules, page 84 of 85
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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
2-(bis(trimethylsiloxy)amino)propene
C9H23NO2Si2*
 dichloromethane

N  Param.: 4.76

sN Param.: 0.86		***J. Org. Chem. 2001, 66, 3196-3200
10.1021/jo0015927
(bis(trimethylsiloxy)amino)styrene
C14H25NO2Si2*
 dichloromethane

N  Param.: 4.80

sN Param.: 0.86		*J. Org. Chem. 2001, 66, 3196-3200
10.1021/jo0015927
2-(bis(tert-butyldimethylsiloxy)amino)propene
C15H35NO2Si2*
 dichloromethane

N  Param.: 4.23

sN Param.: 0.93		***J. Org. Chem. 2001, 66, 3196-3200
10.1021/jo0015927
4-(bis(trimethylsiloxy)amino)pent-4-enoic acid methyl ester
C12H27NO4Si2*
 dichloromethane

N  Param.: 3.84

sN Param.: 0.87		***J. Org. Chem. 2001, 66, 3196-3200
10.1021/jo0015927
1-methylcyclohexene
C7H12*
 dichloromethane

N  Param.: 0.08

sN Param.: 1.15		*****J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y
2-methyl-but-2-ene
C5H10*
 dichloromethane

N  Param.: 0.65

sN Param.: 1.17		*****J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y
2-methylpropene (isobutylene)
C4H8*
 dichloromethane

N  Param.: 1.11

sN Param.: 0.98		*****J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y
1-methyl-4-vinyl-benzene
C9H10*
 dichloromethane

N  Param.: 1.70

sN Param.: 1.06		*****J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y
2-methyl-buta-1,3-diene (isoprene)
C5H8*
 dichloromethane

N  Param.: 1.10

sN Param.: 0.98		*****J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y
trimethyl(prenyl)silane
C8H18Si*
 dichloromethane

N  Param.: 0.90

sN Param.: 1.17		*****J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y
(2-methylallyl)triphenylgermane
C22H22Ge*
 dichloromethane

N  Param.: 4.67

sN Param.: 0.81		*****J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y
1-ethinylcyclohexenyl-Co2(CO)6
*
 dichloromethane

N  Param.: -0.44

sN Param.: 1.06		***J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y
4-(trimethylsilyl)but-1-en-3-ynyl-Co2(CO)6
*
 dichloromethane

N  Param.: -1.11

sN Param.: 0.92		***J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y
cyclohepta-1,3,5-trienyl-Fe(CO)3
*
 dichloromethane

N  Param.: 3.42

sN Param.: 0.94		***J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y
ani(pop)CH+
C20H17O2*

E Param.: 0.61

*****J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y
ani(Ph)CH+
C14H13O*

E Param.: 2.11

*****J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y
ani(tol)CH+
C15H15O*

E Param.: 1.48

*****J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y
pop(Ph)CH+
C19H15O*

E Param.: 2.90

*****J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y
fc(Ph)CH+
C17H15Fe*

E Param.: -2.64

*****J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y
3,3-dimethyl-2-(trimethylsiloxy)buten
C9H20OSi*
 dichloromethane

N  Param.: 3.78

sN Param.: 0.79		**J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y

News

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  • 01/30/25:
    Sesamol-derived ortho-quinone methides (o-QM) have been added (ChemEurJ 2024, e202403785 & OBC 2025, 23, 827-834)
  • 05/22/24:
    Lactone enolates have been added (JOC 2024, 89, 6915-6928).
  • 11/13/24:
    2-Methylene-1,2-dihydropyridines (2-pyNHOs) have been added (EurJOC 2024, 27, e202400373).
  • 05/21/24:
    Mesoionic pyridinium-derived N-heterocyclic olefins (py-mNHOs) have been added (Angew. Chem. Int. Ed. 2024, 63, e202318283).
  • 10/19/23:
    Enamines derived from 4-(alkylthio)-3-imidazolines and aldehydes have been added (ChemEurJ 2023, doi: 10.1002/chem.202302764).
  • 09/28/23:
    Mesoionic N-heterocyclic olefins (mNHOs) have been added (Angew. Chem. Int. Ed. 2023, 62, e202309790).
  • 07/05/23:
    S-Cyanomethylated imidazolidine-4-thione-derived enamines have been added (ChemComm 2023, 59, 8091).
  • 03/16/23:
    Cyclic alpha-diazo carbonyl compounds added (EurJOC 2023, 26, e202300005)
  • 01/30/23:
    NADH and NADPH reactivities (in water, pH 7) determined by Mayer and Moran have been added (OBC 2022, 21, 85-88).
  • 09/20/22:
    Alkenyl boronate nucleophilicity by Liu, Ready and co-workers has been added (JACS 2022, 144, 16118).
  • 01/30/23:
    Electrophilicities of diazo compounds in azo couplings (ChemEurJ 2022, 28, e202201376)
  • 01/30/23:
    Diazocyclopentadiene added (Synthesis 2023, 55, 354-358)
  • 01/30/23:
    Electrophilic indoles added (ChemCommun 2021, 57, 10071-10074)
  • 04/13/21:
    Cyclic Michael acceptors added (Chem. Sci. 2021, 12, 4850-4865)
  • 05/21/21:
    Thiophenolates (in DMSO) added (JOC 2021, 86, 5965-5972)
  • 05/06/20:
    Heteroallenes added (JACS 2020, 142, 8383-8402).
  • 01/27/20:
    Pyrrolidines and Imidazolidinones added (JACS 2020, 142, 1526-1547).
  • 05/06/20:
    GSH reactivity added (Angew. Chem. Int. Ed. 2019, 58, 17704-17708)
  • 01/30/23:
    Phenolates added (JOC 2019, 84, 8837-8858)
  • 04/24/18:
    Ketones added (JACS 2018, 140, 5500).
  • 11/03/17:
    Allyl-boron nucleophiles added (JACS 2017, 139, 15324)
  • 04/23/18:
    Peroxide anions added (Angew. Chem. Int. Ed. 2017, 56, 13279).
  • 04/23/18:
    Michael acceptors added (JACS 2017, 139, 13318).
  • 06/16/17:
    Nucleophilicities of VNS reagents (JOC 2017, 82, 1011).