Electrophiles
| Name | Solvent |
Reactivity Parameters |
Classification |
Reference (title or year) |
|---|---|---|---|---|
jul Meldrum's acid   |
E Param.: -13.97 |
 |
J. Org. Chem. 2008, 73, 2738-2745 10.1021/jo702590s |
|
diethyl benzylidene malonate  |
E Param.: -20.55 |
|
Chem. Eur. J. 2008, 14, 9675-9682 10.1002/chem.200801277 |
|
diethyl 4-nitrobenzylidene malonate  |
E Param.: -17.67 |
|
Chem. Eur. J. 2008, 14, 9675-9682 10.1002/chem.200801277 |
|
diethyl 4-cyano-benzylidene malonate  |
E Param.: -18.06 |
|
Chem. Eur. J. 2008, 14, 9675-9682 10.1002/chem.200801277 |
|
diethyl 3-chloro-benzylidene malonate  |
E Param.: -18.98 |
|
Chem. Eur. J. 2008, 14, 9675-9682 10.1002/chem.200801277 |
|
diethyl 4-methyl-benzylidene malonate  |
E Param.: -21.11 |
|
Chem. Eur. J. 2008, 14, 9675-9682 10.1002/chem.200801277 |
|
diethyl 4-methoxy-benzylidene malonate  |
E Param.: -21.47 |
|
Chem. Eur. J. 2008, 14, 9675-9682 10.1002/chem.200801277 |
|
diethyl 4-(dimethylamino)benzylidene malonate  |
E Param.: -23.10 |
|
Chem. Eur. J. 2008, 14, 9675-9682 10.1002/chem.200801277 |
|
diethyl 2-((1-methyl-1,2,3,4-tetrahydroquinolin-6-yl)methylene)malonate  |
E Param.: -23.40 |
|
Chem. Eur. J. 2008, 14, 9675-9682 10.1002/chem.200801277 |
|
diethyl 2-((julolidine-9-yl)methylene)malonate  |
E Param.: -23.80 |
|
Chem. Eur. J. 2008, 14, 9675-9682 10.1002/chem.200801277 |
|
Me2N+=CH-CH-Ph  |
E Param.: -9.20 |
|
Angew. Chem. Int. Ed. 2008, 47, 8723-8726 10.1002/anie.200802889 |
|
pyrN+=CH-CH-Ph  |
E Param.: -9.80 |
|
Angew. Chem. Int. Ed. 2008, 47, 8723-8726 10.1002/anie.200802889 |
|
pipN+=CH-CH-Ph  |
E Param.: -10.30 |
|
Angew. Chem. Int. Ed. 2008, 47, 8723-8726 10.1002/anie.200802889 |
|
(PhCH2)2N+=CH-CH-Ph  |
E Param.: -8.50 |
|
Angew. Chem. Int. Ed. 2008, 47, 8723-8726 10.1002/anie.200802889 |
|
Jorgensen/Hayashi-iminium ion  |
E Param.: -8.20 |
|
Angew. Chem. Int. Ed. 2008, 47, 8723-8726 10.1002/anie.200802889 |
|
MacMillan-iminium ion (1st generation)  |
MeCN | E Param.: -7.37 |
|
Angew. Chem. Int. Ed. 2011, 50, 9953-9956 10.1002/anie.201103683 |
mor iminium  |
E Param.: -8.60 |
|
Angew. Chem. Int. Ed. 2008, 47, 8723-8726 10.1002/anie.200802889 |
|
2,6-diphenyl-4-benzylidenecyclohexa-2,5-dienone  |
E Param.: -11.87 |
|
Eur. J. Org. Chem. 2009, , 3203-3211 10.1002/ejoc.200900299 |
|
2,6-dimethoxy-4-(4-methoxybenzylidene)cyclohexa-2,5-dienone  |
E Param.: -16.38 |
|
Eur. J. Org. Chem. 2009, , 3203-3211 10.1002/ejoc.200900299 |
|
2,6-dimethoxy-4-(4-(dimethylamino)benzylidene)cyclohexa-2,5-dienone  |
E Param.: -17.18 |
|
Eur. J. Org. Chem. 2009, , 3203-3211 10.1002/ejoc.200900299 |
|
2,6-dimethyl-4-(4-(dimethylamino)benzylidene)cyclohexa-2,5-dienone  |
E Param.: -16.36 |
|
Eur. J. Org. Chem. 2009, , 3203-3211 10.1002/ejoc.200900299 |
|
2,6-di-tert.butyl-4-(3-fluorobenzylidene)cyclohexa-2,5-dienone  |
E Param.: -15.03 |
|
Eur. J. Org. Chem. 2009, , 3203-3211 10.1002/ejoc.200900299 |
|
2,6-di-tert.butyl-4-(3,5-difluorobenzylidene)cyclohexa-2,5-dienone  |
E Param.: -14.50 |
|
Eur. J. Org. Chem. 2009, , 3203-3211 10.1002/ejoc.200900299 |
|
2,6-di-tert.butyl-4-(4-nitrobenzylidene)cyclohexa-2,5-dienone  |
E Param.: -14.36 |
|
Eur. J. Org. Chem. 2009, , 3203-3211 10.1002/ejoc.200900299 |
|
bh6a  |
E Param.: -18.60 |
|
Chem. Eur. J. 2010, 16, 1365-1371 10.1002/chem.200902487 |
|
bh 6f  |
E Param.: -18.90 |
|
Chem. Eur. J. 2010, 16, 1365-1371 10.1002/chem.200902487 |
|
bh 6i  |
E Param.: -19.10 |
|
Chem. Eur. J. 2010, 16, 1365-1371 10.1002/chem.200902487 |
|
bh6j  |
E Param.: -17.90 |
|
Chem. Eur. J. 2010, 16, 1365-1371 10.1002/chem.200902487 |
|
bh 6k  |
E Param.: -18.20 |
|
Chem. Eur. J. 2010, 16, 1365-1371 10.1002/chem.200902487 |
|
bh 6l  |
E Param.: -18.90 |
|
Chem. Eur. J. 2010, 16, 1365-1371 10.1002/chem.200902487 |
|
bh 6m  |
E Param.: -17.30 |
|
Chem. Eur. J. 2010, 16, 1365-1371 10.1002/chem.200902487 |
|
cumyl cation  |
E Param.: 5.74 |
|
Macromolecules 2010, 43, 1719-1723 10.1021/ma9024569 |
|
1,2-diaza-1,3-diene 1a  |
DMSO | E Param.: -13.28 |
|
Chem. Eur. J. 2010, 16, 12008-12016 10.1002/chem.201000828 |
1,2-diaza-1,3-diene 1b  |
DMSO | E Param.: -13.90 |
|
Chem. Eur. J. 2010, 16, 12008-12016 10.1002/chem.201000828 |
1,2-diaza-1,3-diene 1c  |
DMSO | E Param.: -14.91 |
|
Chem. Eur. J. 2010, 16, 12008-12016 10.1002/chem.201000828 |
1,2-diaza-1,3-diene 1d  |
DMSO | E Param.: -15.38 |
|
Chem. Eur. J. 2010, 16, 12008-12016 10.1002/chem.201000828 |
1,2-diaza-1,3-diene 1e  |
MeOH | E Param.: -14.90 |
|
Chem. Eur. J. 2010, 16, 12008-12016 10.1002/chem.201000828 |
1,2-diaza-1,3-diene 1f  |
MeOH | E Param.: -15.30 |
|
Chem. Eur. J. 2010, 16, 12008-12016 10.1002/chem.201000828 |
2,3,4,5,6,6-hexachlorocyclohexa-2,4-dien-1-one  |
MeCN | E Param.: -6.75 |
|
Org. Lett. 2010, 12, 2238-2241 10.1021/ol100592j |
5,7,7-trichloro-8(7H)-quinolinone  |
MeCN | E Param.: -10.48 |
|
Org. Lett. 2010, 12, 2238-2241 10.1021/ol100592j |
2,2,4-trichloro-1(2H)-naphthalenone  |
MeCN | E Param.: -11.24 |
|
Org. Lett. 2010, 12, 2238-2241 10.1021/ol100592j |
dibenzyl azodicarboxylate  |
MeCN | E Param.: -8.89 |
|
Chem. Eur. J. 2010, 16, 11670-11677 10.1002/chem.201001598 |
diethyl azodicarboxylate  |
MeCN | E Param.: -10.15 |
|
Chem. Eur. J. 2010, 16, 11670-11677 10.1002/chem.201001598 |
diisopropyl azodicarboxylate  |
MeCN | E Param.: -10.71 |
|
Chem. Eur. J. 2010, 16, 11670-11677 10.1002/chem.201001598 |
di-tert-butyl azodicarboxylate  |
MeCN | E Param.: -12.23 |
|
Chem. Eur. J. 2010, 16, 11670-11677 10.1002/chem.201001598 |
(4-CF3)2-tritylium ion  |
E Param.: 2.28 |
 |
J. Am. Chem. Soc. 2003, 125, 286-295 10.1021/ja021010y |
|
(3-Cl)3-tritylium ion  |
E Param.: 1.99 |
|
J. Am. Chem. Soc. 2003, 125, 286-295 10.1021/ja021010y |
|
(4-CF3)-tritylium ion  |
E Param.: 1.33 |
|
J. Am. Chem. Soc. 2003, 125, 286-295 10.1021/ja021010y |
|
(3-Cl)-tritylium ion  |
E Param.: 1.06 |
|
J. Am. Chem. Soc. 2003, 125, 286-295 10.1021/ja021010y |
|
(3-CF3)-tritylium ion  |
E Param.: 1.18 |
|
J. Am. Chem. Soc. 2003, 125, 286-295 10.1021/ja021010y |