Cationic Metal-π-Complexes
| Name | Solvent |
Reactivity Parameters |
Classification |
Reference (title or year) |
|---|---|---|---|---|
fc(Ph)CH+  |
E Param.: -2.64 |  | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y | |
fc(ani)CH+ |
E Param.: -2.90 | | Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c | |
fc(Me)CH+ |
E Param.: -2.57 | | Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c | |
fc2CH+ |
E Param.: -8.54 | | Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c | |
C7H7+-Fe(CO)3 |
E Param.: -3.49 | | Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c | |
C7H9+-Fe(CO)3 |
E Param.: -9.21 | | Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c | |
C6H7+-Fe(CO)3 |
E Param.: -7.76 | | Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c | |
C6H6OMe+-Fe(CO)3 |
E Param.: -8.94 | | Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c | |
propyn-1-ylium-Co2(CO)6 |
E Param.: -0.84 | | Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c | |
1-phenyl-proyn-ylium-Co2(CO)6 |
E Param.: -0.97 | | Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c | |
3-phenylpropyn-1-ylium-Co2(CO)6 |
E Param.: -1.58 | | Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c | |
3-(trimethylsilyl)propyn-1-ylium-Co2(CO)6 |
E Param.: -1.60 | | Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c | |
1-phenyl-propyn-1-ylium-Co2(CO)5(PPh3) |
E Param.: -6.19 | | Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c | |
Pd-allyl cation |
E Param.: -10.11 | | Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c | |
1,3-diphenylpropyn-1-ylium-Cr(CO)3 |
E Param.: 1.07 | | Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c | |
1,1,3-triphenylpropyn-1-ylium-Cr(CO)3 |
E Param.: -0.25 | | Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c | |
dicarbonyl(cyclopentadienyl)propene-iron(II) |
E Param.: -11.20 | | Helv. Chim. Acta 2005, 88, 1754-1768 10.1002/hlca.200590137 | |
[(1,3-Diarylallyl)Pd(PPh3)2]+ (Aryl = Ph) |
E Param.: -14.14 | | Organometallics 2012, 31, 2416-2424 10.1021/om3000357 | |
[(1,3-Diarylallyl)Pd(PPh3)2]+ (Aryl = 3,5-difluorophenyl) |
E Param.: -14.21 | | Organometallics 2012, 31, 2416-2424 10.1021/om3000357 | |
[(1,3-Diarylallyl)Pd(PPh3)2]+ (Aryl = 4-(dimethylamino)phenyl) |
E Param.: -14.46 | | Organometallics 2012, 31, 2416-2424 10.1021/om3000357 |