Nucleophiles
| Name | Solvent |
Reactivity Parameters |
Classification |
Reference (title or year) |
|---|---|---|---|---|
bromide (in H2O)![]() ![]() |
water | N Param.: 11.70 sN Param.: 0.60 | J. Am. Chem. Soc. 2005, 127, 2641-2649 10.1021/ja045562n | |
bromide (in 20% aq MeCN)![]() ![]() |
water-MeCN mix | N Param.: 12.20 sN Param.: 0.60 | J. Am. Chem. Soc. 2005, 127, 2641-2649 10.1021/ja045562n | |
bromide (in 40% aq MeCN)![]() ![]() |
water-MeCN mix | N Param.: 12.80 sN Param.: 0.60 | J. Am. Chem. Soc. 2005, 127, 2641-2649 10.1021/ja045562n | |
bromide (in 50% aq MeCN)![]() ![]() |
water-MeCN mix | N Param.: 13.80 sN Param.: 0.60 | J. Am. Chem. Soc. 2005, 127, 2641-2649 10.1021/ja045562n | |
bromide (in CF3CH2OH)![]() ![]() |
TFE | N Param.: 11.70 sN Param.: 0.60 | J. Am. Chem. Soc. 2005, 127, 2641-2649 10.1021/ja045562n | |
5-(tris(pentafluorophenyl)siloxy)-2,3-dihydrofuran![]() ![]() |
dichloromethane | N Param.: 8.16 sN Param.: 0.67 | Eur. J. Org. Chem. 2005, , 1760-1764 10.1002/ejoc.200400706 | |
5-(triphenylsiloxy)-2,3-dihydrofuran![]() ![]() |
dichloromethane | N Param.: 11.28 sN Param.: 0.91 | Eur. J. Org. Chem. 2005, , 1760-1764 10.1002/ejoc.200400706 | |
1-(triphenylsiloxy)cyclopentene![]() ![]() |
dichloromethane | N Param.: 5.76 sN Param.: 1.02 | Eur. J. Org. Chem. 2005, , 1760-1764 10.1002/ejoc.200400706 | |
2,3-dihydrofuran![]() ![]() |
dichloromethane | N Param.: 4.37 sN Param.: 0.90 | Eur. J. Org. Chem. 2005, , 1760-1764 10.1002/ejoc.200400706 | |
2-(tris(pentafluorophenyl)siloxy)-propene![]() ![]() |
dichloromethane | N Param.: 0.58 sN Param.: 0.91 | Eur. J. Org. Chem. 2005, , 1760-1764 10.1002/ejoc.200400706 | |
1-(tris(pentafluorophenyl)siloxy)-cyclopentene![]() ![]() |
dichloromethane | N Param.: 1.38 sN Param.: 0.93 | Eur. J. Org. Chem. 2005, , 1760-1764 10.1002/ejoc.200400706 | |
nitrite ion (in MeCN)![]() ![]() |
MeCN | N Param.: 17.20 sN Param.: 0.72 | Angew. Chem. Int. Ed. 2005, 44, 4623-4626 10.1002/anie.200501274 | |
(allyl)dicarbonyl(cyclopentadienyl)iron(II)![]() ![]() |
dichloromethane | N Param.: 6.78 sN Param.: 0.95 | Helv. Chim. Acta 2005, 88, 1754-1768 10.1002/hlca.200590137 | |
(2-methylallyl)dicarbonyl(cyclopentadienyl)iron(II)![]() ![]() |
dichloromethane | N Param.: 8.45 sN Param.: 0.83 | Helv. Chim. Acta 2005, 88, 1754-1768 10.1002/hlca.200590137 | |
91% n-propanol/9% MeCN (v/v)![]() ![]() |
nPrOH-MeCN mix | N Param.: 7.05 sN Param.: 0.80 | Can. J. Chem. 2005, 83, 1554-1560 10.1139%2Fv05-170 | |
91% propan-2-ol/9% MeCN (v/v)![]() ![]() |
iPrOH-MeCN mix | N Param.: 6.49 sN Param.: 0.96 | Can. J. Chem. 2005, 83, 1554-1560 10.1139%2Fv05-170 | |
methanolate (in methanol)![]() ![]() |
MeOH | N Param.: 15.78 sN Param.: 0.56 | Can. J. Chem. 2005, 83, 1554-1560 10.1139%2Fv05-170 | |
ethanolate (in ethanol)![]() ![]() |
EtOH | N Param.: 15.78 sN Param.: 0.65 | Can. J. Chem. 2005, 83, 1554-1560 10.1139%2Fv05-170 | |
n-propanolate (in propan-1-ol)![]() ![]() |
nPrOH | N Param.: 16.03 sN Param.: 0.70 | Can. J. Chem. 2005, 83, 1554-1560 10.1139%2Fv05-170 | |
isopropanolate (in propan-2-ol)![]() ![]() |
iPrOH | N Param.: 17.03 sN Param.: 0.63 | Can. J. Chem. 2005, 83, 1554-1560 10.1139%2Fv05-170 | |
methanolate (in 91M9AN)![]() ![]() |
MeOH-MeCN mix | N Param.: 14.51 sN Param.: 0.68 | Can. J. Chem. 2005, 83, 1554-1560 10.1139%2Fv05-170 | |
ethanolate (in 91E9AN)![]() ![]() |
EtOH-MeCN mix | N Param.: 16.08 sN Param.: 0.62 | Can. J. Chem. 2005, 83, 1554-1560 10.1139%2Fv05-170 | |
n-propanolate (in 91nPr9AN)![]() ![]() |
nPrOH-MeCN mix | N Param.: 16.73 sN Param.: 0.63 | Can. J. Chem. 2005, 83, 1554-1560 10.1139%2Fv05-170 | |
isopropanolate (in 91iPr9AN)![]() ![]() |
iPrOH-MeCN mix | N Param.: 17.71 sN Param.: 0.58 | Can. J. Chem. 2005, 83, 1554-1560 10.1139%2Fv05-170 | |
H2O (in water)![]() ![]() |
water | N Param.: 5.20 sN Param.: 0.89 | J. Am. Chem. Soc. 2004, 126, 5174-5181 10.1021/ja031828z | |
10% water/90% acetone (v/v)![]() ![]() |
water-acetone mix | N Param.: 5.70 sN Param.: 0.85 | Angew. Chem. Int. Ed. 2004, 43, 2302-2305 10.1002/anie.200353468 | |
20% water/80% acetone (v/v)![]() ![]() |
water-acetone mix | N Param.: 5.77 sN Param.: 0.87 | Angew. Chem. Int. Ed. 2004, 43, 2302-2305 10.1002/anie.200353468 | |
91% water/9% MeCN (v/v)![]() ![]() |
water-MeCN mix | N Param.: 5.16 sN Param.: 0.91 | J. Am. Chem. Soc. 2004, 126, 5174-5181 10.1021/ja031828z | |
80% water/20% MeCN (v/v)![]() ![]() |
water-MeCN mix | N Param.: 5.04 sN Param.: 0.89 | J. Am. Chem. Soc. 2004, 126, 5174-5181 10.1021/ja031828z | |
67% water/33% MeCN (v/v)![]() ![]() |
water-MeCN mix | N Param.: 5.05 sN Param.: 0.90 | J. Am. Chem. Soc. 2004, 126, 5174-5181 10.1021/ja031828z | |
33% water/67% MeCN (v/v)![]() ![]() |
water-MeCN mix | N Param.: 5.02 sN Param.: 0.90 | J. Am. Chem. Soc. 2004, 126, 5174-5181 10.1021/ja031828z | |
20% water/80% MeCN (v/v)![]() ![]() |
water-MeCN mix | N Param.: 5.02 sN Param.: 0.89 | J. Am. Chem. Soc. 2004, 126, 5174-5181 10.1021/ja031828z | |
10% water/90% MeCN (v/v)![]() ![]() |
water-MeCN mix | N Param.: 4.56 sN Param.: 0.94 | J. Am. Chem. Soc. 2004, 126, 5174-5181 10.1021/ja031828z | |
10% water/90%TFE (v/v)![]() ![]() |
water-TFE mix | N Param.: 2.93 sN Param.: 0.88 | J. Am. Chem. Soc. 2004, 126, 5174-5181 10.1021/ja031828z | |
20% water/80%TFE (v/v)![]() ![]() |
water-TFE mix | N Param.: 3.20 sN Param.: 0.88 | J. Am. Chem. Soc. 2004, 126, 5174-5181 10.1021/ja031828z | |
40% water/60%TFE (v/v)![]() ![]() |
water-TFE mix | N Param.: 3.42 sN Param.: 0.90 | J. Am. Chem. Soc. 2004, 126, 5174-5181 10.1021/ja031828z | |
50% water/50%TFE (v/v)![]() ![]() |
water-TFE mix | N Param.: 3.57 sN Param.: 0.89 | J. Am. Chem. Soc. 2004, 126, 5174-5181 10.1021/ja031828z | |
60% water/40%TFE (v/v)![]() ![]() |
water-TFE mix | N Param.: 3.77 sN Param.: 0.88 | J. Am. Chem. Soc. 2004, 126, 5174-5181 10.1021/ja031828z | |
80% water/20%TFE (v/v)![]() ![]() |
water-TFE mix | N Param.: 4.78 sN Param.: 0.83 | J. Am. Chem. Soc. 2004, 126, 5174-5181 10.1021/ja031828z | |
90% water/10%TFE (v/v)![]() ![]() |
water-TFE mix | N Param.: 5.04 sN Param.: 0.90 | J. Am. Chem. Soc. 2004, 126, 5174-5181 10.1021/ja031828z | |
methanol![]() ![]() |
MeOH | N Param.: 7.54 sN Param.: 0.92 | J. Am. Chem. Soc. 2004, 126, 5174-5181 10.1021/ja031828z | |
ethanol![]() ![]() |
EtOH | N Param.: 7.44 sN Param.: 0.90 | J. Am. Chem. Soc. 2004, 126, 5174-5181 10.1021/ja031828z | |
10% water/90%EtOH (v/v)![]() ![]() |
water-EtOH mix | N Param.: 7.03 sN Param.: 0.86 | J. Am. Chem. Soc. 2004, 126, 5174-5181 10.1021/ja031828z | |
20% water/80%EtOH (v/v)![]() ![]() |
water-EtOH mix | N Param.: 6.68 sN Param.: 0.85 | J. Am. Chem. Soc. 2004, 126, 5174-5181 10.1021/ja031828z | |
40% water/60%EtOH (v/v)![]() ![]() |
water-EtOH mix | N Param.: 6.28 sN Param.: 0.87 | J. Am. Chem. Soc. 2004, 126, 5174-5181 10.1021/ja031828z | |
50% water/50%EtOH (v/v)![]() ![]() |
water-EtOH mix | N Param.: 5.96 sN Param.: 0.89 | J. Am. Chem. Soc. 2004, 126, 5174-5181 10.1021/ja031828z | |
60% water/40%EtOH (v/v)![]() ![]() |
water-EtOH mix | N Param.: 5.81 sN Param.: 0.90 | J. Am. Chem. Soc. 2004, 126, 5174-5181 10.1021/ja031828z | |
80% water/20%EtOH (v/v)![]() ![]() |
water-EtOH mix | N Param.: 5.54 sN Param.: 0.94 | J. Am. Chem. Soc. 2004, 126, 5174-5181 10.1021/ja031828z | |
90% water/10%EtOH (v/v)![]() ![]() |
water-EtOH mix | N Param.: 5.38 sN Param.: 0.91 | J. Am. Chem. Soc. 2004, 126, 5174-5181 10.1021/ja031828z | |
91% ethanol/9% MeCN (v/v)![]() ![]() |
EtOH-MeCN mix | N Param.: 7.10 sN Param.: 0.90 | J. Am. Chem. Soc. 2004, 126, 5174-5181 10.1021/ja031828z |



















































