Mayr's Database of Reactivity Parameters

Nucleophiles

5 | 6 | 7 | 8 | 9 | 10 | 11 | 12 | 13 Found 1292 molecules, displaying page 9 of 26 Results per page 10|50|100|all
Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
4-methyl-N-(2-phenylethynyl)-N-(phenylmethyl)benzenesulfonamide
C22H19NO2S*
 dichloromethane

N  Param.: 3.85

sN Param.: 0.84		***Angew. Chem. Int. Ed. 2014, 53, 4968-4971
10.1002/anie.201402055
1-(phenylethynyl)pyrrolidin-2-one
C12H11NO*
 dichloromethane

N  Param.: 3.12

sN Param.: 0.85		*Angew. Chem. Int. Ed. 2014, 53, 4968-4971
10.1002/anie.201402055
4-(2-(fluorodiphenylmethyl)pyrrolidin-1-yl)pyridine
C22H21FN2*
 dichloromethane

N  Param.: 14.57

sN Param.: 0.75		***Eur. J. Org. Chem. 2014, , 1202-1211
10.1002/ejoc.201301730
1,4-dimethylcyclohexa-1,4-diene (in CH2Cl2)
C8H12*
 dichloromethane

N  Param.: 1.88

sN Param.: 0.96		**J. Am. Chem. Soc. 2014, 136, 13863-13873
10.1021/ja507598y
1,3,5-trimethylcyclohexa-1,4-diene (in CH2Cl2)
C9H14*
 dichloromethane

N  Param.: 4.95

sN Param.: 0.79		**J. Am. Chem. Soc. 2014, 136, 13863-13873
10.1021/ja507598y
1,2,4,5-tetramethylcyclohexa-1,4-diene (in CH2Cl2)
C10H16*
 dichloromethane

N  Param.: 4.27

sN Param.: 0.86		**J. Am. Chem. Soc. 2014, 136, 13863-13873
10.1021/ja507598y
bis(4-methoxyphenyl)methane (in CH2Cl2)
C15H16O2*
 dichloromethane

N  Param.: -2.11

sN Param.: 0.98		**J. Am. Chem. Soc. 2014, 136, 13863-13873
10.1021/ja507598y
(E)-1-styrylpyrrolidine (in CH2Cl2)
C12H15N*
 dichloromethane

N  Param.: 12.26

sN Param.: 0.93		***J. Am. Chem. Soc. 2014, 136, 14263-14269
10.1021/ja508065e
(E)-1-styryl-2-tritylpyrrolidine (in CH2Cl2)
C31H29N*
 dichloromethane

N  Param.: 10.19

sN Param.: 1.06		***J. Am. Chem. Soc. 2014, 136, 14263-14269
10.1021/ja508065e
(E)-1-styryl-2-(triphenylsilyl)pyrrolidine (in CH2Cl2)
C30H29NSi*
 dichloromethane

N  Param.: 11.77

sN Param.: 0.98		***J. Am. Chem. Soc. 2014, 136, 14263-14269
10.1021/ja508065e
(1H-inden-1-yl)trimethylstannane (in CH2Cl2)
C12H16Sn*
 dichloromethane

N  Param.: 6.68

sN Param.: 0.81		***Angew. Chem. Int. Ed. 2015, 54, 12497-12500
10.1002/anie.201501385
(1H-inden-1-yl)trimethylsilane (in CH2Cl2)
C12H16Si*
 dichloromethane

N  Param.: -0.10

sN Param.: 1.05		***Angew. Chem. Int. Ed. 2015, 54, 12497-12500
10.1002/anie.201501385
nicotine (in CH2Cl2)
C10H14N2*
 dichloromethane

N  Param.: 10.40

sN Param.: 1.04		***J. Phys. Org. Chem. 2016, 29, 759-767
10.1002/poc.3580
3-methylpyridine (in CH2Cl2)
C6H7N*
 dichloromethane

N  Param.: 10.90

sN Param.: 0.93		***J. Phys. Org. Chem. 2016, 29, 759-767
10.1002/poc.3580
1-methyl-2-phenylpyrrolidine (in CH2Cl2)
C11H15N*
 dichloromethane

N  Param.: 16.80

sN Param.: 0.49		***J. Phys. Org. Chem. 2016, 29, 759-767
10.1002/poc.3580
4-(morpholino)pyridine (in CH2Cl2)
C9H12N2O*
 dichloromethane

N  Param.: 14.59

sN Param.: 0.69		***Eur. J. Org. Chem. 2016, , 4050-4058
10.1002/ejoc.201600572
Cp2Zr(Me)2 - Dimethylzirconocene
*
 dichloromethane

N  Param.: 4.35

sN Param.: 1.09		***Chem. Eur. J. 2016, 22, 11196-11200
10.1002/chem.201602452
Cp2Zr(CH2Ph)2 - Dibenzylzirconocene
*
 dichloromethane

N  Param.: 5.10

sN Param.: 1.03		***Chem. Eur. J. 2016, 22, 11196-11200
10.1002/chem.201602452
Cp2Ti(CH2Ph)2 - Dibenzyltitanocene
*
 dichloromethane

N  Param.: 4.38

sN Param.: 1.00		*Chem. Eur. J. 2016, 22, 11196-11200
10.1002/chem.201602452
(Cp*)2Zr(Me)2 - Dimethyl-bis(pentamethylcyclopentadienyl)zirconium
C22H36Zr*
 dichloromethane

N  Param.: 5.49

sN Param.: 1.06		***Chem. Eur. J. 2016, 22, 11196-11200
10.1002/chem.201602452
Dimethyl 1,1'-isopropylidenezirconocene
*
 dichloromethane

N  Param.: 5.20

sN Param.: 1.00		*Chem. Eur. J. 2016, 22, 11196-11200
10.1002/chem.201602452
Dimethyl bis(indenyl)zirconium(IV)
*
 dichloromethane

N  Param.: 6.89

sN Param.: 1.00		*Chem. Eur. J. 2016, 22, 11196-11200
10.1002/chem.201602452
Meldrum's acid iodonium ylide (in CH2Cl2)
*
 dichloromethane

N  Param.: 4.36

sN Param.: 1.06		***J. Am. Chem. Soc. 2016, 138, 10304-10313
10.1021/jacs.6b05768
Dimedone iodonium ylide (in CH2Cl2)
*
 dichloromethane

N  Param.: 6.18

sN Param.: 0.81		***J. Am. Chem. Soc. 2016, 138, 10304-10313
10.1021/jacs.6b05768
N,N-Dimethylbarbituric acid iodonium ylide (in CHCl2)
*
 dichloromethane

N  Param.: 7.98

sN Param.: 0.71		***J. Am. Chem. Soc. 2016, 138, 10304-10313
10.1021/jacs.6b05768
6-methyl-3-(phenyl-l3-iodanylidene)dihydro-2H-pyran-2,4(3H)-dione (in CH2Cl2)
*
 dichloromethane

N  Param.: 4.67

sN Param.: 0.92		***J. Am. Chem. Soc. 2016, 138, 10304-10313
10.1021/jacs.6b05768
ditert-butyl-phenylphosphane
C14H23P*
 dichloromethane

N  Param.: 12.40

sN Param.: 0.55		-Chem. Eur. J. 2017, 23, 7422-7427
10.1002/chem.201701080
tris(2,6-dimethoxyphenyl)phosphane
C24H27O6P*
 dichloromethane

N  Param.: 15.19

sN Param.: 0.88		-Chem. Eur. J. 2017, 23, 7422-7427
10.1002/chem.201701080
tris(2,4-dimethylphenyl)phosphane
C24H27P*
 dichloromethane

N  Param.: 14.88

sN Param.: 0.41		-Chem. Eur. J. 2017, 23, 7422-7427
10.1002/chem.201701080
tris(2-methoxyphenyl)phosphane
C21H21O3P*
 dichloromethane

N  Param.: 14.26

sN Param.: 0.73		-Chem. Eur. J. 2017, 23, 7422-7427
10.1002/chem.201701080
tris(2-methylphenyl)phosphane
C21H21P*
 dichloromethane

N  Param.: 8.56

sN Param.: 0.70		-Chem. Eur. J. 2017, 23, 7422-7427
10.1002/chem.201701080
4,4,5,5-tetramethyl-2-prop-2-enyl-1,3,2-dioxaborolane (in CH2Cl2)
C9H17BO2*
 dichloromethane

N  Param.: -0.64

sN Param.: 1.10		***J. Am. Chem. Soc. 2017, 139, 15324-15327
10.1021/jacs.7b10240
(p-nitrophenyl)diazomethane
*
 dichloromethane

N  Param.: 7.17

sN Param.: 0.83		***J. Am. Chem. Soc. 2018, 140, 16758-16772
10.1021/jacs.8b09995
(p-cyanophenyl)diazomethane
*
 dichloromethane

N  Param.: 7.66

sN Param.: 0.80		***J. Am. Chem. Soc. 2018, 140, 16758-16772
10.1021/jacs.8b09995
(p-bromophenyl)diazomethane
*
 dichloromethane

N  Param.: 8.87

sN Param.: 0.82		***J. Am. Chem. Soc. 2018, 140, 16758-16772
10.1021/jacs.8b09995
dimethylsulfide (in CH2Cl2)
C2H6S*
 dichloromethane

N  Param.: 12.32

sN Param.: 0.72		**Chem. Eur. J. 2021, 21, 11367-11376
10.1002/chem.202100977
dimethylselenide (in CH2Cl2)
C2H6Se*
 dichloromethane

N  Param.: 12.60

sN Param.: 0.72		-Chem. Eur. J. 2021, 21, 11367-11376
10.1002/chem.202100977
dibutylsulfide (in CH2Cl2)
C8H18S*
 dichloromethane

N  Param.: 11.86

sN Param.: 0.74		**Chem. Eur. J. 2021, 21, 11367-11376
10.1002/chem.202100977
tetrahydrothiophene (in CH2Cl2)
C4H8S*
 dichloromethane

N  Param.: 13.10

sN Param.: 0.72		-Chem. Eur. J. 2021, 21, 11367-11376
10.1002/chem.202100977
tetrahydrothiopyran (in CH2Cl2)
C5H10S*
 dichloromethane

N  Param.: 11.94

sN Param.: 0.75		**Chem. Eur. J. 2021, 21, 11367-11376
10.1002/chem.202100977
3-diazoindolin-2-one
C8H5N3O*
 dichloromethane

N  Param.: 3.16

sN Param.: 1.03		***Eur. J. Org. Chem. 2023, 26, e202300005
10.1002/ejoc.202300005
2-diazoindan-1-one
C9H6N2O*
 dichloromethane

N  Param.: 5.61

sN Param.: 0.65		***Eur. J. Org. Chem. 2023, 26, e202300005
10.1002/ejoc.202300005
2-diazocyclohexanone
C6H8N2O*
 dichloromethane

N  Param.: 3.44

sN Param.: 0.83		***Eur. J. Org. Chem. 2023, 26, e202300005
10.1002/ejoc.202300005
2-diazo-1-tetralone
C10H8N2O*
 dichloromethane

N  Param.: 3.51

sN Param.: 0.86		***Eur. J. Org. Chem. 2023, 26, e202300005
10.1002/ejoc.202300005
2-diazoindandione
C9H4N2O2*
 dichloromethane

N  Param.: 0.16

sN Param.: 0.86		***Eur. J. Org. Chem. 2023, 26, e202300005
10.1002/ejoc.202300005
2-diazo-1-benzosuberone
C11H10N2O*
 dichloromethane

N  Param.: 2.72

sN Param.: 0.96		***Eur. J. Org. Chem. 2023, 26, e202300005
10.1002/ejoc.202300005
2-diazobenzothiophen-3(2H)-one
C8H4N2OS*
 dichloromethane

N  Param.: 0.40

sN Param.: 0.93		***Eur. J. Org. Chem. 2023, 26, e202300005
10.1002/ejoc.202300005
2-((2,2,5,5-tetramethyl-1-styryl-2,5-dihydro-1H-imidazol-4-yl)thio)acetonitrile (in CH2Cl2)
C17H21N3S*
 dichloromethane

N  Param.: 7.06

sN Param.: 1.11		***Chem. Commun. 2023, 59, 8091-8084
10.1039/d3cc01912h
diazocyclopentadiene (in CH2Cl2)
C5H4N2*
 dichloromethane

N  Param.: 4.84

sN Param.: 1.06		***Synthesis 2023, 55, 354-358
10.1055/s-0041-1737327
(E)-4-(ethylthio)-2,2,5,5-tetramethyl-1-styryl-2,5-dihydro-1H-imidazole (in CH2Cl2)
C17H24N2S *
 dichloromethane

N  Param.: 8.13

sN Param.: 0.97		***Chem. Eur. J. 2023, , EarlyView
10.1002/chem.202302764