Carbanions
| Name | Solvent |
Reactivity Parameters |
Classification |
Reference (title or year) |
|---|---|---|---|---|
1-(ethoxycarbonyl)-2-oxocyclododecan-1-ide (in DMSO)   |
DMSO | N Param.: 20.60 sN Param.: 0.63 |
 |
Eur. J. Org. Chem. 2015, , 7594-7601 10.1002/ejoc.201501107 |
3-methyl-2,4-dioxotetrahydro-2H-pyran-3-ide (in DMSO)  |
DMSO | N Param.: 14.46 sN Param.: 0.91 |
|
Eur. J. Org. Chem. 2015, , 7594-7601 10.1002/ejoc.201501107 |
3-acetyl-2-oxotetrahydro-2H-pyran-3-ide (in DMSO)  |
DMSO | N Param.: 17.00 sN Param.: 0.74 |
|
Eur. J. Org. Chem. 2015, , 7594-7601 10.1002/ejoc.201501107 |
anion of diethyl 2-(isopropyl)malonate (in DMSO)  |
DMSO | N Param.: 18.74 sN Param.: 0.71 |
|
Eur. J. Org. Chem. 2016, , 1841-1848 10.1002/ejoc.201600107 |
anion of diethyl 2-butylmalonate (in DMSO)  |
DMSO | N Param.: 23.00 sN Param.: 0.55 |
|
Eur. J. Org. Chem. 2016, , 1841-1848 10.1002/ejoc.201600107 |
anion of diethyl 2-cyclohexylmalonate (in DMSO)  |
DMSO | N Param.: 19.23 sN Param.: 0.67 |
|
Eur. J. Org. Chem. 2016, , 1841-1848 10.1002/ejoc.201600107 |
anion of diethyl 2-phenylmalonate (in DMSO)  |
DMSO | N Param.: 15.93 sN Param.: 0.99 |
|
Eur. J. Org. Chem. 2016, , 1841-1848 10.1002/ejoc.201600107 |
anion of diethyl 2-(4-nitrophenyl)malonate (in DMSO)  |
DMSO | N Param.: 14.94 sN Param.: 0.96 |
|
Eur. J. Org. Chem. 2016, , 1841-1848 10.1002/ejoc.201600107 |
anion of triethyl methanetricarboxylate (in DMSO)  |
DMSO | N Param.: 15.33 sN Param.: 0.72 |
|
Eur. J. Org. Chem. 2016, , 1841-1848 10.1002/ejoc.201600107 |
anion of diethyl 2-(acetyl)malonate (in DMSO)  |
DMSO | N Param.: 13.83 sN Param.: 0.84 |
|
Eur. J. Org. Chem. 2016, , 1841-1848 10.1002/ejoc.201600107 |
anion of diethyl 2-(benzoyl)malonate (in DMSO)  |
DMSO | N Param.: 13.63 sN Param.: 0.80 |
|
Eur. J. Org. Chem. 2016, , 1841-1848 10.1002/ejoc.201600107 |
anion of 5-phenyl Meldrum's acid (in DMSO)  |
DMSO | N Param.: 11.54 sN Param.: 0.95 |
|
Eur. J. Org. Chem. 2016, , 1841-1848 10.1002/ejoc.201600107 |
anion of 5-(p-anisyl) Meldrum's acid (in DMSO)  |
DMSO | N Param.: 12.35 sN Param.: 0.90 |
|
Eur. J. Org. Chem. 2016, , 1841-1848 10.1002/ejoc.201600107 |
anion of diethyl 2-(p-anisyl)malonate (in DMSO)  |
DMSO | N Param.: 16.73 sN Param.: 0.91 |
|
Eur. J. Org. Chem. 2016, , 1841-1848 10.1002/ejoc.201600107 |
bis(phenylsulfonyl)methanide (in DMSO)  |
DMSO | N Param.: 15.68 sN Param.: 0.74 |
|
Angew. Chem. Int. Ed. 2016, 55, 12845-12848 10.1002/anie.201605616 |
fluorobis(phenylsulfonyl)methanide (in DMSO)  |
DMSO | N Param.: 17.46 sN Param.: 0.73 |
|
Angew. Chem. Int. Ed. 2016, 55, 12845-12848 10.1002/anie.201605616 |
methoxybis(phenylsulfonyl)methanide (in DMSO)  |
DMSO | N Param.: 17.29 sN Param.: 0.70 |
|
Angew. Chem. Int. Ed. 2016, 55, 12845-12848 10.1002/anie.201605616 |
2H-benzo[d][1,3]dithiol-2-ide 1,1,3,3-tetraoxide (in DMSO)  |
DMSO | N Param.: 16.06 sN Param.: 0.69 |
|
Angew. Chem. Int. Ed. 2016, 55, 12845-12848 10.1002/anie.201605616 |
2-fluoro-2H-benzo[d][1,3]dithiol-2-ide 1,1,3,3-tetraoxide (in DMSO)  |
DMSO | N Param.: 19.03 sN Param.: 0.58 |
|
Angew. Chem. Int. Ed. 2016, 55, 12845-12848 10.1002/anie.201605616 |
2-methoxy-2H-benzo[d][1,3]dithiol-2-ide 1,1,3,3-tetraoxide (in DMSO)  |
DMSO | N Param.: 17.36 sN Param.: 0.71 |
|
Angew. Chem. Int. Ed. 2016, 55, 12845-12848 10.1002/anie.201605616 |
2-ethoxy-2-oxo-1-(phenylsulfonyl)ethan-1-ide (in DMSO)  |
DMSO | N Param.: 18.81 sN Param.: 0.59 |
|
Angew. Chem. Int. Ed. 2016, 55, 12845-12848 10.1002/anie.201605616 |
2-ethoxy-1-fluoro-2-oxo-1-(phenylsulfonyl)ethan-1-ide (in DMSO)  |
DMSO | N Param.: 20.51 sN Param.: 0.64 |
|
Angew. Chem. Int. Ed. 2016, 55, 12845-12848 10.1002/anie.201605616 |
2-ethoxy-1-methoxy-2-oxo-1-(phenylsulfonyl)ethan-1-ide (in DMSO)  |
DMSO | N Param.: 19.15 sN Param.: 0.59 |
|
Angew. Chem. Int. Ed. 2016, 55, 12845-12848 10.1002/anie.201605616 |
1,3-diethoxy-2-fluoro-1,3-dioxopropan-2-ide (in DMSO)  |
DMSO | N Param.: 20.63 sN Param.: 0.76 |
|
Angew. Chem. Int. Ed. 2016, 55, 12845-12848 10.1002/anie.201605616 |
2-chloro-1,3-diethoxy-1,3-dioxopropan-2-ide (in DMSO)  |
DMSO | N Param.: 18.19 sN Param.: 0.74 |
|
Angew. Chem. Int. Ed. 2016, 55, 12845-12848 10.1002/anie.201605616 |
1,2,3-trimethoxy-1,3-dioxopropan-2-ide (in DMSO)  |
DMSO | N Param.: 20.08 sN Param.: 0.74 |
|
Angew. Chem. Int. Ed. 2016, 55, 12845-12848 10.1002/anie.201605616 |
chloro(phenylsulfonyl)methanide (in DMSO)  |
DMSO | N Param.: 28.27 sN Param.: 0.42 |
|
J. Org. Chem. 2017, 82, 2011-2017 10.1021/acs.joc.6b02844 |
bromo(phenylsulfonyl)methanide (in DMSO)  |
DMSO | N Param.: 23.90 sN Param.: 0.62 |
|
J. Org. Chem. 2017, 82, 2011-2017 10.1021/acs.joc.6b02844 |
chloro((4-cyanophenyl)sulfonyl)methanide (in DMSO)  |
DMSO | N Param.: 25.59 sN Param.: 0.51 |
|
J. Org. Chem. 2017, 82, 2011-2017 10.1021/acs.joc.6b02844 |
chloro((4-nitrophenyl)sulfonyl)methanide (in DMSO)  |
DMSO | N Param.: 24.88 sN Param.: 0.49 |
|
J. Org. Chem. 2017, 82, 2011-2017 10.1021/acs.joc.6b02844 |
chloro((4-chlorophenyl)sulfonyl)methanide (in DMSO)  |
DMSO | N Param.: 26.90 sN Param.: 0.45 |
|
J. Org. Chem. 2017, 82, 2011-2017 10.1021/acs.joc.6b02844 |
anion of ethyl 2-cyano-2-phenylacetate (in DMSO)  |
DMSO | N Param.: 15.85 sN Param.: 1.04 |
|
Eur. J. Org. Chem. 2017, , 1196-1202 10.1002/ejoc.201601513 |
anion of 2-phenylmalononitrile (in DMSO)  |
DMSO | N Param.: 15.58 sN Param.: 1.00 |
|
Eur. J. Org. Chem. 2017, , 1196-1202 10.1002/ejoc.201601513 |
anion of 2-phenyl-2-(phenylsulfonyl)acetonitrile (in DMSO)  |
DMSO | N Param.: 15.97 sN Param.: 0.72 |
|
Eur. J. Org. Chem. 2017, , 1196-1202 10.1002/ejoc.201601513 |
anion of (phenylmethylenedisulfonyl)dibenzene (in DMSO)  |
DMSO | N Param.: 15.07 sN Param.: 0.79 |
|
Eur. J. Org. Chem. 2017, , 1196-1202 10.1002/ejoc.201601513 |
anion of 1,2,3-triphenylpropane-1,3-dione (in DMSO)  |
DMSO | N Param.: 14.99 sN Param.: 0.83 |
|
Eur. J. Org. Chem. 2017, , 1196-1202 10.1002/ejoc.201601513 |
barbiturate anion (in DMSO)  |
DMSO | N Param.: 15.59 sN Param.: 0.80 |
|
J. Org. Chem. 2017, 82, 8476-8488 10.1021/acs.joc.7b01223 |
1,3-dimethylbarbiturate anion (in DMSO)  |
DMSO | N Param.: 17.46 sN Param.: 0.72 |
|
J. Org. Chem. 2017, 82, 8476-8488 10.1021/acs.joc.7b01223 |
2-thiobarbiturate anion (in DMSO)  |
DMSO | N Param.: 14.24 sN Param.: 0.82 |
|
J. Org. Chem. 2017, 82, 8476-8488 10.1021/acs.joc.7b01223 |
1,3-diethyl-thiobarbiturate anion (in DMSO)  |
DMSO | N Param.: 14.90 sN Param.: 0.80 |
|
J. Org. Chem. 2017, 82, 8476-8488 10.1021/acs.joc.7b01223 |
1-((diphenylmethylene)amino)-2-ethoxy-2-oxoethan-1-ide (in DMSO)  |
DMSO | N Param.: 26.95 sN Param.: 0.52 |
|
Tetrahedron 2019, 75, 459-463 10.1016/j.tet.2018.1[...] |
2-(tert-butoxy)-1-((diphenylmethylene)amino)-2-oxoethan-1-ide (in DMSO)  |
DMSO | N Param.: 27.77 sN Param.: 0.47 |
|
Tetrahedron 2019, 75, 459-463 10.1016/j.tet.2018.1[...] |
1-(benzylideneamino)-2-ethoxy-2-oxoethan-1-ide (in DMSO)  |
DMSO | N Param.: 29.10 sN Param.: 0.50 |
|
Tetrahedron 2019, 75, 459-463 10.1016/j.tet.2018.1[...] |
1-((4-chlorobenzylidene)amino)-2-ethoxy-2-oxoethan-1-ide (in DMSO)  |
DMSO | N Param.: 29.02 sN Param.: 0.49 |
|
Tetrahedron 2019, 75, 459-463 10.1016/j.tet.2018.1[...] |
2-(benzylideneamino)-1-ethoxy-1-oxopropan-2-ide (in DMSO)  |
DMSO | N Param.: 30.82 sN Param.: 0.41 |
|
Tetrahedron 2019, 75, 459-463 10.1016/j.tet.2018.1[...] |
cyano((diphenylmethylene)amino)methanide  |
DMSO | N Param.: 29.50 sN Param.: 0.50 |
|
Tetrahedron 2019, 75, 459-463 10.1016/j.tet.2018.1[...] |
1-ethoxy-3-(4-nitrophenyl)-1,3-dioxopropan-2-ide (in DMSO)  |
DMSO | N Param.: 16.26 sN Param.: 0.83 |
|
J. Am. Chem. Soc. 2018, 140, 11474-11486 10.1021/jacs.8b07147 |
anion of 4-(trifluoromethyl)benzyl trifluoromethyl sulfone (in MeCN)  |
MeCN | N Param.: 16.15 sN Param.: 0.99 |
|
J. Am. Chem. Soc. 2020, 142, 8383-8402 10.1021/jacs.0c01960 |
anion of 4-cyanobenzyl trifluoromethyl sulfone (in MeCN)  |
MeCN | N Param.: 15.62 sN Param.: 0.99 |
|
J. Am. Chem. Soc. 2020, 142, 8383-8402 10.1021/jacs.0c01960 |
anion of 4-nitrobenzyl-CN (in MeCN)  |
MeCN | N Param.: 20.10 sN Param.: 0.71 |
|
J. Am. Chem. Soc. 2020, 142, 8383-8402 10.1021/jacs.0c01960 |
anion of (4-NO2-C6H4)CH2SO2Ph (in MeCN)  |
MeCN | N Param.: 19.90 sN Param.: 0.66 |
|
J. Am. Chem. Soc. 2020, 142, 8383-8402 10.1021/jacs.0c01960 |
anion of nitroethane (in DMF)  |
DMF | N Param.: 22.21 sN Param.: 0.48 |
|
Chem. Eur. J. 2008, 14, 6108-6118 10.1002/chem.200800329 |
chloro(phenylsulfonyl)methanide (in DMF)  |
DMF | N Param.: 26.64 sN Param.: 0.64 |
 |
Chem. Eur. J. 2008, 14, 6108-6118 10.1002/chem.200800329 |
enolate of 3-isochromanone (in DMSO)  |
DMSO | N Param.: 25.39 sN Param.: 0.54 |
|
J. Org. Chem. 2024, 89, 6915-6928 10.1021/acs.joc.4c00277 |
enolate of 2-coumaranone (in DMSO)  |
DMSO | N Param.: 19.60 sN Param.: 0.75 |
|
J. Org. Chem. 2024, 89, 6915-6928 10.1021/acs.joc.4c00277 |