C-Electrophiles
| Name | Solvent |
Reactivity Parameters |
Classification |
Reference (title or year) |
|---|---|---|---|---|
benzhydrylium ion Ph2CH+   |
E Param.: 5.47 |
 |
J. Am. Chem. Soc. 2012, 134, 13902-13911 10.1021/ja306522b |
|
ani(Br)2QM  |
E Param.: -8.63 |
|
Angew. Chem. Int. Ed. 2002, 41, 91-95 10.1002/1521-3773(20[...] |
|
ani(Ph)2QM  |
E Param.: -12.18 |
|
Angew. Chem. Int. Ed. 2002, 41, 91-95 10.1002/1521-3773(20[...] |
|
dma(Ph)2QM  |
E Param.: -13.39 |
|
Angew. Chem. Int. Ed. 2002, 41, 91-95 10.1002/1521-3773(20[...] |
|
tol(t-Bu)2QM  |
E Param.: -15.83 |
|
Angew. Chem. Int. Ed. 2002, 41, 91-95 10.1002/1521-3773(20[...] |
|
ani(t-Bu)2QM  |
E Param.: -16.11 |
|
Angew. Chem. Int. Ed. 2002, 41, 91-95 10.1002/1521-3773(20[...] |
|
dma(t-Bu)2QM  |
E Param.: -17.29 |
|
Angew. Chem. Int. Ed. 2002, 41, 91-95 10.1002/1521-3773(20[...] |
|
jul(t-Bu)2QM  |
E Param.: -17.90 |
|
Angew. Chem. Int. Ed. 2002, 41, 91-95 10.1002/1521-3773(20[...] |
|
(pcp)2CH+  |
E Param.: 5.48 |
|
J. Am. Chem. Soc. 2012, 134, 13902-13911 10.1021/ja306522b |
|
pfp(Ph)CH+  |
E Param.: 5.20 |
|
J. Am. Chem. Soc. 2012, 134, 13902-13911 10.1021/ja306522b |
|
(fur)2CH+  |
E Param.: -1.36 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
|
(ani)2CH+  |
E Param.: 0.00 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
|
(tol)2CH+  |
E Param.: 3.63 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
|
(pfa)2CH+  |
E Param.: -3.14 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
|
(mfa)2CH+  |
E Param.: -3.85 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
|
(dpa)2CH+  |
E Param.: -4.72 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
|
(mor)2CH+  |
E Param.: -5.53 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
|
(mpa)2CH+  |
E Param.: -5.89 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
|
(dma)2CH+  |
E Param.: -7.02 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
|
(pyr)2CH+  |
E Param.: -7.69 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
|
(thq)2CH+  |
E Param.: -8.22 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
|
(ind)2CH+  |
E Param.: -8.76 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
|
(jul)2CH+  |
E Param.: -9.45 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
|
(lil)2CH+  |
E Param.: -10.04 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
|
5-methoxyfuroxano[3,4-d]pyrimidine  |
E Param.: -8.37 |
|
J. Phys. Org. Chem. 2003, 16, 431-437 10.1002/poc.606 |
|
benzylidenemalononitrile  |
E Param.: -9.42 |
|
J. Org. Chem. 2003, 68, 6880-6886 10.1021/jo0344182 |
|
p-(methoxy)benzylidenemalononitrile  |
E Param.: -10.80 |
|
J. Org. Chem. 2003, 68, 6880-6886 10.1021/jo0344182 |
|
p-(dimethylamino)benzylidenemalononitrile  |
E Param.: -13.30 |
|
J. Org. Chem. 2003, 68, 6880-6886 10.1021/jo0344182 |
|
ani(pop)CH+  |
E Param.: 0.61 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
|
ani(Ph)CH+  |
E Param.: 2.11 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
|
ani(tol)CH+  |
E Param.: 1.48 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
|
pop(Ph)CH+  |
E Param.: 2.90 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
|
tol(Ph)CH+  |
E Param.: 4.43 |
|
J. Am. Chem. Soc. 2012, 134, 13902-13911 10.1021/ja306522b |
|
(pfp)2CH+  |
E Param.: 5.01, Deviation: ±0.05 |
|
J. Am. Chem. Soc. 2012, 134, 13902-13911 10.1021/ja306522b |
|
pop(tol)CH+  |
E Param.: 2.16, Deviation: ±0.03 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
fc(Ph)CH+  |
E Param.: -2.64 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
|
fc(ani)CH+  |
E Param.: -2.90, Deviation: ±0.09 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
fc(Me)CH+  |
E Param.: -2.57 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
fc2CH+  |
E Param.: -8.54, Deviation: ±0.53 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
C7H7+-Fe(CO)3  |
E Param.: -3.49, Deviation: ±0.17 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
C7H9+-Fe(CO)3  |
E Param.: -9.21, Deviation: ±0.36 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
C6H7+-Fe(CO)3  |
E Param.: -7.76, Deviation: ±0.31 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
C6H6OMe+-Fe(CO)3  |
E Param.: -8.94, Deviation: ±0.13 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
benzaldehyde-boron trichloride complex  |
E Param.: 1.12, Deviation: ±0.24 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
4-chlorobenzaldehyde-boron trichloride complex  |
E Param.: 1.44, Deviation: ±0.20 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
tropylium ion  |
E Param.: -3.72, Deviation: ±0.03 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
propyn-1-ylium-Co2(CO)6  |
E Param.: -0.84, Deviation: ±0.36 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
1-phenyl-proyn-ylium-Co2(CO)6  |
E Param.: -0.97, Deviation: ±0.08 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
3-phenylpropyn-1-ylium-Co2(CO)6  |
E Param.: -1.58, Deviation: ±0.58 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
3-(trimethylsilyl)propyn-1-ylium-Co2(CO)6  |
E Param.: -1.60, Deviation: ±0.34 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |