C-Electrophiles

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Name	Solvent	Reactivity Parameters	Reference (title or year)
o-chloranil (C-Cl)		E Param.: -12.02	J. Am. Chem. Soc. 2014, 136, 11499-11512 10.1021/ja505613b
3-benzylidene-1-methyl-3H-indol-1-ium ion		E Param.: -1.80	J. Org. Chem. 2015, 80, 8643-8656 10.1021/acs.joc.5b01298
1-methyl-3-(4-methylbenzylidene)-3H-indol-1-ium ion		E Param.: -2.19	J. Org. Chem. 2015, 80, 8643-8656 10.1021/acs.joc.5b01298
3-(4-methoxybenzylidene)-1-methyl-3H-indol-1-ium iom		E Param.: -3.02	J. Org. Chem. 2015, 80, 8643-8656 10.1021/acs.joc.5b01298
3-(4-(dimethylamino)benzylidene)-1-methyl-3H-indol-1-ium ion		E Param.: -6.26	J. Org. Chem. 2015, 80, 8643-8656 10.1021/acs.joc.5b01298
1-methyl-3-((julolidin-9-yl)methylene)-3H-indol-1-ium ion		E Param.: -7.79	J. Org. Chem. 2015, 80, 8643-8656 10.1021/acs.joc.5b01298
(E)-2-methyl-3-(4-methylbenzylidene)-3H-indol-1-ium ion		E Param.: -5.15	J. Org. Chem. 2015, 80, 8643-8656 10.1021/acs.joc.5b01298
(E)-1,2-dimethyl-3-(4-methylbenzylidene)-3H-indol-1-ium ion		E Param.: -5.05	J. Org. Chem. 2015, 80, 8643-8656 10.1021/acs.joc.5b01298
(E)-3-benzylidene-1,2-dimethyl-3H-indol-1-ium ion		E Param.: -4.96	J. Org. Chem. 2015, 80, 8643-8656 10.1021/acs.joc.5b01298
bis(1-methylindol-3-yl)methylium ion		E Param.: -5.99	J. Org. Chem. 2015, 80, 8643-8656 10.1021/acs.joc.5b01298
bis(5-methoxy-1-methylindol-3-yl)methylium ion		E Param.: -6.90	J. Org. Chem. 2015, 80, 8643-8656 10.1021/acs.joc.5b01298
bis(1,2-dimethylindol-3-yl)methylium ion		E Param.: -10.23	J. Org. Chem. 2015, 80, 8643-8656 10.1021/acs.joc.5b01298
dibenzo[a,d]tropylium ion	dichloromethane	E Param.: -0.63	Liebigs Ann. 1995, , 2005-2009 10.1002/jlac.1995199[...]
ethenesulfonyl fluoride (ESF)	DMSO	E Param.: -12.09	Angew. Chem. Int. Ed. 2016, 55, 12664-12667 10.1002/anie.201601875
2-phenylethene-1-sulfonyl fluoride	DMSO	E Param.: -16.63	Angew. Chem. Int. Ed. 2016, 55, 12664-12667 10.1002/anie.201601875
(E)-2-(tert-butyl)-3-(4-methylbenzylidene)-3H-indol-1-ium	dichloromethane	E Param.: -5.06	Eur. J. Org. Chem. 2016, , 4050-4058 10.1002/ejoc.201600572
9-phenyl-9H-fluoren-9-ylium	dichloromethane	E Param.: 2.41	Chem. Eur. J. 2017, 23, 623-630 10.1002/chem.201603963
9-(4-methoxyphenyl)-9H-fluoren-9-ylium	dichloromethane	E Param.: 0.85	Chem. Eur. J. 2017, 23, 623-630 10.1002/chem.201603963
9-(4-(dimethylamino)phenyl)-9H-fluoren-9-ylium	dichloromethane	E Param.: -4.51	Chem. Eur. J. 2017, 23, 623-630 10.1002/chem.201603963
(E)-4-phenylbut-3-en-2-one (in DMSO)	DMSO	E Param.: -23.01	J. Am. Chem. Soc. 2017, 139, 13318-13329 10.1021/jacs.7b05106
cinnamonitrile (in DMSO)	DMSO	E Param.: -24.60	J. Am. Chem. Soc. 2017, 139, 13318-13329 10.1021/jacs.7b05106
methyl prop-2-enoate (in DMSO)	DMSO	E Param.: -18.84	J. Am. Chem. Soc. 2017, 139, 13318-13329 10.1021/jacs.7b05106
ethyl prop-2-enoate (in DMSO)	DMSO	E Param.: -19.07	J. Am. Chem. Soc. 2017, 139, 13318-13329 10.1021/jacs.7b05106
tert-butyl prop-2-enoate (in DMSO)	DMSO	E Param.: -20.22	J. Am. Chem. Soc. 2017, 139, 13318-13329 10.1021/jacs.7b05106
N,N-dimethylprop-2-enamide (in DMSO)	DMSO	E Param.: -23.54	J. Am. Chem. Soc. 2017, 139, 13318-13329 10.1021/jacs.7b05106
ethenylsulfonylbenzene (in DMSO)	DMSO	E Param.: -18.36	J. Am. Chem. Soc. 2017, 139, 13318-13329 10.1021/jacs.7b05106
acrylonitrile (in DMSO)	DMSO	E Param.: -19.05	J. Am. Chem. Soc. 2017, 139, 13318-13329 10.1021/jacs.7b05106
but-3-en-2-one (in DMSO)	DMSO	E Param.: -16.76	J. Am. Chem. Soc. 2017, 139, 13318-13329 10.1021/jacs.7b05106
1-phenylprop-2-en-1-one (in DMSO)	DMSO	E Param.: -15.25	J. Am. Chem. Soc. 2017, 139, 13318-13329 10.1021/jacs.7b05106
ethyl 2-methylprop-2-enoate (in DMSO)	DMSO	E Param.: -22.77	J. Am. Chem. Soc. 2017, 139, 13318-13329 10.1021/jacs.7b05106
ethyl (E)-but-2-enoate (in DMSO)	DMSO	E Param.: -23.59	J. Am. Chem. Soc. 2017, 139, 13318-13329 10.1021/jacs.7b05106
ethyl cinnamate (in DMSO)	DMSO	E Param.: -24.52	J. Am. Chem. Soc. 2017, 139, 13318-13329 10.1021/jacs.7b05106
(E)-1-methyl-4-(styrylsulfonyl)benzene (in DMSO)	DMSO	E Param.: -24.69	J. Am. Chem. Soc. 2017, 139, 13318-13329 10.1021/jacs.7b05106
2-cinnamoyl-3-methyl-1-(perfluorophenyl)-1H-imidazol-3-ium	DMSO	E Param.: -10.09	Top. Catal. 2018, 61, 585-590 10.1007/s11244-018-0[...]
1-(tert-butyl)-2-cinnamoyl-3-methyl-1H-imidazol-3-ium	DMSO	E Param.: -11.80	Top. Catal. 2018, 61, 585-590 10.1007/s11244-018-0[...]
2-cinnamoyl-1-mesityl-3-methyl-1H-imidazol-3-ium	DMSO	E Param.: -11.48	Top. Catal. 2018, 61, 585-590 10.1007/s11244-018-0[...]
2-cinnamoyl-1-(4-methoxyphenyl)-3-methyl-1H-imidazol-3-ium	DMSO	E Param.: -11.79	Top. Catal. 2018, 61, 585-590 10.1007/s11244-018-0[...]
2-cinnamoyl-1-(2,6-dimethoxyphenyl)-3-methyl-1H-imidazol-3-ium	DMSO	E Param.: -12.02	Top. Catal. 2018, 61, 585-590 10.1007/s11244-018-0[...]
cyclobutanone (in DMSO)	DMSO	E Param.: -17.50	J. Am. Chem. Soc. 2018, 140, 5500-5515 10.1021/jacs.8b01657
cyclopentanone (in DMSO)	DMSO	E Param.: -21.00	J. Am. Chem. Soc. 2018, 140, 5500-5515 10.1021/jacs.8b01657
cyclohexanone (in DMSO)	DMSO	E Param.: -19.90	J. Am. Chem. Soc. 2018, 140, 5500-5515 10.1021/jacs.8b01657
cycloheptanone (in DMSO)	DMSO	E Param.: -22.10	J. Am. Chem. Soc. 2018, 140, 5500-5515 10.1021/jacs.8b01657
1-methylpiperidin-4-one (in DMSO)	DMSO	E Param.: -18.40	J. Am. Chem. Soc. 2018, 140, 5500-5515 10.1021/jacs.8b01657
oxan-4-one (in DMSO)	DMSO	E Param.: -17.90	J. Am. Chem. Soc. 2018, 140, 5500-5515 10.1021/jacs.8b01657
thian-4-one (in DMSO)	DMSO	E Param.: -16.90	J. Am. Chem. Soc. 2018, 140, 5500-5515 10.1021/jacs.8b01657
1,4-dioxaspiro[4.5]decan-8-one (in DMSO)	DMSO	E Param.: -18.20	J. Am. Chem. Soc. 2018, 140, 5500-5515 10.1021/jacs.8b01657
pentan-2-one (in DMSO)	DMSO	E Param.: -22.30	J. Am. Chem. Soc. 2018, 140, 5500-5515 10.1021/jacs.8b01657
1-methylsulfanylpropan-2-one (in DMSO)	DMSO	E Param.: -15.60	J. Am. Chem. Soc. 2018, 140, 5500-5515 10.1021/jacs.8b01657
3-methylcyclopentenone	DMSO	E Param.: -28.90	Chem. Sci. 2021, 12, 4850-4865 10.1039/D0SC06628A
2-methylcyclopentenone	DMSO	E Param.: -22.10	Chem. Sci. 2021, 12, 4850-4865 10.1039/D0SC06628A