Electrophiles
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« Back Forward » Found 355 molecules, displaying page 2 of 4 Results per page
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| Name | Solvent |
Reactivity Parameters |
Classification |
Reference (title or year) |
|---|---|---|---|---|
2,6-di-tert.butyl-4-(3-fluorobenzylidene)cyclohexa-2,5-dienone  |
E Param.: -15.03 |  | Eur. J. Org. Chem. 2009, , 3203-3211 10.1002/ejoc.200900299 | |
1,2-diaza-1,3-diene 1c |
DMSO | E Param.: -14.91 | | Chem. Eur. J. 2010, 16, 12008-12016 10.1002/chem.201000828 |
1,2-diaza-1,3-diene 1e |
MeOH | E Param.: -14.90 | | Chem. Eur. J. 2010, 16, 12008-12016 10.1002/chem.201000828 |
3-nitro-1-tosyl-1H-indole |
E Param.: -14.87 | | Chem. Commun. 2021, 57, 10071-10074 10.1039/d1cc04074j | |
4-methoxy-<i>trans-beta</i>-nitrostyrene |
E Param.: -14.70 | | J. Org. Chem. 2011, 76, 9370-9378 10.1021/jo201678u | |
jul-indan-1,3-dione |
E Param.: -14.68 | | Org. Biomol. Chem. 2007, 5, 3020-3026 10.1039/b708025e | |
4-bromo-3-nitro-1-tosyl-1H-indole |
E Param.: -14.60 | | Chem. Commun. 2021, 57, 10071-10074 10.1039/d1cc04074j | |
2-(4-methoxybenzylidene)-1,3-dithiane 1,1,3,3-tetraoxide |
DMSO | E Param.: -14.55 | | Chem. Asian J. 2012, 7, 1401-1407 10.1002/asia.201101046 |
((2-(2-iodophenyl)propan-2-yl)oxy)(trifluoromethyl)sulfane |
E Param.: -14.52 | | Angew. Chem. Int. Ed. 2018, 57, 12690-12695 10.1002/anie.201805859 | |
2,6-di-tert.butyl-4-(3,5-difluorobenzylidene)cyclohexa-2,5-dienone |
E Param.: -14.50 | | Eur. J. Org. Chem. 2009, , 3203-3211 10.1002/ejoc.200900299 | |
[(1,3-Diarylallyl)Pd(PPh3)2]+ (Aryl = 4-(dimethylamino)phenyl) |
E Param.: -14.46 | | Organometallics 2012, 31, 2416-2424 10.1021/om3000357 | |
2,6-di-tert.butyl-4-(4-nitrobenzylidene)cyclohexa-2,5-dienone |
E Param.: -14.36 | | Eur. J. Org. Chem. 2009, , 3203-3211 10.1002/ejoc.200900299 | |
4-methyl-<i>trans-beta</i>-nitrostyrene |
E Param.: -14.23 | | J. Org. Chem. 2011, 76, 9370-9378 10.1021/jo201678u | |
(E)-tert-butyl benzylidenecarbamate (in DMSO) |
DMSO | E Param.: -14.22 | | J. Am. Chem. Soc. 2011, 133, 8240-8251 10.1021/ja200820m |
[(1,3-Diarylallyl)Pd(PPh3)2]+ (Aryl = 3,5-difluorophenyl) |
E Param.: -14.21 | | Organometallics 2012, 31, 2416-2424 10.1021/om3000357 | |
[(1,3-Diarylallyl)Pd(PPh3)2]+ (Aryl = Ph) |
E Param.: -14.14 | | Organometallics 2012, 31, 2416-2424 10.1021/om3000357 | |
ethyl 3-nitro-1H-indole-1-carboxylate |
E Param.: -14.10 | | Chem. Commun. 2021, 57, 10071-10074 10.1039/d1cc04074j | |
N-methyl maleimide |
DMSO | E Param.: -14.07 | | Eur. J. Org. Chem. 2014, , 2956-2963 10.1002/ejoc.201301779 |
jul Meldrum's acid |
E Param.: -13.97 | | J. Org. Chem. 2008, 73, 2738-2745 10.1021/jo702590s | |
1,2-diaza-1,3-diene 1b |
DMSO | E Param.: -13.90 | | Chem. Eur. J. 2010, 16, 12008-12016 10.1002/chem.201000828 |
(2-(4-methoxyphenyl)ethene-1,1-diyldisulfonyl)dibenzene |
DMSO | E Param.: -13.88 | | Chem. Asian J. 2012, 7, 1401-1407 10.1002/asia.201101046 |
<i>trans-beta</i>-nitrostyrene |
E Param.: -13.85 | | J. Org. Chem. 2011, 76, 9370-9378 10.1021/jo201678u | |
julBBS |
E Param.: -13.84 | | J. Org. Chem. 2007, 72, 9170-9180 10.1021/jo071273g | |
p-chloranil (C-Cl) |
E Param.: -13.84 | | J. Am. Chem. Soc. 2014, 136, 11499-11512 10.1021/ja505613b | |
((2-phenylpropan-2-yl)oxy)(trifluoromethyl)sulfane |
E Param.: -13.77 | | Angew. Chem. Int. Ed. 2018, 57, 12690-12695 10.1002/anie.201805859 | |
2-(p-(dimethylamino)benzylidene)-indan-1,3-dione |
E Param.: -13.56 | | Org. Biomol. Chem. 2007, 5, 3020-3026 10.1039/b708025e | |
N-methyl-N-((trifluoromethyl)thio)-p-toluenesulfonamide |
E Param.: -13.44 | | Angew. Chem. Int. Ed. 2018, 57, 12690-12695 10.1002/anie.201805859 | |
dma(Ph)2QM |
E Param.: -13.39 | | Angew. Chem. Int. Ed. 2002, 41, 91-95 10.1002/1521-3773(20[...] | |
Umemoto I (tetrafluoroborate) |
E Param.: -13.39 | | Eur. J. Org. Chem. 2024, 27, e202400085 10.1002/ejoc.202400085 | |
4-bromo-<i>trans-beta</i>-nitrostyrene |
E Param.: -13.37 | | J. Org. Chem. 2011, 76, 9370-9378 10.1021/jo201678u | |
p-(dimethylamino)benzylidenemalononitrile |
E Param.: -13.30 | | J. Org. Chem. 2003, 68, 6880-6886 10.1021/jo0344182 | |
1,2-diaza-1,3-diene 1a |
DMSO | E Param.: -13.28 | | Chem. Eur. J. 2010, 16, 12008-12016 10.1002/chem.201000828 |
1,3,5-trinitrobenzene |
E Param.: -13.19 | | J. Org. Chem. 2005, 70, 6242-6253 10.1021/jo0505526 | |
Umemoto I (triflate) |
E Param.: -13.08 | | Eur. J. Org. Chem. 2024, 27, e202400085 10.1002/ejoc.202400085 | |
(E)-N-(4-methoxybenzylidene)-4-methylbenzenesulfonamide (in DMSO) |
DMSO | E Param.: -13.05 | | J. Am. Chem. Soc. 2011, 133, 8240-8251 10.1021/ja200820m |
2-(4-methoxybenzylidene)benzo[d][1,3]dithiole 1,1,3,3-tetraoxide |
DMSO | E Param.: -13.02 | | Chem. Asian J. 2012, 7, 1401-1407 10.1002/asia.201101046 |
(2-phenylethene-1,1-diyldisulfonyl)dibenzene |
DMSO | E Param.: -12.93 | | Chem. Asian J. 2012, 7, 1401-1407 10.1002/asia.201101046 |
benzaldehyde (in DMSO) |
DMSO | E Param.: -12.90 | | J. Am. Chem. Soc. 2018, 140, 5500-5515 10.1021/jacs.8b01657 |
3,6-dinitro-1-tosyl-1H-indole |
E Param.: -12.90 | | Chem. Commun. 2021, 57, 10071-10074 10.1039/d1cc04074j | |
Umemoto II (triflate) |
E Param.: -12.80 | | Eur. J. Org. Chem. 2024, 27, e202400085 10.1002/ejoc.202400085 | |
dmaBBS |
E Param.: -12.76 | | J. Org. Chem. 2007, 72, 9170-9180 10.1021/jo071273g | |
p-(dimethylamino)benzylidene Meldrum's acid |
E Param.: -12.76 | | J. Org. Chem. 2008, 73, 2738-2745 10.1021/jo702590s | |
4-cyano-<i>trans-beta</i>-nitrostyrene |
E Param.: -12.61 | | J. Org. Chem. 2011, 76, 9370-9378 10.1021/jo201678u | |
N-(trifluoromethyl)thio)succinimide |
E Param.: -12.56 | | Angew. Chem. Int. Ed. 2018, 57, 12690-12695 10.1002/anie.201805859 | |
4-nitro-<i>trans-beta</i>-nitrostyrene |
E Param.: -12.37 | | J. Org. Chem. 2011, 76, 9370-9378 10.1021/jo201678u | |
2,4-dinitrothiophene |
E Param.: -12.33 | | J. Org. Chem. 2005, 70, 6242-6253 10.1021/jo0505526 | |
2,5-dichloroquinone (C-H) |
E Param.: -12.28 | | J. Am. Chem. Soc. 2014, 136, 11499-11512 10.1021/ja505613b | |
di-tert-butyl azodicarboxylate |
MeCN | E Param.: -12.23 | | Chem. Eur. J. 2010, 16, 11670-11677 10.1002/chem.201001598 |
ani(Ph)2QM |
E Param.: -12.18 | | Angew. Chem. Int. Ed. 2002, 41, 91-95 10.1002/1521-3773(20[...] | |
p-chloranil (C=O) |
E Param.: -12.13 | | J. Am. Chem. Soc. 2014, 136, 11499-11512 10.1021/ja505613b | |
ethenesulfonyl fluoride (ESF) |
DMSO | E Param.: -12.09 | | Angew. Chem. Int. Ed. 2016, 55, 12664-12667 10.1002/anie.201601875 |
o-chloranil (C-Cl) |
E Param.: -12.02 | | J. Am. Chem. Soc. 2014, 136, 11499-11512 10.1021/ja505613b | |
2-cinnamoyl-1-(2,6-dimethoxyphenyl)-3-methyl-1H-imidazol-3-ium |
DMSO | E Param.: -12.02 | | Top. Catal. 2018, 61, 585-590 10.1007/s11244-018-0[...] |
N-(trifluoromethyl)thio)phthalimide |
E Param.: -11.92 | | Angew. Chem. Int. Ed. 2018, 57, 12690-12695 10.1002/anie.201805859 | |
jul(S)BBS |
E Param.: -11.89 | | J. Org. Chem. 2007, 72, 9170-9180 10.1021/jo071273g | |
2,6-diphenyl-4-benzylidenecyclohexa-2,5-dienone |
E Param.: -11.87 | | Eur. J. Org. Chem. 2009, , 3203-3211 10.1002/ejoc.200900299 | |
N-(difluoromethyl)thio)phthalimide |
E Param.: -11.86 | | Angew. Chem. Int. Ed. 2018, 57, 12690-12695 10.1002/anie.201805859 | |
1-(tert-butyl)-2-cinnamoyl-3-methyl-1H-imidazol-3-ium |
DMSO | E Param.: -11.80 | | Top. Catal. 2018, 61, 585-590 10.1007/s11244-018-0[...] |
2-cinnamoyl-1-(4-methoxyphenyl)-3-methyl-1H-imidazol-3-ium |
DMSO | E Param.: -11.79 | | Top. Catal. 2018, 61, 585-590 10.1007/s11244-018-0[...] |
2-benzylidenebenzo[d][1,3]dithiole 1,1,3,3-tetraoxide |
DMSO | E Param.: -11.78 | | Chem. Asian J. 2012, 7, 1401-1407 10.1002/asia.201101046 |
2,6-di-tert-butyl-4-(2,2,2-trifluoroethylidene)cyclohexa-2,5-dien-1-one |
DMSO | E Param.: -11.68 | | Eur. J. Org. Chem. 2020, , 3812-3817 10.1002/ejoc.202000295 |
2-cinnamoyl-1,3-dimethyl-1H-imidazol-3-ium |
DMSO | E Param.: -11.52 | | Angew. Chem. Int. Ed. 2012, 51, 5234-5238 10.1002/anie.201109042 |
(E)-N-benzylidene-4-methylbenzenesulfonamide (in DMSO) |
DMSO | E Param.: -11.50 | | J. Am. Chem. Soc. 2011, 133, 8240-8251 10.1021/ja200820m |
2-cinnamoyl-1-mesityl-3-methyl-1H-imidazol-3-ium |
DMSO | E Param.: -11.48 | | Top. Catal. 2018, 61, 585-590 10.1007/s11244-018-0[...] |
2-(p-methoxybenzylidene)-indan-1,3-dione |
E Param.: -11.32 | | Org. Biomol. Chem. 2007, 5, 3020-3026 10.1039/b708025e | |
maleic anhydride |
DMSO | E Param.: -11.31 | | Eur. J. Org. Chem. 2014, , 2956-2963 10.1002/ejoc.201301779 |
(4-NMe2)3-tritylium ion (= Crystal violet) |
E Param.: -11.26 |  | J. Am. Chem. Soc. 2003, 125, 286-295 10.1021/ja021010y | |
2,2,4-trichloro-1(2H)-naphthalenone |
MeCN | E Param.: -11.24 | | Org. Lett. 2010, 12, 2238-2241 10.1021/ol100592j |
dicarbonyl(cyclopentadienyl)propene-iron(II) |
E Param.: -11.20 | | Helv. Chim. Acta 2005, 88, 1754-1768 10.1002/hlca.200590137 | |
p-fluoranil (C-F) |
E Param.: -11.12 | | J. Am. Chem. Soc. 2014, 136, 11499-11512 10.1021/ja505613b | |
p-(methoxy)benzylidenemalononitrile |
E Param.: -10.80 | | J. Org. Chem. 2003, 68, 6880-6886 10.1021/jo0344182 | |
dma(S)BBS |
E Param.: -10.73 | | J. Org. Chem. 2007, 72, 9170-9180 10.1021/jo071273g | |
diisopropyl azodicarboxylate |
MeCN | E Param.: -10.71 | | Chem. Eur. J. 2010, 16, 11670-11677 10.1002/chem.201001598 |
p-AniCH=N+Me2 (in MeCN) |
MeCN | E Param.: -10.69 | | J. Am. Chem. Soc. 2013, 135, 6579-6587 10.1021/ja401106x |
(S,E)-5-benzyl-1-((E)-3-(4-(dimethylamino)phenyl)allylidene)-2,2,3-trimethyl-4-oxoimidazolidin-1-ium |
dichloromethane | E Param.: -10.60 | | Asian J. Org. Chem. 2014, 3, 550-555 10.1002/ajoc.201402009 |
5,7,7-trichloro-8(7H)-quinolinone |
MeCN | E Param.: -10.48 | | Org. Lett. 2010, 12, 2238-2241 10.1021/ol100592j |
N-fluoro-2,4,6-trimethylpyridinium tetrafluoroborate |
E Param.: -10.46 | | J. Am. Chem. Soc. 2018, 140, 11474-11486 10.1021/jacs.8b07147 | |
aniBBS |
E Param.: -10.37 | | J. Org. Chem. 2007, 72, 9170-9180 10.1021/jo071273g | |
pipN+=CH-CH-Ph |
E Param.: -10.30 | | Angew. Chem. Int. Ed. 2008, 47, 8723-8726 10.1002/anie.200802889 | |
(4-NMe2)2-tritylium ion (= Malachite green) |
E Param.: -10.29 | | J. Am. Chem. Soc. 2003, 125, 286-295 10.1021/ja021010y | |
p-(methoxy)benzylidene Meldrum's acid |
E Param.: -10.28 | | J. Org. Chem. 2008, 73, 2738-2745 10.1021/jo702590s | |
bis(1,2-dimethylindol-3-yl)methylium ion |
E Param.: -10.23 | | J. Org. Chem. 2015, 80, 8643-8656 10.1021/acs.joc.5b01298 | |
diethyl azodicarboxylate |
MeCN | E Param.: -10.15 | | Chem. Eur. J. 2010, 16, 11670-11677 10.1002/chem.201001598 |
Pd-allyl cation |
E Param.: -10.11 | | Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c | |
2-benzylidene-indan-1,3-dione |
E Param.: -10.11 | | Org. Biomol. Chem. 2007, 5, 3020-3026 10.1039/b708025e | |
2-cinnamoyl-3-methyl-1-(perfluorophenyl)-1H-imidazol-3-ium |
DMSO | E Param.: -10.09 | | Top. Catal. 2018, 61, 585-590 10.1007/s11244-018-0[...] |
(lil)2CH+ |
E Param.: -10.04 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y | |
N-fluoropyridinium tetrafluoroborate |
E Param.: -9.89 | | J. Am. Chem. Soc. 2018, 140, 11474-11486 10.1021/jacs.8b07147 | |
1,1,3-tris(4-(dimethylamino)phenyl)allylium ion |
E Param.: -9.84 | | Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c | |
pyrN+=CH-CH-Ph |
E Param.: -9.80 | | Angew. Chem. Int. Ed. 2008, 47, 8723-8726 10.1002/anie.200802889 | |
bis(julidin-9-yl)allylium ion |
E Param.: -9.78 | | J. Org. Chem. 2011, 76, 9391-9408 10.1021/jo201668w | |
pTolCH=N+CH2 (in MeCN) |
MeCN | E Param.: -9.64 | | J. Am. Chem. Soc. 2013, 135, 6579-6587 10.1021/ja401106x |
PhCH=N+(CH2)5 (in MeCN) |
MeCN | E Param.: -9.60 | | J. Am. Chem. Soc. 2013, 135, 6579-6587 10.1021/ja401106x |
indolecarboxylate derived iminium ion |
dichloromethane | E Param.: -9.50 | | Angew. Chem. Int. Ed. 2009, 48, 5034-5037 10.1002/anie.200900933 |
(jul)2CH+ |
E Param.: -9.45 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y | |
benzylidenemalononitrile |
E Param.: -9.42 | | J. Org. Chem. 2003, 68, 6880-6886 10.1021/jo0344182 | |
p-fluoranil (C=O) |
E Param.: -9.37 | | J. Am. Chem. Soc. 2014, 136, 11499-11512 10.1021/ja505613b | |
PhCH=N+(CH2)4 (in MeCN) |
MeCN | E Param.: -9.35 | | J. Am. Chem. Soc. 2013, 135, 6579-6587 10.1021/ja401106x |
PhCH=N+Me2 (in MeCN) |
MeCN | E Param.: -9.27 | | J. Am. Chem. Soc. 2013, 135, 6579-6587 10.1021/ja401106x |
C7H9+-Fe(CO)3 |
E Param.: -9.21 | | Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |