Electrophiles
1 | 2 | 3 | 4
« Back Forward » Found 355 molecules, displaying page 3 of 4 Results per page
10|50|100|all
| Name | Solvent |
Reactivity Parameters |
Classification |
Reference (title or year) |
|---|---|---|---|---|
jul(S)BBS  |
E Param.: -11.89 |  | J. Org. Chem. 2007, 72, 9170-9180 10.1021/jo071273g | |
N-(trifluoromethyl)thio)phthalimide |
E Param.: -11.92 | | Angew. Chem. Int. Ed. 2018, 57, 12690-12695 10.1002/anie.201805859 | |
o-chloranil (C-Cl) |
E Param.: -12.02 | | J. Am. Chem. Soc. 2014, 136, 11499-11512 10.1021/ja505613b | |
2-cinnamoyl-1-(2,6-dimethoxyphenyl)-3-methyl-1H-imidazol-3-ium |
DMSO | E Param.: -12.02 | | Top. Catal. 2018, 61, 585-590 10.1007/s11244-018-0[...] |
ethenesulfonyl fluoride (ESF) |
DMSO | E Param.: -12.09 | | Angew. Chem. Int. Ed. 2016, 55, 12664-12667 10.1002/anie.201601875 |
p-chloranil (C=O) |
E Param.: -12.13 | | J. Am. Chem. Soc. 2014, 136, 11499-11512 10.1021/ja505613b | |
ani(Ph)2QM |
E Param.: -12.18 | | Angew. Chem. Int. Ed. 2002, 41, 91-95 10.1002/1521-3773(20[...] | |
di-tert-butyl azodicarboxylate |
MeCN | E Param.: -12.23 | | Chem. Eur. J. 2010, 16, 11670-11677 10.1002/chem.201001598 |
2,5-dichloroquinone (C-H) |
E Param.: -12.28 | | J. Am. Chem. Soc. 2014, 136, 11499-11512 10.1021/ja505613b | |
2,4-dinitrothiophene |
E Param.: -12.33 | | J. Org. Chem. 2005, 70, 6242-6253 10.1021/jo0505526 | |
4-nitro-<i>trans-beta</i>-nitrostyrene |
E Param.: -12.37 | | J. Org. Chem. 2011, 76, 9370-9378 10.1021/jo201678u | |
N-(trifluoromethyl)thio)succinimide |
E Param.: -12.56 | | Angew. Chem. Int. Ed. 2018, 57, 12690-12695 10.1002/anie.201805859 | |
4-cyano-<i>trans-beta</i>-nitrostyrene |
E Param.: -12.61 | | J. Org. Chem. 2011, 76, 9370-9378 10.1021/jo201678u | |
dmaBBS |
E Param.: -12.76 | | J. Org. Chem. 2007, 72, 9170-9180 10.1021/jo071273g | |
p-(dimethylamino)benzylidene Meldrum's acid |
E Param.: -12.76 | | J. Org. Chem. 2008, 73, 2738-2745 10.1021/jo702590s | |
Umemoto II (triflate) |
E Param.: -12.80 | | Eur. J. Org. Chem. 2024, 27, e202400085 10.1002/ejoc.202400085 | |
benzaldehyde (in DMSO) |
DMSO | E Param.: -12.90 | | J. Am. Chem. Soc. 2018, 140, 5500-5515 10.1021/jacs.8b01657 |
3,6-dinitro-1-tosyl-1H-indole |
E Param.: -12.90 | | Chem. Commun. 2021, 57, 10071-10074 10.1039/d1cc04074j | |
(2-phenylethene-1,1-diyldisulfonyl)dibenzene |
DMSO | E Param.: -12.93 | | Chem. Asian J. 2012, 7, 1401-1407 10.1002/asia.201101046 |
2-(4-methoxybenzylidene)benzo[d][1,3]dithiole 1,1,3,3-tetraoxide |
DMSO | E Param.: -13.02 | | Chem. Asian J. 2012, 7, 1401-1407 10.1002/asia.201101046 |
(E)-N-(4-methoxybenzylidene)-4-methylbenzenesulfonamide (in DMSO) |
DMSO | E Param.: -13.05 | | J. Am. Chem. Soc. 2011, 133, 8240-8251 10.1021/ja200820m |
Umemoto I (triflate) |
E Param.: -13.08 | | Eur. J. Org. Chem. 2024, 27, e202400085 10.1002/ejoc.202400085 | |
1,3,5-trinitrobenzene |
E Param.: -13.19 | | J. Org. Chem. 2005, 70, 6242-6253 10.1021/jo0505526 | |
1,2-diaza-1,3-diene 1a |
DMSO | E Param.: -13.28 | | Chem. Eur. J. 2010, 16, 12008-12016 10.1002/chem.201000828 |
p-(dimethylamino)benzylidenemalononitrile |
E Param.: -13.30 | | J. Org. Chem. 2003, 68, 6880-6886 10.1021/jo0344182 | |
4-bromo-<i>trans-beta</i>-nitrostyrene |
E Param.: -13.37 | | J. Org. Chem. 2011, 76, 9370-9378 10.1021/jo201678u | |
dma(Ph)2QM |
E Param.: -13.39 | | Angew. Chem. Int. Ed. 2002, 41, 91-95 10.1002/1521-3773(20[...] | |
Umemoto I (tetrafluoroborate) |
E Param.: -13.39 | | Eur. J. Org. Chem. 2024, 27, e202400085 10.1002/ejoc.202400085 | |
N-methyl-N-((trifluoromethyl)thio)-p-toluenesulfonamide |
E Param.: -13.44 | | Angew. Chem. Int. Ed. 2018, 57, 12690-12695 10.1002/anie.201805859 | |
2-(p-(dimethylamino)benzylidene)-indan-1,3-dione |
E Param.: -13.56 | | Org. Biomol. Chem. 2007, 5, 3020-3026 10.1039/b708025e | |
((2-phenylpropan-2-yl)oxy)(trifluoromethyl)sulfane |
E Param.: -13.77 | | Angew. Chem. Int. Ed. 2018, 57, 12690-12695 10.1002/anie.201805859 | |
julBBS |
E Param.: -13.84 | | J. Org. Chem. 2007, 72, 9170-9180 10.1021/jo071273g | |
p-chloranil (C-Cl) |
E Param.: -13.84 | | J. Am. Chem. Soc. 2014, 136, 11499-11512 10.1021/ja505613b | |
<i>trans-beta</i>-nitrostyrene |
E Param.: -13.85 | | J. Org. Chem. 2011, 76, 9370-9378 10.1021/jo201678u | |
(2-(4-methoxyphenyl)ethene-1,1-diyldisulfonyl)dibenzene |
DMSO | E Param.: -13.88 | | Chem. Asian J. 2012, 7, 1401-1407 10.1002/asia.201101046 |
1,2-diaza-1,3-diene 1b |
DMSO | E Param.: -13.90 | | Chem. Eur. J. 2010, 16, 12008-12016 10.1002/chem.201000828 |
jul Meldrum's acid |
E Param.: -13.97 | | J. Org. Chem. 2008, 73, 2738-2745 10.1021/jo702590s | |
N-methyl maleimide |
DMSO | E Param.: -14.07 | | Eur. J. Org. Chem. 2014, , 2956-2963 10.1002/ejoc.201301779 |
ethyl 3-nitro-1H-indole-1-carboxylate |
E Param.: -14.10 | | Chem. Commun. 2021, 57, 10071-10074 10.1039/d1cc04074j | |
[(1,3-Diarylallyl)Pd(PPh3)2]+ (Aryl = Ph) |
E Param.: -14.14 | | Organometallics 2012, 31, 2416-2424 10.1021/om3000357 | |
[(1,3-Diarylallyl)Pd(PPh3)2]+ (Aryl = 3,5-difluorophenyl) |
E Param.: -14.21 | | Organometallics 2012, 31, 2416-2424 10.1021/om3000357 | |
(E)-tert-butyl benzylidenecarbamate (in DMSO) |
DMSO | E Param.: -14.22 | | J. Am. Chem. Soc. 2011, 133, 8240-8251 10.1021/ja200820m |
4-methyl-<i>trans-beta</i>-nitrostyrene |
E Param.: -14.23 | | J. Org. Chem. 2011, 76, 9370-9378 10.1021/jo201678u | |
2,6-di-tert.butyl-4-(4-nitrobenzylidene)cyclohexa-2,5-dienone |
E Param.: -14.36 | | Eur. J. Org. Chem. 2009, , 3203-3211 10.1002/ejoc.200900299 | |
[(1,3-Diarylallyl)Pd(PPh3)2]+ (Aryl = 4-(dimethylamino)phenyl) |
E Param.: -14.46 | | Organometallics 2012, 31, 2416-2424 10.1021/om3000357 | |
2,6-di-tert.butyl-4-(3,5-difluorobenzylidene)cyclohexa-2,5-dienone |
E Param.: -14.50 | | Eur. J. Org. Chem. 2009, , 3203-3211 10.1002/ejoc.200900299 | |
((2-(2-iodophenyl)propan-2-yl)oxy)(trifluoromethyl)sulfane |
E Param.: -14.52 | | Angew. Chem. Int. Ed. 2018, 57, 12690-12695 10.1002/anie.201805859 | |
2-(4-methoxybenzylidene)-1,3-dithiane 1,1,3,3-tetraoxide |
DMSO | E Param.: -14.55 | | Chem. Asian J. 2012, 7, 1401-1407 10.1002/asia.201101046 |
4-bromo-3-nitro-1-tosyl-1H-indole |
E Param.: -14.60 | | Chem. Commun. 2021, 57, 10071-10074 10.1039/d1cc04074j | |
jul-indan-1,3-dione |
E Param.: -14.68 | | Org. Biomol. Chem. 2007, 5, 3020-3026 10.1039/b708025e | |
4-methoxy-<i>trans-beta</i>-nitrostyrene |
E Param.: -14.70 | | J. Org. Chem. 2011, 76, 9370-9378 10.1021/jo201678u | |
3-nitro-1-tosyl-1H-indole |
E Param.: -14.87 | | Chem. Commun. 2021, 57, 10071-10074 10.1039/d1cc04074j | |
1,2-diaza-1,3-diene 1e |
MeOH | E Param.: -14.90 | | Chem. Eur. J. 2010, 16, 12008-12016 10.1002/chem.201000828 |
1,2-diaza-1,3-diene 1c |
DMSO | E Param.: -14.91 | | Chem. Eur. J. 2010, 16, 12008-12016 10.1002/chem.201000828 |
2,6-di-tert.butyl-4-(3-fluorobenzylidene)cyclohexa-2,5-dienone |
E Param.: -15.03 | | Eur. J. Org. Chem. 2009, , 3203-3211 10.1002/ejoc.200900299 | |
(E)-N-(4-(dimethylamino)benzylidene)-4-methylbenzenesulfonamide (in DMSO) |
DMSO | E Param.: -15.09 | | J. Am. Chem. Soc. 2011, 133, 8240-8251 10.1021/ja200820m |
1-phenylprop-2-en-1-one (in DMSO) |
DMSO | E Param.: -15.25 | | J. Am. Chem. Soc. 2017, 139, 13318-13329 10.1021/jacs.7b05106 |
1,2-diaza-1,3-diene 1f |
MeOH | E Param.: -15.30 | | Chem. Eur. J. 2010, 16, 12008-12016 10.1002/chem.201000828 |
1,2-diaza-1,3-diene 1d |
DMSO | E Param.: -15.38 | | Chem. Eur. J. 2010, 16, 12008-12016 10.1002/chem.201000828 |
phenyl isocyanate |
MeCN | E Param.: -15.38 | | J. Am. Chem. Soc. 2020, 142, 8383-8402 10.1021/jacs.0c01960 |
1-methylsulfanylpropan-2-one (in DMSO) |
DMSO | E Param.: -15.60 | | J. Am. Chem. Soc. 2018, 140, 5500-5515 10.1021/jacs.8b01657 |
fumaronitrile |
DMSO | E Param.: -15.71 | | Eur. J. Org. Chem. 2014, , 2956-2963 10.1002/ejoc.201301779 |
tol(t-Bu)2QM |
E Param.: -15.83 | | Angew. Chem. Int. Ed. 2002, 41, 91-95 10.1002/1521-3773(20[...] | |
(E)-N-benzylidene-P,P-diphenylphosphinic amide |
DMSO | E Param.: -15.89 | | J. Am. Chem. Soc. 2011, 133, 8240-8251 10.1021/ja200820m |
p-nitrophenyl isothiocyanate |
DMSO | E Param.: -15.89 | | J. Am. Chem. Soc. 2020, 142, 8383-8402 10.1021/jacs.0c01960 |
ani(t-Bu)2QM |
E Param.: -16.11 | | Angew. Chem. Int. Ed. 2002, 41, 91-95 10.1002/1521-3773(20[...] | |
2,5-dichloroquinone (C-Cl) |
E Param.: -16.11 | | J. Am. Chem. Soc. 2014, 136, 11499-11512 10.1021/ja505613b | |
p-quinone (C-H) |
E Param.: -16.19 | | J. Am. Chem. Soc. 2014, 136, 11499-11512 10.1021/ja505613b | |
(E)-2,6-di-tert-butyl-4-(3-(4-nitrophenyl)allylidene)cyclohexa-2,5-dien-1-one |
DMSO | E Param.: -16.25 | | Org. Lett. 2020, 22, 2182-2186 10.1021/acs.orglett.[...] |
2,6-dimethyl-4-(4-(dimethylamino)benzylidene)cyclohexa-2,5-dienone |
E Param.: -16.36 | | Eur. J. Org. Chem. 2009, , 3203-3211 10.1002/ejoc.200900299 | |
2,6-dimethoxy-4-(4-methoxybenzylidene)cyclohexa-2,5-dienone |
E Param.: -16.38 | | Eur. J. Org. Chem. 2009, , 3203-3211 10.1002/ejoc.200900299 | |
4-(2,2-bis(phenylsulfonyl)vinyl)-N,N-dimethylaniline |
DMSO | E Param.: -16.53 | | Chem. Asian J. 2012, 7, 1401-1407 10.1002/asia.201101046 |
butynone |
E Param.: -16.60 |  | Angew. Chem. Int. Ed. 2019, 58, 17704-17708 10.1002/anie.201909803 | |
2-phenylethene-1-sulfonyl fluoride |
DMSO | E Param.: -16.63 | | Angew. Chem. Int. Ed. 2016, 55, 12664-12667 10.1002/anie.201601875 |
but-3-en-2-one (in DMSO) |
DMSO | E Param.: -16.76 | | J. Am. Chem. Soc. 2017, 139, 13318-13329 10.1021/jacs.7b05106 |
E)-2,6-di-tert-butyl-4-(3-(4-chlorophenyl)allylidene)cyclohexa-2,5-dien-1-one |
DMSO | E Param.: -16.84 | | Org. Lett. 2020, 22, 2182-2186 10.1021/acs.orglett.[...] |
thian-4-one (in DMSO) |
DMSO | E Param.: -16.90 | | J. Am. Chem. Soc. 2018, 140, 5500-5515 10.1021/jacs.8b01657 |
4-phenylbut-3-yn-2-one |
E Param.: -16.90 | | Angew. Chem. Int. Ed. 2019, 58, 17704-17708 10.1002/anie.201909803 | |
(E)-2,6-di-tert-butyl-4-(3-phenylallylidene)cyclohexa-2,5-dien-1-one |
DMSO | E Param.: -17.00 | | Org. Lett. 2020, 22, 2182-2186 10.1021/acs.orglett.[...] |
2,6-dimethoxy-4-(4-(dimethylamino)benzylidene)cyclohexa-2,5-dienone |
E Param.: -17.18 | | Eur. J. Org. Chem. 2009, , 3203-3211 10.1002/ejoc.200900299 | |
dma(t-Bu)2QM |
E Param.: -17.29 | | Angew. Chem. Int. Ed. 2002, 41, 91-95 10.1002/1521-3773(20[...] | |
bh 6m |
E Param.: -17.30 | | Chem. Eur. J. 2010, 16, 1365-1371 10.1002/chem.200902487 | |
(E)-3-(4-nitro-phenyl)-1-phenyl-prop-2-en-1-one (in DMSO) |
DMSO | E Param.: -17.33 | | J. Am. Chem. Soc. 2011, 133, 8240-8251 10.1021/ja200820m |
(E)-2,6-di-tert-butyl-4-(3-(4-methoxyphenyl)allylidene)cyclohexa-2,5-dien-1-one |
DMSO | E Param.: -17.42 | | Org. Lett. 2020, 22, 2182-2186 10.1021/acs.orglett.[...] |
cyclobutanone (in DMSO) |
DMSO | E Param.: -17.50 | | J. Am. Chem. Soc. 2018, 140, 5500-5515 10.1021/jacs.8b01657 |
(E)-3-(4-cyano-phenyl)-1-phenyl-prop-2-en-1-one (in DMSO) |
DMSO | E Param.: -17.64 | | J. Am. Chem. Soc. 2011, 133, 8240-8251 10.1021/ja200820m |
diethyl 4-nitrobenzylidene malonate |
E Param.: -17.67 | | Chem. Eur. J. 2008, 14, 9675-9682 10.1002/chem.200801277 | |
carbon disulfide |
DMSO | E Param.: -17.70 | | J. Am. Chem. Soc. 2020, 142, 8383-8402 10.1021/jacs.0c01960 |
diethyl fumarate |
DMSO | E Param.: -17.79 | | Eur. J. Org. Chem. 2014, , 2956-2963 10.1002/ejoc.201301779 |
jul(t-Bu)2QM |
E Param.: -17.90 | | Angew. Chem. Int. Ed. 2002, 41, 91-95 10.1002/1521-3773(20[...] | |
bh6j |
E Param.: -17.90 | | Chem. Eur. J. 2010, 16, 1365-1371 10.1002/chem.200902487 | |
oxan-4-one (in DMSO) |
DMSO | E Param.: -17.90 | | J. Am. Chem. Soc. 2018, 140, 5500-5515 10.1021/jacs.8b01657 |
hex-3-yn-2-one |
E Param.: -17.90 | | Angew. Chem. Int. Ed. 2019, 58, 17704-17708 10.1002/anie.201909803 | |
diethyl 4-cyano-benzylidene malonate |
E Param.: -18.06 | | Chem. Eur. J. 2008, 14, 9675-9682 10.1002/chem.200801277 | |
phenyl isothiocyanate |
DMSO | E Param.: -18.15 | | J. Am. Chem. Soc. 2020, 142, 8383-8402 10.1021/jacs.0c01960 |
bh 6k |
E Param.: -18.20 | | Chem. Eur. J. 2010, 16, 1365-1371 10.1002/chem.200902487 | |
1,4-dioxaspiro[4.5]decan-8-one (in DMSO) |
DMSO | E Param.: -18.20 | | J. Am. Chem. Soc. 2018, 140, 5500-5515 10.1021/jacs.8b01657 |
dimethyl diazomalonate |
E Param.: -18.20 | | Chem. Eur. J. 2022, 28, e202201376 10.1002/chem.202201376 | |
(p-nitrophenyl)diazomethane |
E Param.: -18.30 | | Chem. Eur. J. 2022, 28, e202201376 10.1002/chem.202201376 | |
ethenylsulfonylbenzene (in DMSO) |
DMSO | E Param.: -18.36 | | J. Am. Chem. Soc. 2017, 139, 13318-13329 10.1021/jacs.7b05106 |