Electrophiles
| Name | Solvent |
Reactivity Parameters |
Classification |
Reference (title or year) |
|---|---|---|---|---|
benzhydrylium ion Ph2CH+   |
E Param.: 5.47 |
 |
J. Am. Chem. Soc. 2012, 134, 13902-13911 10.1021/ja306522b |
|
ani(Br)2QM  |
E Param.: -8.63 |
|
Angew. Chem. Int. Ed. 2002, 41, 91-95 10.1002/1521-3773(20[...] |
|
ani(Ph)2QM  |
E Param.: -12.18 |
|
Angew. Chem. Int. Ed. 2002, 41, 91-95 10.1002/1521-3773(20[...] |
|
dma(Ph)2QM  |
E Param.: -13.39 |
|
Angew. Chem. Int. Ed. 2002, 41, 91-95 10.1002/1521-3773(20[...] |
|
tol(t-Bu)2QM  |
E Param.: -15.83 |
|
Angew. Chem. Int. Ed. 2002, 41, 91-95 10.1002/1521-3773(20[...] |
|
ani(t-Bu)2QM  |
E Param.: -16.11 |
|
Angew. Chem. Int. Ed. 2002, 41, 91-95 10.1002/1521-3773(20[...] |
|
dma(t-Bu)2QM  |
E Param.: -17.29 |
|
Angew. Chem. Int. Ed. 2002, 41, 91-95 10.1002/1521-3773(20[...] |
|
jul(t-Bu)2QM  |
E Param.: -17.90 |
|
Angew. Chem. Int. Ed. 2002, 41, 91-95 10.1002/1521-3773(20[...] |
|
(pcp)2CH+  |
E Param.: 5.48 |
|
J. Am. Chem. Soc. 2012, 134, 13902-13911 10.1021/ja306522b |
|
pfp(Ph)CH+  |
E Param.: 5.20 |
|
J. Am. Chem. Soc. 2012, 134, 13902-13911 10.1021/ja306522b |
|
(fur)2CH+  |
E Param.: -1.36 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
|
(ani)2CH+  |
E Param.: 0.00 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
|
(tol)2CH+  |
E Param.: 3.63 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
|
(pfa)2CH+  |
E Param.: -3.14 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
|
(mfa)2CH+  |
E Param.: -3.85 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
|
(dpa)2CH+  |
E Param.: -4.72 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
|
(mor)2CH+  |
E Param.: -5.53 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
|
(mpa)2CH+  |
E Param.: -5.89 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
|
(dma)2CH+  |
E Param.: -7.02 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
|
(pyr)2CH+  |
E Param.: -7.69 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
|
(thq)2CH+  |
E Param.: -8.22 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
|
(ind)2CH+  |
E Param.: -8.76 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
|
(jul)2CH+  |
E Param.: -9.45 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
|
(lil)2CH+  |
E Param.: -10.04 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
|
5-methoxyfuroxano[3,4-d]pyrimidine  |
E Param.: -8.37 |
|
J. Phys. Org. Chem. 2003, 16, 431-437 10.1002/poc.606 |
|
benzylidenemalononitrile  |
E Param.: -9.42 |
|
J. Org. Chem. 2003, 68, 6880-6886 10.1021/jo0344182 |
|
p-(methoxy)benzylidenemalononitrile  |
E Param.: -10.80 |
|
J. Org. Chem. 2003, 68, 6880-6886 10.1021/jo0344182 |
|
p-(dimethylamino)benzylidenemalononitrile  |
E Param.: -13.30 |
|
J. Org. Chem. 2003, 68, 6880-6886 10.1021/jo0344182 |
|
ani(pop)CH+  |
E Param.: 0.61 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
|
ani(Ph)CH+  |
E Param.: 2.11 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
|
ani(tol)CH+  |
E Param.: 1.48 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
|
pop(Ph)CH+  |
E Param.: 2.90 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
|
tol(Ph)CH+  |
E Param.: 4.43 |
|
J. Am. Chem. Soc. 2012, 134, 13902-13911 10.1021/ja306522b |
|
(pfp)2CH+  |
E Param.: 5.01, Deviation: ±0.05 |
|
J. Am. Chem. Soc. 2012, 134, 13902-13911 10.1021/ja306522b |
|
pop(tol)CH+  |
E Param.: 2.16, Deviation: ±0.03 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
fc(Ph)CH+  |
E Param.: -2.64 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
|
fc(ani)CH+  |
E Param.: -2.90, Deviation: ±0.09 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
fc(Me)CH+  |
E Param.: -2.57 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
fc2CH+  |
E Param.: -8.54, Deviation: ±0.53 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
C7H7+-Fe(CO)3  |
E Param.: -3.49, Deviation: ±0.17 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
C7H9+-Fe(CO)3  |
E Param.: -9.21, Deviation: ±0.36 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
C6H7+-Fe(CO)3  |
E Param.: -7.76, Deviation: ±0.31 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
C6H6OMe+-Fe(CO)3  |
E Param.: -8.94, Deviation: ±0.13 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
benzaldehyde-boron trichloride complex  |
E Param.: 1.12, Deviation: ±0.24 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
4-chlorobenzaldehyde-boron trichloride complex  |
E Param.: 1.44, Deviation: ±0.20 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
tropylium ion  |
E Param.: -3.72, Deviation: ±0.03 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
propyn-1-ylium-Co2(CO)6  |
E Param.: -0.84, Deviation: ±0.36 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
1-phenyl-proyn-ylium-Co2(CO)6  |
E Param.: -0.97, Deviation: ±0.08 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
3-phenylpropyn-1-ylium-Co2(CO)6  |
E Param.: -1.58, Deviation: ±0.58 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
3-(trimethylsilyl)propyn-1-ylium-Co2(CO)6  |
E Param.: -1.60, Deviation: ±0.34 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
1-phenyl-propyn-1-ylium-Co2(CO)5(PPh3)  |
E Param.: -6.19, Deviation: ±0.44 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
2-phenyl-1,3-dithiolan-2-ylium ion  |
E Param.: -5.91, Deviation: ±0.33 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
2-phenyl-1,3-dithianylium ion  |
E Param.: -6.43, Deviation: ±0.04 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
1,3-dithianylium ion  |
E Param.: -2.14, Deviation: ±0.07 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
N-ethylidenecarbazolium ion  |
E Param.: 2.41, Deviation: ±0.33 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
N-methylacridinium ion  |
E Param.: -7.15, Deviation: ±0.12 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
dimethylmethyleneammonium ion  |
E Param.: -6.69 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
methyl(phenyl)methyleneammonium ion  |
E Param.: -5.17 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
Vilsmeier ion  |
E Param.: -5.77 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
methoxy-phenylmethylium ion  |
E Param.: 2.97, Deviation: ±0.09 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
methoxy-(4-methoxyphenyl)methylium ion  |
E Param.: 0.14, Deviation: ±0.01 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
methoxy-(4-methylphenyl)methylium ion  |
E Param.: 1.90, Deviation: ±0.22 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
Pd-allyl cation  |
E Param.: -10.11, Deviation: ±0.96 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
flavylium ion  |
E Param.: -3.45, Deviation: ±0.16 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
2-(4-methoxyphenyl)chromenylium ion  |
E Param.: -4.95, Deviation: ±0.06 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
1,1,3-triphenylallylium ion  |
E Param.: 0.98, Deviation: ±0.20 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
1,1-dianisyl-3-phenylallylium ion  |
E Param.: -2.67, Deviation: ±0.30 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
1,1-bis(4-dimethylaminophenyl)-3-phenylallylium ion  |
E Param.: -8.97, Deviation: ±0.32 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
1,1,3-tris(4-(dimethylamino)phenyl)allylium ion  |
E Param.: -9.84, Deviation: ±0.21 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
1-phenylcyclopent-2-enylium ion  |
E Param.: 2.89, Deviation: ±0.25 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
1-(4-chlorophenyl)cyclopent-2-enylium ion  |
E Param.: 3.20, Deviation: ±0.37 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
1,3-diphenylpropyn-1-ylium-Cr(CO)3  |
E Param.: 1.07, Deviation: ±0.30 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
1,1,3-triphenylpropyn-1-ylium-Cr(CO)3  |
E Param.: -0.25, Deviation: ±0.20 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
tritylium ion (Ph3C+)  |
E Param.: 0.51 |
 |
J. Am. Chem. Soc. 2003, 125, 286-295 10.1021/ja021010y |
|
4,6-dinitrobenzofuroxan  |
E Param.: -5.06 |
|
J. Org. Chem. 2006, 71, 9088-9095 10.1021/jo0614339 |
|
1,3,5-trinitrobenzene  |
E Param.: -13.19, Deviation: ±0.45 |
|
J. Org. Chem. 2005, 70, 6242-6253 10.1021/jo0505526 |
|
6-nitro-tetrazolo[1,5a]pyridine  |
E Param.: -9.05, Deviation: ±0.12 |
|
J. Org. Chem. 2005, 70, 6242-6253 10.1021/jo0505526 |
|
dicarbonyl(cyclopentadienyl)propene-iron(II)  |
E Param.: -11.20 |
|
Helv. Chim. Acta 2005, 88, 1754-1768 10.1002/hlca.200590137 |
|
4-nitro-6-(trifluoromethylsulfonyl)benzofuroxan  |
E Param.: -4.91, Deviation: ±0.31 |
|
J. Org. Chem. 2005, 70, 6242-6253 10.1021/jo0505526 |
|
4,6-dinitrotetrazolopyridine  |
E Param.: -4.67, Deviation: ±0.30 |
|
J. Org. Chem. 2005, 70, 6242-6253 10.1021/jo0505526 |
|
4,6-dinitrobenzofurazan  |
E Param.: -5.46, Deviation: ±0.36 |
|
J. Org. Chem. 2005, 70, 6242-6253 10.1021/jo0505526 |
|
2,4-dinitrothiophene  |
E Param.: -12.33, Deviation: ±0.11 |
|
J. Org. Chem. 2005, 70, 6242-6253 10.1021/jo0505526 |
|
6-cyano-4-nitrobenzofuroxan  |
E Param.: -7.01, Deviation: ±0.16 |
|
J. Org. Chem. 2005, 70, 6242-6253 10.1021/jo0505526 |
|
4-cyano-6-nitro-benzofuroxane  |
E Param.: -6.41, Deviation: ±0.38 |
|
J. Org. Chem. 2005, 70, 6242-6253 10.1021/jo0505526 |
|
4-aza-6-nitrobenzofuroxan  |
E Param.: -5.86, Deviation: ±0.36 |
|
J. Org. Chem. 2005, 70, 6242-6253 10.1021/jo0505526 |
|
(2,4,6-trimethylphenyl)ethylium ion  |
E Param.: 6.04 |
|
Macromolecules 2005, 38, 33-40 10.1021/ma048389o |
|
1,3-bis(2,4,6-trimethylphenyl)but-1-ylium ion  |
E Param.: 6.16 |
|
Macromolecules 2005, 38, 33-40 10.1021/ma048389o |
|
2-(p-(dimethylamino)benzylidene)-indan-1,3-dione  |
E Param.: -13.56 |
|
Org. Biomol. Chem. 2007, 5, 3020-3026 10.1039/b708025e |
|
2-(p-methoxybenzylidene)-indan-1,3-dione  |
E Param.: -11.32 |
|
Org. Biomol. Chem. 2007, 5, 3020-3026 10.1039/b708025e |
|
2-benzylidene-indan-1,3-dione  |
E Param.: -10.11 |
|
Org. Biomol. Chem. 2007, 5, 3020-3026 10.1039/b708025e |
|
jul-indan-1,3-dione  |
E Param.: -14.68 |
|
Org. Biomol. Chem. 2007, 5, 3020-3026 10.1039/b708025e |
|
aniBBS  |
E Param.: -10.37 |
|
J. Org. Chem. 2007, 72, 9170-9180 10.1021/jo071273g |
|
dmaBBS  |
E Param.: -12.76 |
|
J. Org. Chem. 2007, 72, 9170-9180 10.1021/jo071273g |
|
julBBS  |
E Param.: -13.84 |
|
J. Org. Chem. 2007, 72, 9170-9180 10.1021/jo071273g |
|
dma(S)BBS  |
E Param.: -10.73 |
|
J. Org. Chem. 2007, 72, 9170-9180 10.1021/jo071273g |
|
jul(S)BBS  |
E Param.: -11.89 |
|
J. Org. Chem. 2007, 72, 9170-9180 10.1021/jo071273g |
|
4-nitrobenzodifuroxan (NBDF)  |
E Param.: -6.15 |
|
Chem. Eur. J. 2007, 13, 8317-8324 10.1002/chem.200700676 |
|
benzylidene-Meldrum's acid  |
E Param.: -9.15 |
|
J. Org. Chem. 2008, 73, 2738-2745 10.1021/jo702590s |
|
p-(methoxy)benzylidene Meldrum's acid  |
E Param.: -10.28 |
|
J. Org. Chem. 2008, 73, 2738-2745 10.1021/jo702590s |
|
p-(dimethylamino)benzylidene Meldrum's acid  |
E Param.: -12.76 |
|
J. Org. Chem. 2008, 73, 2738-2745 10.1021/jo702590s |