Carbocations
| Name | Solvent |
Reactivity Parameters |
Classification |
Reference (title or year) |
|---|---|---|---|---|
cumyl cation  |
E Param.: 5.74 |  | Macromolecules 2010, 43, 1719-1723 10.1021/ma9024569 | |
(4-CF3)2-tritylium ion |
E Param.: 2.28 |  | J. Am. Chem. Soc. 2003, 125, 286-295 10.1021/ja021010y | |
(3-Cl)3-tritylium ion |
E Param.: 1.99 | | J. Am. Chem. Soc. 2003, 125, 286-295 10.1021/ja021010y | |
(4-CF3)-tritylium ion |
E Param.: 1.33 | | J. Am. Chem. Soc. 2003, 125, 286-295 10.1021/ja021010y | |
(3-Cl)-tritylium ion |
E Param.: 1.06 | | J. Am. Chem. Soc. 2003, 125, 286-295 10.1021/ja021010y | |
(3-CF3)-tritylium ion |
E Param.: 1.18 | | J. Am. Chem. Soc. 2003, 125, 286-295 10.1021/ja021010y | |
(4-Me)-tritylium ion |
E Param.: -0.13 | | J. Am. Chem. Soc. 2003, 125, 286-295 10.1021/ja021010y | |
(4-Me)2-tritylium ion |
E Param.: -0.70 | | J. Am. Chem. Soc. 2003, 125, 286-295 10.1021/ja021010y | |
(4-Me)3-tritylium ion |
E Param.: -1.21 | | J. Am. Chem. Soc. 2003, 125, 286-295 10.1021/ja021010y | |
(4-MeO,3-OMe)-tritylium ion |
E Param.: -1.62 | | J. Am. Chem. Soc. 2003, 125, 286-295 10.1021/ja021010y | |
(4-OMe,3-Me)-tritylium ion |
E Param.: -1.84 | | J. Am. Chem. Soc. 2003, 125, 286-295 10.1021/ja021010y | |
(4-MeO)-tritylium ion |
E Param.: -1.59 | | Eur. J. Org. Chem. 2011, , 6470-6475 10.1002/ejoc.201100910 | |
(4-MeO,4-Me)-tritylium ion |
E Param.: -2.13 | | J. Am. Chem. Soc. 2003, 125, 286-295 10.1021/ja021010y | |
(4-MeO)2-tritylium ion |
E Param.: -3.04 | | J. Am. Chem. Soc. 2003, 125, 286-295 10.1021/ja021010y | |
(4-MeO)3-tritylium ion |
E Param.: -4.35 | | J. Am. Chem. Soc. 2003, 125, 286-295 10.1021/ja021010y | |
(4-NMe2)-tritylium ion |
E Param.: -7.93 | | J. Am. Chem. Soc. 2003, 125, 286-295 10.1021/ja021010y | |
(4-NMe2)2-tritylium ion (= Malachite green) |
E Param.: -10.29 | | J. Am. Chem. Soc. 2003, 125, 286-295 10.1021/ja021010y | |
(4-NMe2)3-tritylium ion (= Crystal violet) |
E Param.: -11.26 | | J. Am. Chem. Soc. 2003, 125, 286-295 10.1021/ja021010y | |
(4-F)-tritylium ion |
E Param.: 0.35 | | Eur. J. Org. Chem. 2011, , 6470-6475 10.1002/ejoc.201100910 | |
(4-F)2-tritylium ion |
E Param.: 0.17 | | Eur. J. Org. Chem. 2011, , 6470-6475 10.1002/ejoc.201100910 | |
(4-F)3-tritylium ion |
E Param.: 0.05 | | Eur. J. Org. Chem. 2011, , 6470-6475 10.1002/ejoc.201100910 | |
(3-F)-tritylium ion |
E Param.: 1.01 | | Eur. J. Org. Chem. 2011, , 6470-6475 10.1002/ejoc.201100910 | |
(3-F)2-tritylium ion |
E Param.: 1.54 | | Eur. J. Org. Chem. 2011, , 6470-6475 10.1002/ejoc.201100910 | |
(3-F)3-tritylium ion |
E Param.: 2.07 | | Eur. J. Org. Chem. 2011, , 6470-6475 10.1002/ejoc.201100910 | |
(3-F)4-tritylium ion |
E Param.: 2.54 | | Eur. J. Org. Chem. 2011, , 6470-6475 10.1002/ejoc.201100910 | |
diarylallylium ion (3,3-F2)2 |
E Param.: 6.11 | | J. Org. Chem. 2011, 76, 9391-9408 10.1021/jo201668w | |
diarylallylium ion (3-F)2 |
E Param.: 4.15 | | J. Org. Chem. 2011, 76, 9391-9408 10.1021/jo201668w | |
diarylallylium ion (4-Br)2 |
E Param.: 2.85 | | J. Org. Chem. 2011, 76, 9391-9408 10.1021/jo201668w | |
diarylallylium ion (4-Cl)2 |
E Param.: 2.69 | | J. Org. Chem. 2011, 76, 9391-9408 10.1021/jo201668w | |
diphenylallylium ion |
E Param.: 2.70 | | J. Org. Chem. 2011, 76, 9391-9408 10.1021/jo201668w | |
di-p-tolyl-allylium ion |
E Param.: 1.23 | | J. Org. Chem. 2011, 76, 9391-9408 10.1021/jo201668w | |
di-p-anisyl-allylium ion |
E Param.: -1.45 | | J. Org. Chem. 2011, 76, 9391-9408 10.1021/jo201668w | |
diarylallylium ion (4-NMe2)2 |
E Param.: -7.50 | | J. Org. Chem. 2011, 76, 9391-9408 10.1021/jo201668w | |
bis(julidin-9-yl)allylium ion |
E Param.: -9.78 | | J. Org. Chem. 2011, 76, 9391-9408 10.1021/jo201668w | |
benzhydrylium ion Ph2CH+ |
E Param.: 5.47 | | J. Am. Chem. Soc. 2012, 134, 13902-13911 10.1021/ja306522b | |
(pcp)2CH+ |
E Param.: 5.48 | | J. Am. Chem. Soc. 2012, 134, 13902-13911 10.1021/ja306522b | |
pfp(Ph)CH+ |
E Param.: 5.20 | | J. Am. Chem. Soc. 2012, 134, 13902-13911 10.1021/ja306522b | |
(fur)2CH+ |
E Param.: -1.36 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y | |
(ani)2CH+ |
E Param.: 0.00 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y | |
(tol)2CH+ |
E Param.: 3.63 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y | |
(pfa)2CH+ |
E Param.: -3.14 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y | |
(mfa)2CH+ |
E Param.: -3.85 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y | |
(dpa)2CH+ |
E Param.: -4.72 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y | |
(mor)2CH+ |
E Param.: -5.53 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y | |
(mpa)2CH+ |
E Param.: -5.89 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y | |
(dma)2CH+ |
E Param.: -7.02 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y | |
(pyr)2CH+ |
E Param.: -7.69 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y | |
(thq)2CH+ |
E Param.: -8.22 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y | |
(ind)2CH+ |
E Param.: -8.76 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y | |
(jul)2CH+ |
E Param.: -9.45 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y | |
(lil)2CH+ |
E Param.: -10.04 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y | |
ani(pop)CH+ |
E Param.: 0.61 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y | |
ani(Ph)CH+ |
E Param.: 2.11 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y | |
ani(tol)CH+ |
E Param.: 1.48 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y | |
pop(Ph)CH+ |
E Param.: 2.90 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y | |
tol(Ph)CH+ |
E Param.: 4.43 | | J. Am. Chem. Soc. 2012, 134, 13902-13911 10.1021/ja306522b | |
(pfp)2CH+ |
E Param.: 5.01 | | J. Am. Chem. Soc. 2012, 134, 13902-13911 10.1021/ja306522b | |
pop(tol)CH+ |
E Param.: 2.16 | | Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c | |
tropylium ion |
E Param.: -3.72 | | Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c | |
2-phenyl-1,3-dithiolan-2-ylium ion |
E Param.: -5.91 | | Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c | |
2-phenyl-1,3-dithianylium ion |
E Param.: -6.43 | | Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c | |
1,3-dithianylium ion |
E Param.: -2.14 | | Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c | |
N-ethylidenecarbazolium ion |
E Param.: 2.41 | | Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c | |
N-methylacridinium ion |
E Param.: -7.15 | | Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c | |
dimethylmethyleneammonium ion |
E Param.: -6.69 | | Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c | |
methyl(phenyl)methyleneammonium ion |
E Param.: -5.17 | | Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c | |
Vilsmeier ion |
E Param.: -5.77 | | Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c | |
methoxy-phenylmethylium ion |
E Param.: 2.97 | | Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c | |
methoxy-(4-methoxyphenyl)methylium ion |
E Param.: 0.14 | | Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c | |
methoxy-(4-methylphenyl)methylium ion |
E Param.: 1.90 | | Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c | |
flavylium ion |
E Param.: -3.45 | | Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c | |
2-(4-methoxyphenyl)chromenylium ion |
E Param.: -4.95 | | Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c | |
1,1,3-triphenylallylium ion |
E Param.: 0.98 | | Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c | |
1,1-dianisyl-3-phenylallylium ion |
E Param.: -2.67 | | Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c | |
1,1-bis(4-dimethylaminophenyl)-3-phenylallylium ion |
E Param.: -8.97 | | Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c | |
1,1,3-tris(4-(dimethylamino)phenyl)allylium ion |
E Param.: -9.84 | | Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c | |
1-phenylcyclopent-2-enylium ion |
E Param.: 2.89 | | Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c | |
1-(4-chlorophenyl)cyclopent-2-enylium ion |
E Param.: 3.20 | | Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c | |
tritylium ion (Ph3C+) |
E Param.: 0.51 | | J. Am. Chem. Soc. 2003, 125, 286-295 10.1021/ja021010y | |
(2,4,6-trimethylphenyl)ethylium ion |
E Param.: 6.04 | | Macromolecules 2005, 38, 33-40 10.1021/ma048389o | |
1,3-bis(2,4,6-trimethylphenyl)but-1-ylium ion |
E Param.: 6.16 | | Macromolecules 2005, 38, 33-40 10.1021/ma048389o | |
Me2N+=CH-CH-Ph |
E Param.: -9.20 | | Angew. Chem. Int. Ed. 2008, 47, 8723-8726 10.1002/anie.200802889 | |
pyrN+=CH-CH-Ph |
E Param.: -9.80 | | Angew. Chem. Int. Ed. 2008, 47, 8723-8726 10.1002/anie.200802889 | |
pipN+=CH-CH-Ph |
E Param.: -10.30 | | Angew. Chem. Int. Ed. 2008, 47, 8723-8726 10.1002/anie.200802889 | |
(PhCH2)2N+=CH-CH-Ph |
E Param.: -8.50 | | Angew. Chem. Int. Ed. 2008, 47, 8723-8726 10.1002/anie.200802889 | |
Jorgensen/Hayashi-iminium ion |
E Param.: -8.20 | | Angew. Chem. Int. Ed. 2008, 47, 8723-8726 10.1002/anie.200802889 | |
mor iminium |
E Param.: -8.60 | | Angew. Chem. Int. Ed. 2008, 47, 8723-8726 10.1002/anie.200802889 | |
(fur)(ani)CH+ |
E Param.: -0.81 | | J. Am. Chem. Soc. 2012, 134, 13902-13911 10.1021/ja306522b | |
(mfp)PhCH+ |
E Param.: 6.23 | | J. Am. Chem. Soc. 2012, 134, 13902-13911 10.1021/ja306522b | |
(tfm)PhCH+ |
E Param.: 6.70 | | J. Am. Chem. Soc. 2012, 134, 13902-13911 10.1021/ja306522b | |
(dfp)PhCH+ |
E Param.: 6.74 | | J. Am. Chem. Soc. 2012, 134, 13902-13911 10.1021/ja306522b | |
(mfp)2CH+ |
E Param.: 6.87 | | J. Am. Chem. Soc. 2012, 134, 13902-13911 10.1021/ja306522b | |
(dfp)(mfp)CH+ |
E Param.: 7.52 | | J. Am. Chem. Soc. 2012, 134, 13902-13911 10.1021/ja306522b | |
(tfm)2CH+ |
E Param.: 7.96 | | J. Am. Chem. Soc. 2012, 134, 13902-13911 10.1021/ja306522b | |
(dfp)2CH+ |
E Param.: 8.02 | | J. Am. Chem. Soc. 2012, 134, 13902-13911 10.1021/ja306522b | |
(Ftol)2CH+ |
E Param.: 5.24 | | J. Am. Chem. Soc. 2012, 134, 13902-13911 10.1021/ja306522b | |
3-benzylidene-1-methyl-3H-indol-1-ium ion |
E Param.: -1.80 | | J. Org. Chem. 2015, 80, 8643-8656 10.1021/acs.joc.5b01298 | |
1-methyl-3-(4-methylbenzylidene)-3H-indol-1-ium ion |
E Param.: -2.19 | | J. Org. Chem. 2015, 80, 8643-8656 10.1021/acs.joc.5b01298 | |
3-(4-methoxybenzylidene)-1-methyl-3H-indol-1-ium iom |
E Param.: -3.02 | | J. Org. Chem. 2015, 80, 8643-8656 10.1021/acs.joc.5b01298 | |
3-(4-(dimethylamino)benzylidene)-1-methyl-3H-indol-1-ium ion |
E Param.: -6.26 | | J. Org. Chem. 2015, 80, 8643-8656 10.1021/acs.joc.5b01298 |