Electrophiles
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« Back Forward » Found 375 molecules, displaying page 1 of 4 Results per page
10|50|100|all
| Name | Solvent |
Reactivity Parameters |
Classification |
Reference (title or year) |
|---|---|---|---|---|
[(1,3-Diarylallyl)Pd(PPh3)2]+ (Aryl = Ph)  |
E Param.: -14.14 |  | Organometallics 2012, 31, 2416-2424 10.1021/om3000357 | |
[(1,3-Diarylallyl)Pd(PPh3)2]+ (Aryl = 4-(dimethylamino)phenyl) |
E Param.: -14.46 | | Organometallics 2012, 31, 2416-2424 10.1021/om3000357 | |
[(1,3-Diarylallyl)Pd(PPh3)2]+ (Aryl = 3,5-difluorophenyl) |
E Param.: -14.21 | | Organometallics 2012, 31, 2416-2424 10.1021/om3000357 | |
Vilsmeier ion |
E Param.: -5.77 | | Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c | |
Umemoto II (triflate) |
E Param.: -12.80 | | Eur. J. Org. Chem. 2024, 27, e202400085 10.1002/ejoc.202400085 | |
Umemoto I (triflate) |
E Param.: -13.08 | | Eur. J. Org. Chem. 2024, 27, e202400085 10.1002/ejoc.202400085 | |
Umemoto I (tetrafluoroborate) |
E Param.: -13.39 | | Eur. J. Org. Chem. 2024, 27, e202400085 10.1002/ejoc.202400085 | |
tropylium ion |
E Param.: -3.72 | | Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c | |
tritylium ion (Ph3C+) |
E Param.: 0.51 |  | J. Am. Chem. Soc. 2003, 125, 286-295 10.1021/ja021010y | |
tol(t-Bu)2QM |
E Param.: -15.83 | | Angew. Chem. Int. Ed. 2002, 41, 91-95 10.1002/1521-3773(20[...] | |
tol(Ph)CH+ |
E Param.: 4.43 | | J. Am. Chem. Soc. 2012, 134, 13902-13911 10.1021/ja306522b | |
thian-4-one (in DMSO) |
DMSO | E Param.: -16.90 | | J. Am. Chem. Soc. 2018, 140, 5500-5515 10.1021/jacs.8b01657 |
tert-butyl prop-2-enoate (in DMSO) |
DMSO | E Param.: -20.22 | | J. Am. Chem. Soc. 2017, 139, 13318-13329 10.1021/jacs.7b05106 |
Selectfluor |
E Param.: -5.20 | | J. Am. Chem. Soc. 2018, 140, 11474-11486 10.1021/jacs.8b07147 | |
pyrN+=CH-CH-Ph |
E Param.: -9.80 | | Angew. Chem. Int. Ed. 2008, 47, 8723-8726 10.1002/anie.200802889 | |
pTolCH=N+CH2 (in MeCN) |
MeCN | E Param.: -9.64 | | J. Am. Chem. Soc. 2013, 135, 6579-6587 10.1021/ja401106x |
propyn-1-ylium-Co2(CO)6 |
E Param.: -0.84 | | Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c | |
pop(tol)CH+ |
E Param.: 2.16 | | Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c | |
pop(Ph)CH+ |
E Param.: 2.90 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y | |
pipN+=CH-CH-Ph |
E Param.: -10.30 | | Angew. Chem. Int. Ed. 2008, 47, 8723-8726 10.1002/anie.200802889 | |
phenyl isothiocyanate |
DMSO | E Param.: -18.15 | | J. Am. Chem. Soc. 2020, 142, 8383-8402 10.1021/jacs.0c01960 |
phenyl isocyanate |
MeCN | E Param.: -15.38 | | J. Am. Chem. Soc. 2020, 142, 8383-8402 10.1021/jacs.0c01960 |
PhCH=N+Me2 (in MeCN) |
MeCN | E Param.: -9.27 | | J. Am. Chem. Soc. 2013, 135, 6579-6587 10.1021/ja401106x |
PhCH=N+(CH2)5 (in MeCN) |
MeCN | E Param.: -9.60 | | J. Am. Chem. Soc. 2013, 135, 6579-6587 10.1021/ja401106x |
PhCH=N+(CH2)4 (in MeCN) |
MeCN | E Param.: -9.35 | | J. Am. Chem. Soc. 2013, 135, 6579-6587 10.1021/ja401106x |
Ph2C=C=N(+)Me2 |
E Param.: -1.90 | | Synthesis 2025, , eFirst 10.1055/a-2649-1999 | |
pfp(Ph)CH+ |
E Param.: 5.20 | | J. Am. Chem. Soc. 2012, 134, 13902-13911 10.1021/ja306522b | |
pentan-2-one (in DMSO) |
DMSO | E Param.: -22.30 | | J. Am. Chem. Soc. 2018, 140, 5500-5515 10.1021/jacs.8b01657 |
Pd-allyl cation |
E Param.: -10.11 | | Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c | |
p-tosyl isocyanate |
MeCN | E Param.: -7.69 | | J. Am. Chem. Soc. 2020, 142, 8383-8402 10.1021/jacs.0c01960 |
p-quinone (C-H) |
E Param.: -16.19 | | J. Am. Chem. Soc. 2014, 136, 11499-11512 10.1021/ja505613b | |
p-nitrophenyl isothiocyanate |
DMSO | E Param.: -15.89 | | J. Am. Chem. Soc. 2020, 142, 8383-8402 10.1021/jacs.0c01960 |
p-nitro-cinnamaldehyde (in DMSO) |
DMSO | | J. Am. Chem. Soc. 2011, 133, 8240-8251 10.1021/ja200820m | |
p-fluoranil (C=O) |
E Param.: -9.37 | | J. Am. Chem. Soc. 2014, 136, 11499-11512 10.1021/ja505613b | |
p-fluoranil (C-F) |
E Param.: -11.12 | | J. Am. Chem. Soc. 2014, 136, 11499-11512 10.1021/ja505613b | |
p-chloranil (C=O) |
E Param.: -12.13 | | J. Am. Chem. Soc. 2014, 136, 11499-11512 10.1021/ja505613b | |
p-chloranil (C-Cl) |
E Param.: -13.84 | | J. Am. Chem. Soc. 2014, 136, 11499-11512 10.1021/ja505613b | |
p-CF3-C6H4-CH=N+Me2 (in MeCN) |
MeCN | E Param.: -8.34 | | J. Am. Chem. Soc. 2013, 135, 6579-6587 10.1021/ja401106x |
p-AniCH=N+Me2 (in MeCN) |
MeCN | E Param.: -10.69 | | J. Am. Chem. Soc. 2013, 135, 6579-6587 10.1021/ja401106x |
p-(methoxy)benzylidenemalononitrile |
E Param.: -10.80 | | J. Org. Chem. 2003, 68, 6880-6886 10.1021/jo0344182 | |
p-(methoxy)benzylidene Meldrum's acid |
E Param.: -10.28 | | J. Org. Chem. 2008, 73, 2738-2745 10.1021/jo702590s | |
p-(dimethylamino)benzylidenemalononitrile |
E Param.: -13.30 | | J. Org. Chem. 2003, 68, 6880-6886 10.1021/jo0344182 | |
p-(dimethylamino)benzylidene Meldrum's acid |
E Param.: -12.76 | | J. Org. Chem. 2008, 73, 2738-2745 10.1021/jo702590s | |
oxan-4-one (in DMSO) |
DMSO | E Param.: -17.90 | | J. Am. Chem. Soc. 2018, 140, 5500-5515 10.1021/jacs.8b01657 |
o-chloranil (C=O) |
E Param.: -8.77 | | J. Am. Chem. Soc. 2014, 136, 11499-11512 10.1021/ja505613b | |
o-chloranil (C-Cl) |
E Param.: -12.02 | | J. Am. Chem. Soc. 2014, 136, 11499-11512 10.1021/ja505613b | |
NFSI |
MeCN | E Param.: -8.44 | | J. Am. Chem. Soc. 2018, 140, 11474-11486 10.1021/jacs.8b07147 |
N-methylacridinium ion |
E Param.: -7.15 | | Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c | |
N-methyl-N-((trifluoromethyl)thio)-p-toluenesulfonamide |
E Param.: -13.44 | | Angew. Chem. Int. Ed. 2018, 57, 12690-12695 10.1002/anie.201805859 | |
N-methyl-N-((trifluoromethyl)thio)-aniline |
E Param.: -23.32 | | Angew. Chem. Int. Ed. 2018, 57, 12690-12695 10.1002/anie.201805859 | |
N-methyl maleimide |
DMSO | E Param.: -14.07 | | Eur. J. Org. Chem. 2014, , 2956-2963 10.1002/ejoc.201301779 |
N-fluoropyridinium tetrafluoroborate |
E Param.: -9.89 | | J. Am. Chem. Soc. 2018, 140, 11474-11486 10.1021/jacs.8b07147 | |
N-fluoro-2,6-dichloropyridinium tetrafluoroborate |
E Param.: -5.29 | | J. Am. Chem. Soc. 2018, 140, 11474-11486 10.1021/jacs.8b07147 | |
N-fluoro-2,4,6-trimethylpyridinium tetrafluoroborate |
E Param.: -10.46 | | J. Am. Chem. Soc. 2018, 140, 11474-11486 10.1021/jacs.8b07147 | |
N-ethylidenecarbazolium ion |
E Param.: 2.41 | | Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c | |
N-(trifluoromethyl)thio)succinimide |
E Param.: -12.56 | | Angew. Chem. Int. Ed. 2018, 57, 12690-12695 10.1002/anie.201805859 | |
N-(trifluoromethyl)thio)saccharin |
E Param.: -6.48 | | Angew. Chem. Int. Ed. 2018, 57, 12690-12695 10.1002/anie.201805859 | |
N-(trifluoromethyl)thio)phthalimide |
E Param.: -11.92 | | Angew. Chem. Int. Ed. 2018, 57, 12690-12695 10.1002/anie.201805859 | |
N-(phenylsulfonyl)-N-((trifluoromethyl)thio)benzenesulfonamide |
E Param.: -6.06 | | Angew. Chem. Int. Ed. 2018, 57, 12690-12695 10.1002/anie.201805859 | |
N-(difluoromethyl)thio)phthalimide |
E Param.: -11.86 | | Angew. Chem. Int. Ed. 2018, 57, 12690-12695 10.1002/anie.201805859 | |
N,N-dimethylprop-2-enamide (in DMSO) |
DMSO | E Param.: -23.54 | | J. Am. Chem. Soc. 2017, 139, 13318-13329 10.1021/jacs.7b05106 |
mor iminium |
E Param.: -8.60 | | Angew. Chem. Int. Ed. 2008, 47, 8723-8726 10.1002/anie.200802889 | |
methyl(phenyl)methyleneammonium ion |
E Param.: -5.17 | | Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c | |
methyl prop-2-enoate (in DMSO) |
DMSO | E Param.: -18.84 | | J. Am. Chem. Soc. 2017, 139, 13318-13329 10.1021/jacs.7b05106 |
methyl diazoacetate |
E Param.: -18.50 | | Chem. Eur. J. 2022, 28, e202201376 10.1002/chem.202201376 | |
methoxy-phenylmethylium ion |
E Param.: 2.97 | | Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c | |
methoxy-(4-methylphenyl)methylium ion |
E Param.: 1.90 | | Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c | |
methoxy-(4-methoxyphenyl)methylium ion |
E Param.: 0.14 | | Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c | |
Me2N+=CH-CH-Ph |
E Param.: -9.20 | | Angew. Chem. Int. Ed. 2008, 47, 8723-8726 10.1002/anie.200802889 | |
Me2C=C=N(+)Me2 |
E Param.: -2.80 | | Synthesis 2025, , eFirst 10.1055/a-2649-1999 | |
maleic anhydride |
DMSO | E Param.: -11.31 | | Eur. J. Org. Chem. 2014, , 2956-2963 10.1002/ejoc.201301779 |
MacMillan-iminium ion (spiro) |
MeCN | E Param.: -7.67 | | Angew. Chem. Int. Ed. 2011, 50, 9953-9956 10.1002/anie.201103683 |
MacMillan-iminium ion (2nd generation) |
MeCN | E Param.: -5.52 | | Angew. Chem. Int. Ed. 2011, 50, 9953-9956 10.1002/anie.201103683 |
MacMillan-iminium ion (1st generation) |
MeCN | E Param.: -7.37 | | Angew. Chem. Int. Ed. 2011, 50, 9953-9956 10.1002/anie.201103683 |
julBBS |
E Param.: -13.84 | | J. Org. Chem. 2007, 72, 9170-9180 10.1021/jo071273g | |
jul-indan-1,3-dione |
E Param.: -14.68 | | Org. Biomol. Chem. 2007, 5, 3020-3026 10.1039/b708025e | |
jul(t-Bu)2QM |
E Param.: -17.90 | | Angew. Chem. Int. Ed. 2002, 41, 91-95 10.1002/1521-3773(20[...] | |
jul(S)BBS |
E Param.: -11.89 | | J. Org. Chem. 2007, 72, 9170-9180 10.1021/jo071273g | |
jul Meldrum's acid |
E Param.: -13.97 | | J. Org. Chem. 2008, 73, 2738-2745 10.1021/jo702590s | |
Jorgensen/Hayashi-iminium ion |
E Param.: -8.20 | | Angew. Chem. Int. Ed. 2008, 47, 8723-8726 10.1002/anie.200802889 | |
indolecarboxylate derived iminium ion |
dichloromethane | E Param.: -9.50 | | Angew. Chem. Int. Ed. 2009, 48, 5034-5037 10.1002/anie.200900933 |
hexanal (in DMSO) |
DMSO | | J. Am. Chem. Soc. 2011, 133, 8240-8251 10.1021/ja200820m | |
hex-3-yn-2-one |
E Param.: -17.90 | | Angew. Chem. Int. Ed. 2019, 58, 17704-17708 10.1002/anie.201909803 | |
furan-2(5H)-one |
DMSO | E Param.: -20.70 | | Chem. Sci. 2021, 12, 4850-4865 10.1039/D0SC06628A |
fumaronitrile |
DMSO | E Param.: -15.71 | | Eur. J. Org. Chem. 2014, , 2956-2963 10.1002/ejoc.201301779 |
flavylium ion |
E Param.: -3.45 | | Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c | |
fc2CH+ |
E Param.: -8.54 | | Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c | |
fc(Ph)CH+ |
E Param.: -2.64 | | J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y | |
fc(Me)CH+ |
E Param.: -2.57 | | Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c | |
fc(ani)CH+ |
E Param.: -2.90 | | Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c | |
ethyl prop-2-enoate (in DMSO) |
DMSO | E Param.: -19.07 | | J. Am. Chem. Soc. 2017, 139, 13318-13329 10.1021/jacs.7b05106 |
ethyl cinnamate (in DMSO) |
DMSO | E Param.: -24.52 | | J. Am. Chem. Soc. 2017, 139, 13318-13329 10.1021/jacs.7b05106 |
ethyl 3-nitro-1H-indole-1-carboxylate |
E Param.: -14.10 | | Chem. Commun. 2021, 57, 10071-10074 10.1039/d1cc04074j | |
ethyl 2-methylprop-2-enoate (in DMSO) |
DMSO | E Param.: -22.77 | | J. Am. Chem. Soc. 2017, 139, 13318-13329 10.1021/jacs.7b05106 |
ethyl 2-(3,5-di-tert-butyl-4-oxocyclohexa-2,5-dien-1-ylidene)acetate |
E Param.: -12.01 | | Chem. Eur. J. 2025, 31, e202501224 10.1002/chem.202501224 | |
ethyl (E)-but-2-enoate (in DMSO) |
DMSO | E Param.: -23.59 | | J. Am. Chem. Soc. 2017, 139, 13318-13329 10.1021/jacs.7b05106 |
ethenylsulfonylbenzene (in DMSO) |
DMSO | E Param.: -18.36 | | J. Am. Chem. Soc. 2017, 139, 13318-13329 10.1021/jacs.7b05106 |
ethenesulfonyl fluoride (ESF) |
DMSO | E Param.: -12.09 | | Angew. Chem. Int. Ed. 2016, 55, 12664-12667 10.1002/anie.201601875 |
E)-2,6-di-tert-butyl-4-(3-(4-chlorophenyl)allylidene)cyclohexa-2,5-dien-1-one |
DMSO | E Param.: -16.84 | | Org. Lett. 2020, 22, 2182-2186 10.1021/acs.orglett.[...] |
dmaBBS |
E Param.: -12.76 | | J. Org. Chem. 2007, 72, 9170-9180 10.1021/jo071273g |