| jul Meldrum's acid |
| E Param.: -13.97 |  | J. Org. Chem. 2008, 73, 2738-2745
10.1021/jo702590s |
| diethyl benzylidene malonate |
| E Param.: -20.55 | | Chem. Eur. J. 2008, 14, 9675-9682
10.1002/chem.200801277 |
| diethyl 4-nitrobenzylidene malonate |
| E Param.: -17.67 | | Chem. Eur. J. 2008, 14, 9675-9682
10.1002/chem.200801277 |
| diethyl 4-cyano-benzylidene malonate |
| E Param.: -18.06 | | Chem. Eur. J. 2008, 14, 9675-9682
10.1002/chem.200801277 |
| diethyl 3-chloro-benzylidene malonate |
| E Param.: -18.98 | | Chem. Eur. J. 2008, 14, 9675-9682
10.1002/chem.200801277 |
| diethyl 4-methyl-benzylidene malonate |
| E Param.: -21.11 | | Chem. Eur. J. 2008, 14, 9675-9682
10.1002/chem.200801277 |
| diethyl 4-methoxy-benzylidene malonate |
| E Param.: -21.47 | | Chem. Eur. J. 2008, 14, 9675-9682
10.1002/chem.200801277 |
| diethyl 4-(dimethylamino)benzylidene malonate |
| E Param.: -23.10 | | Chem. Eur. J. 2008, 14, 9675-9682
10.1002/chem.200801277 |
| Me2N+=CH-CH-Ph |
| E Param.: -9.20 | | Angew. Chem. Int. Ed. 2008, 47, 8723-8726
10.1002/anie.200802889 |
| pyrN+=CH-CH-Ph |
| E Param.: -9.80 | | Angew. Chem. Int. Ed. 2008, 47, 8723-8726
10.1002/anie.200802889 |
| (PhCH2)2N+=CH-CH-Ph |
| E Param.: -8.50 | | Angew. Chem. Int. Ed. 2008, 47, 8723-8726
10.1002/anie.200802889 |
| Jorgensen/Hayashi-iminium ion |
| E Param.: -8.20 | | Angew. Chem. Int. Ed. 2008, 47, 8723-8726
10.1002/anie.200802889 |
| MacMillan-iminium ion (1st generation) |
MeCN | E Param.: -7.37 | | Angew. Chem. Int. Ed. 2011, 50, 9953-9956
10.1002/anie.201103683 |
| mor iminium |
| E Param.: -8.60 | | Angew. Chem. Int. Ed. 2008, 47, 8723-8726
10.1002/anie.200802889 |
| 2,6-diphenyl-4-benzylidenecyclohexa-2,5-dienone |
| E Param.: -11.87 | | Eur. J. Org. Chem. 2009, , 3203-3211
10.1002/ejoc.200900299 |
| 2,6-dimethoxy-4-(4-methoxybenzylidene)cyclohexa-2,5-dienone |
| E Param.: -16.38 | | Eur. J. Org. Chem. 2009, , 3203-3211
10.1002/ejoc.200900299 |
| 2,6-dimethoxy-4-(4-(dimethylamino)benzylidene)cyclohexa-2,5-dienone |
| E Param.: -17.18 | | Eur. J. Org. Chem. 2009, , 3203-3211
10.1002/ejoc.200900299 |
| 2,6-dimethyl-4-(4-(dimethylamino)benzylidene)cyclohexa-2,5-dienone |
| E Param.: -16.36 | | Eur. J. Org. Chem. 2009, , 3203-3211
10.1002/ejoc.200900299 |
| 2,6-di-tert.butyl-4-(3-fluorobenzylidene)cyclohexa-2,5-dienone |
| E Param.: -15.03 | | Eur. J. Org. Chem. 2009, , 3203-3211
10.1002/ejoc.200900299 |
| 2,6-di-tert.butyl-4-(3,5-difluorobenzylidene)cyclohexa-2,5-dienone |
| E Param.: -14.50 | | Eur. J. Org. Chem. 2009, , 3203-3211
10.1002/ejoc.200900299 |
| 2,6-di-tert.butyl-4-(4-nitrobenzylidene)cyclohexa-2,5-dienone |
| E Param.: -14.36 | | Eur. J. Org. Chem. 2009, , 3203-3211
10.1002/ejoc.200900299 |
| cumyl cation |
| E Param.: 5.74 | | Macromolecules 2010, 43, 1719-1723
10.1021/ma9024569 |
| 1,2-diaza-1,3-diene 1a |
DMSO | E Param.: -13.28 | | Chem. Eur. J. 2010, 16, 12008-12016
10.1002/chem.201000828 |
| 1,2-diaza-1,3-diene 1b |
DMSO | E Param.: -13.90 | | Chem. Eur. J. 2010, 16, 12008-12016
10.1002/chem.201000828 |
| 1,2-diaza-1,3-diene 1c |
DMSO | E Param.: -14.91 | | Chem. Eur. J. 2010, 16, 12008-12016
10.1002/chem.201000828 |
| 1,2-diaza-1,3-diene 1d |
DMSO | E Param.: -15.38 | | Chem. Eur. J. 2010, 16, 12008-12016
10.1002/chem.201000828 |
| 2,3,4,5,6,6-hexachlorocyclohexa-2,4-dien-1-one |
MeCN | E Param.: -6.75 | | Org. Lett. 2010, 12, 2238-2241
10.1021/ol100592j |
| 5,7,7-trichloro-8(7H)-quinolinone |
MeCN | E Param.: -10.48 | | Org. Lett. 2010, 12, 2238-2241
10.1021/ol100592j |
| 2,2,4-trichloro-1(2H)-naphthalenone |
MeCN | E Param.: -11.24 | | Org. Lett. 2010, 12, 2238-2241
10.1021/ol100592j |
| dibenzyl azodicarboxylate |
MeCN | E Param.: -8.89 | | Chem. Eur. J. 2010, 16, 11670-11677
10.1002/chem.201001598 |
| diethyl azodicarboxylate |
MeCN | E Param.: -10.15 | | Chem. Eur. J. 2010, 16, 11670-11677
10.1002/chem.201001598 |
| diisopropyl azodicarboxylate |
MeCN | E Param.: -10.71 | | Chem. Eur. J. 2010, 16, 11670-11677
10.1002/chem.201001598 |
| di-tert-butyl azodicarboxylate |
MeCN | E Param.: -12.23 | | Chem. Eur. J. 2010, 16, 11670-11677
10.1002/chem.201001598 |
| (E)-3-(4-nitro-phenyl)-1-phenyl-prop-2-en-1-one (in DMSO) |
DMSO | E Param.: -17.33 | | J. Am. Chem. Soc. 2011, 133, 8240-8251
10.1021/ja200820m |
| (E)-3-(4-cyano-phenyl)-1-phenyl-prop-2-en-1-one (in DMSO) |
DMSO | E Param.: -17.64 | | J. Am. Chem. Soc. 2011, 133, 8240-8251
10.1021/ja200820m |
| (E)-1,3-diphenylprop-2-en-1-one (in DMSO) |
DMSO | E Param.: -19.39 | | J. Am. Chem. Soc. 2017, 139, 13318-13329
10.1021/jacs.7b05106 |
| (E)-N-benzylidene-4-methylbenzenesulfonamide (in DMSO) |
DMSO | E Param.: -11.50 | | J. Am. Chem. Soc. 2011, 133, 8240-8251
10.1021/ja200820m |
| (E)-N-(4-methoxybenzylidene)-4-methylbenzenesulfonamide (in DMSO) |
DMSO | E Param.: -13.05 | | J. Am. Chem. Soc. 2011, 133, 8240-8251
10.1021/ja200820m |
| (E)-N-(4-(dimethylamino)benzylidene)-4-methylbenzenesulfonamide (in DMSO) |
DMSO | E Param.: -15.09 | | J. Am. Chem. Soc. 2011, 133, 8240-8251
10.1021/ja200820m |
| (E)-tert-butyl benzylidenecarbamate (in DMSO) |
DMSO | E Param.: -14.22 | | J. Am. Chem. Soc. 2011, 133, 8240-8251
10.1021/ja200820m |
| (E)-N-benzylidene-P,P-diphenylphosphinic amide |
DMSO | E Param.: -15.89 | | J. Am. Chem. Soc. 2011, 133, 8240-8251
10.1021/ja200820m |
| diarylallylium ion (3,3-F2)2 |
| E Param.: 6.11 | | J. Org. Chem. 2011, 76, 9391-9408
10.1021/jo201668w |
| diarylallylium ion (4-Br)2 |
| E Param.: 2.85 | | J. Org. Chem. 2011, 76, 9391-9408
10.1021/jo201668w |
| diphenylallylium ion |
| E Param.: 2.70 | | J. Org. Chem. 2011, 76, 9391-9408
10.1021/jo201668w |
| di-p-tolyl-allylium ion |
| E Param.: 1.23 | | J. Org. Chem. 2011, 76, 9391-9408
10.1021/jo201668w |
| di-p-anisyl-allylium ion |
| E Param.: -1.45 | | J. Org. Chem. 2011, 76, 9391-9408
10.1021/jo201668w |
| diarylallylium ion (4-NMe2)2 |
| E Param.: -7.50 | | J. Org. Chem. 2011, 76, 9391-9408
10.1021/jo201668w |
| bis(julidin-9-yl)allylium ion |
| E Param.: -9.78 | | J. Org. Chem. 2011, 76, 9391-9408
10.1021/jo201668w |
| 4-methoxy-<i>trans-beta</i>-nitrostyrene |
| E Param.: -14.70 | | J. Org. Chem. 2011, 76, 9370-9378
10.1021/jo201678u |
| 4-methyl-<i>trans-beta</i>-nitrostyrene |
| E Param.: -14.23 | | J. Org. Chem. 2011, 76, 9370-9378
10.1021/jo201678u |
| <i>trans-beta</i>-nitrostyrene |
| E Param.: -13.85 | | J. Org. Chem. 2011, 76, 9370-9378
10.1021/jo201678u |
| 4-bromo-<i>trans-beta</i>-nitrostyrene |
| E Param.: -13.37 | | J. Org. Chem. 2011, 76, 9370-9378
10.1021/jo201678u |
| 4-cyano-<i>trans-beta</i>-nitrostyrene |
| E Param.: -12.61 | | J. Org. Chem. 2011, 76, 9370-9378
10.1021/jo201678u |
| 4-nitro-<i>trans-beta</i>-nitrostyrene |
| E Param.: -12.37 | | J. Org. Chem. 2011, 76, 9370-9378
10.1021/jo201678u |
| (ethene-1,1-diyldisulfonyl)dibenzene |
DMSO | E Param.: -7.50 | | Chem. Asian J. 2012, 7, 1401-1407
10.1002/asia.201101046 |
| (2-phenylethene-1,1-diyldisulfonyl)dibenzene |
DMSO | E Param.: -12.93 | | Chem. Asian J. 2012, 7, 1401-1407
10.1002/asia.201101046 |
| (2-(4-methoxyphenyl)ethene-1,1-diyldisulfonyl)dibenzene |
DMSO | E Param.: -13.88 | | Chem. Asian J. 2012, 7, 1401-1407
10.1002/asia.201101046 |
| 4-(2,2-bis(phenylsulfonyl)vinyl)-N,N-dimethylaniline |
DMSO | E Param.: -16.53 | | Chem. Asian J. 2012, 7, 1401-1407
10.1002/asia.201101046 |
| 2-benzylidenebenzo[d][1,3]dithiole 1,1,3,3-tetraoxide |
DMSO | E Param.: -11.78 | | Chem. Asian J. 2012, 7, 1401-1407
10.1002/asia.201101046 |
| 2-(4-methoxybenzylidene)benzo[d][1,3]dithiole 1,1,3,3-tetraoxide |
DMSO | E Param.: -13.02 | | Chem. Asian J. 2012, 7, 1401-1407
10.1002/asia.201101046 |
| 2-(4-methoxybenzylidene)-1,3-dithiane 1,1,3,3-tetraoxide |
DMSO | E Param.: -14.55 | | Chem. Asian J. 2012, 7, 1401-1407
10.1002/asia.201101046 |
| MacMillan-iminium ion (2nd generation) |
MeCN | E Param.: -5.52 | | Angew. Chem. Int. Ed. 2011, 50, 9953-9956
10.1002/anie.201103683 |
| MacMillan-iminium ion (spiro) |
MeCN | E Param.: -7.67 | | Angew. Chem. Int. Ed. 2011, 50, 9953-9956
10.1002/anie.201103683 |
| [(1,3-Diarylallyl)Pd(PPh3)2]+ (Aryl = Ph) |
| E Param.: -14.14 | | Organometallics 2012, 31, 2416-2424
10.1021/om3000357 |
| [(1,3-Diarylallyl)Pd(PPh3)2]+ (Aryl = 3,5-difluorophenyl) |
| E Param.: -14.21 | | Organometallics 2012, 31, 2416-2424
10.1021/om3000357 |
| [(1,3-Diarylallyl)Pd(PPh3)2]+ (Aryl = 4-(dimethylamino)phenyl) |
| E Param.: -14.46 | | Organometallics 2012, 31, 2416-2424
10.1021/om3000357 |
| 2-cinnamoyl-1,3-dimethyl-1H-imidazol-3-ium |
DMSO | E Param.: -11.52 | | Angew. Chem. Int. Ed. 2012, 51, 5234-5238
10.1002/anie.201109042 |
| PhCH=N+Me2 (in MeCN) |
MeCN | E Param.: -9.27 | | J. Am. Chem. Soc. 2013, 135, 6579-6587
10.1021/ja401106x |
| pTolCH=N+CH2 (in MeCN) |
MeCN | E Param.: -9.64 | | J. Am. Chem. Soc. 2013, 135, 6579-6587
10.1021/ja401106x |
| p-AniCH=N+Me2 (in MeCN) |
MeCN | E Param.: -10.69 | | J. Am. Chem. Soc. 2013, 135, 6579-6587
10.1021/ja401106x |
| PhCH=N+(CH2)4 (in MeCN) |
MeCN | E Param.: -9.35 | | J. Am. Chem. Soc. 2013, 135, 6579-6587
10.1021/ja401106x |
| PhCH=N+(CH2)5 (in MeCN) |
MeCN | E Param.: -9.60 | | J. Am. Chem. Soc. 2013, 135, 6579-6587
10.1021/ja401106x |
| p-CF3-C6H4-CH=N+Me2 (in MeCN) |
MeCN | E Param.: -8.34 | | J. Am. Chem. Soc. 2013, 135, 6579-6587
10.1021/ja401106x |
| 2,3-dichloro-5,6-dicyano-p-benzoquinone (DDQ) |
MeCN | E Param.: -3.66 | | J. Am. Chem. Soc. 2013, 135, 12377-12387
10.1021/ja405890d |
| maleic anhydride |
DMSO | E Param.: -11.31 | | Eur. J. Org. Chem. 2014, , 2956-2963
10.1002/ejoc.201301779 |
| N-methyl maleimide |
DMSO | E Param.: -14.07 | | Eur. J. Org. Chem. 2014, , 2956-2963
10.1002/ejoc.201301779 |
| fumaronitrile |
DMSO | E Param.: -15.71 | | Eur. J. Org. Chem. 2014, , 2956-2963
10.1002/ejoc.201301779 |
| diethyl fumarate |
DMSO | E Param.: -17.79 | | Eur. J. Org. Chem. 2014, , 2956-2963
10.1002/ejoc.201301779 |
| diethyl maleate |
DMSO | E Param.: -19.49 | | Eur. J. Org. Chem. 2014, , 2956-2963
10.1002/ejoc.201301779 |
| 2,5-dichloroquinone (C-H) |
| E Param.: -12.28 | | J. Am. Chem. Soc. 2014, 136, 11499-11512
10.1021/ja505613b |
| 2,5-dichloroquinone (C-Cl) |
| E Param.: -16.11 | | J. Am. Chem. Soc. 2014, 136, 11499-11512
10.1021/ja505613b |
| p-chloranil (C=O) |
| E Param.: -12.13 | | J. Am. Chem. Soc. 2014, 136, 11499-11512
10.1021/ja505613b |
| p-chloranil (C-Cl) |
| E Param.: -13.84 | | J. Am. Chem. Soc. 2014, 136, 11499-11512
10.1021/ja505613b |
| p-fluoranil (C=O) |
| E Param.: -9.37 | | J. Am. Chem. Soc. 2014, 136, 11499-11512
10.1021/ja505613b |
| p-fluoranil (C-F) |
| E Param.: -11.12 | | J. Am. Chem. Soc. 2014, 136, 11499-11512
10.1021/ja505613b |
| o-chloranil (C=O) |
| E Param.: -8.77 | | J. Am. Chem. Soc. 2014, 136, 11499-11512
10.1021/ja505613b |
| o-chloranil (C-Cl) |
| E Param.: -12.02 | | J. Am. Chem. Soc. 2014, 136, 11499-11512
10.1021/ja505613b |
| 3-benzylidene-1-methyl-3H-indol-1-ium ion |
| E Param.: -1.80 | | J. Org. Chem. 2015, 80, 8643-8656
10.1021/acs.joc.5b01298 |
| 1-methyl-3-(4-methylbenzylidene)-3H-indol-1-ium ion |
| E Param.: -2.19 | | J. Org. Chem. 2015, 80, 8643-8656
10.1021/acs.joc.5b01298 |
| 3-(4-methoxybenzylidene)-1-methyl-3H-indol-1-ium iom |
| E Param.: -3.02 | | J. Org. Chem. 2015, 80, 8643-8656
10.1021/acs.joc.5b01298 |
| 3-(4-(dimethylamino)benzylidene)-1-methyl-3H-indol-1-ium ion |
| E Param.: -6.26 | | J. Org. Chem. 2015, 80, 8643-8656
10.1021/acs.joc.5b01298 |
| 1-methyl-3-((julolidin-9-yl)methylene)-3H-indol-1-ium ion |
| E Param.: -7.79 | | J. Org. Chem. 2015, 80, 8643-8656
10.1021/acs.joc.5b01298 |
| (E)-2-methyl-3-(4-methylbenzylidene)-3H-indol-1-ium ion |
| E Param.: -5.15 | | J. Org. Chem. 2015, 80, 8643-8656
10.1021/acs.joc.5b01298 |
| (E)-1,2-dimethyl-3-(4-methylbenzylidene)-3H-indol-1-ium ion |
| E Param.: -5.05 | | J. Org. Chem. 2015, 80, 8643-8656
10.1021/acs.joc.5b01298 |
| bis(1-methylindol-3-yl)methylium ion |
| E Param.: -5.99 | | J. Org. Chem. 2015, 80, 8643-8656
10.1021/acs.joc.5b01298 |
| bis(5-methoxy-1-methylindol-3-yl)methylium ion |
| E Param.: -6.90 | | J. Org. Chem. 2015, 80, 8643-8656
10.1021/acs.joc.5b01298 |
| bis(1,2-dimethylindol-3-yl)methylium ion |
| E Param.: -10.23 | | J. Org. Chem. 2015, 80, 8643-8656
10.1021/acs.joc.5b01298 |
| ethenesulfonyl fluoride (ESF) |
DMSO | E Param.: -12.09 | | Angew. Chem. Int. Ed. 2016, 55, 12664-12667
10.1002/anie.201601875 |
| 2-phenylethene-1-sulfonyl fluoride |
DMSO | E Param.: -16.63 | | Angew. Chem. Int. Ed. 2016, 55, 12664-12667
10.1002/anie.201601875 |
| 9-phenyl-9H-fluoren-9-ylium |
dichloromethane | E Param.: 2.41 | | Chem. Eur. J. 2017, 23, 623-630
10.1002/chem.201603963 |
C-Nucleophiles (572)
